Dissolved gas analysis (DGA) is used to assess the condition of power transformers. It uses the concentrations of various gases dissolved in the transformer oil due to decomposition of the oil and paper insulation. DGA has gained worldwide acceptance as a method for the detection of incipient faults in transformers.

A review of dissolved gas analysis measurement and interpretation techniques

A power transformer outage has a dramatic financial consequence not only for electric power systems utilities but also for interconnected customers. The service reliability of this important asset largely depends upon the condition of the oil-paper insulation. Therefore, by keeping the qualities of oil-paper insulation system in pristine condition, the maintenance planners can reduce the decline rate of internal faults. Accurate diagnostic methods for analyzing the condition of transformers are therefore essential. Currently, there are various electrical and physicochemical diagnostic techniques available for insulation condition monitoring of power transformers. This paper is aimed at the description, analysis and interpretation of modern physicochemical diagnostics techniques for assessing insulation condition in aged transformers. Since fields and laboratory experiences have shown that transformer oil contains about 70% of diagnostic information, the physicochemical analyses of oil samples can therefore be extremely useful in monitoring the condition of power transformers.

Review of Physicochemical-Based Diagnostic Techniques for Assessing Insulation Condition in Aged Transformers

This article attempts to capture and summarize the known technical information and recommendations for analysis of furan test results. It will also provide the technical basis for continued gathering and evaluation of furan data for liquid power transformers, and provide a recommended structure for collecting that data.

Furan analysis for liquid power transformers

As a non-renewable resource, mineral oil has been re-evaluated for its value and suitability as the coolant and insulator in transformers because of its environmental unfriendliness, fire hazards, and operating efficiency dissatisfaction. As a result, alternative dielectric liquids meeting the demands for more reliable, safer, and cleaner energy has been a critical need. Plant-based insulating fluids, non-toxic to the environment and ultimately biodegradable, have been flowing into the mainstream for achieving cost efficiencies, performance advantages, and enhancing safety. With more than 20 years of field experience, plant-based oils are now employed in more than 600,000 transformers worldwide, and have been established an enviable performance track record. Far from being just a mineral oil replacement, but more significantly, plant-based oils have filled a gap in some specific application scenarios where mineral oils fail to satisfy the fire-safety and environmental standards. This article reviews the research status of plant-based insulating fluids for transformer, including both challenges and outlook circa 2020. Plant-based oils have many inherent advantages over mineral oil, but also have numerous and unique challenges.

A critical review of plant-based insulating fluids for transformer: 30-year development

Ester-based dielectric fluids have gained widespread popularity for applications in high voltage apparatus. Synthetic and natural esters have been subjected to research for decades vis-a-vis mineral insulating oils around the world. Although many researchers favor the application of ester fluids, utilities are still uncertain and application of these alternatives remains a challenge. The intent of this survey is to present recent research progress and highlight the state of the art of key aspects that should be emphasized in future research. The contemporary research scenarios pertaining to the performance of ester fluids versus mineral oils, miscibility, and retrofilling of insulating fluids are discussed. In addition, pre-breakdown phenomena, usage of esters in on-load tap changers, environmental and fire resistance properties, and use of esters in cold climates are also discussed. Importantly, challenges and future aspects that should be investigated to improve the existing knowledge of ester dielectric fluids for applications in transformer technology are highlighted.

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Alternative Dielectric Fluids for Transformer Insulation System: Progress, Challenges, and Future Prospects

In this study, headspace gas chromatography/mass spectrometry has been used to assess the volatile by-products generated by the ageing of oil-impregnated paper insulation of power transformers. Sealed-glass ampoules were used to age under oxidative conditions 0.5-g specimens of insulating paper in 9 mL of inhibited mineral oil in a temperature range of 60–120 °C and moisture of 0.5, 1 and 2% (w/w). A linear relationship between one of the oil-soluble degradation by-products, i.e. methanol, and the number of ruptured 1,4-β-glycosidic bonds of cellulose, regardless of the type of paper (ordinary Kraft or thermally-upgraded (TU) Kraft paper), was established for the first time in this field. Ageing at 130 °C of model compounds of the Kraft paper constituents (α-cellulose, hemicellulose and lignin) and two cellulosic breakdown by-products (D-(+)-glucose and 1,6-anhydro-β-d-glucopyranose) confirmed that the α-cellulose degradation was mostly responsible for the presence of this molecule in the system. Furthermore, additional 130 °C-tests with six different papers and pressboard samples under a tight control of initial moisture indicated that at least one molecule of methanol is formed for each rupture of 1,4-β-glucosidic bond of the molecular chains. Stability tests showed that the ageing indicator is stable under the oxygen and temperature conditions of open-breathing transformers. The presence of methanol was detected in 94% of oil samples collected from over than 900 in-service pieces of equipment, confirming the potential for this application. Lastly, the tests have shown that oil-oxidation by-products and TU-nitrogenous agents modify the methanol partitioning coefficients in the paper/oil/air system, which makes their study essential over a range of field conditions encountered by power transformers. Results are presented and discussed in comparison with 2-furfuraldehyde, which is the current reference in the domain.

Identification of a chemical indicator of the rupture of 1,4-β-glycosidic bonds of cellulose in an oil-impregnated insulating paper system

All electrical utilities deal with the task of determining the residual life of their in-service power transformers. Given the difficulties experienced with the use of first and second generations of markers (carbon oxides and 2-furfuraldehyde), several organizations are now considering the use of methanol for this purpose. Hydro-Quebec, which discovered this approach, uses this molecule on a regular basis to evaluate the state of the cellulose insulation of in-service power transformers and applies it to Electricite de France's nuclear power plant transformers. In this paper, some examples of the application of methanol in the field are presented against the information received from the early marker generations.

Methanol: A Novel Approach to Power Transformer Asset Management

Recently, the existence of a relation between the rupture of 1,4-β-glycosidic bonds in the cellulose during thermal-ageing of paper/oil systems and the detection of methanol in the oil has been reported for the first time in this journal (Jalbert et al. 2007). The present study addresses the rate constants of the reaction for standard wood kraft papers, two immersed in inhibited naphthenic oil under air (paper/oil weight–volume ratio of 1:18) and one in non-inhibited paraffinic oil under nitrogen (paper/oil weight–volume ratio of 1:30). The isotherms in the range of 60–130 °C show that the initial rate of methanol production markedly increases with temperature and to a lesser extent with the moisture of the specimens (initially between 0.5 and 2.25% (w/w)), similarly to what is noted for the depolymerization through the Ekenstam’s pseudo-zero order model. The Arrhenius expression of the rate constants reveals linear relationships that confirm the dominance of a given mechanism in both cases. A very good agreement is also noted for the activation energy over the entirely paper/oil systems studied (106.9 ± 4.3 and 103.5 ± 3.7 kJ mol−1 for methanol and scissions, respectively). Furthermore, a comparison of the rate constants \( \left( {k_{{{\text{CH}}_{ 3} {\text{OH}}}} /k_{\text{scissions}} } \right) \) shows approximately constant values indicating an apparent yield for the methanol of about one-third molecule per every scission for the tests under air (0.27 ± 0.04 for Clupak HD75 and 0.37 ± 0.14 for Munksjo TH70) and even lower for the ones under N2 (0.12 ± 0.03 for Munksjo E.G.). As expected from a pseudo-zero order model, these values were shown to be consistent with a similar comparison of the amount of CH3OH and chain-end groups produced under specific time–temperature ageing conditions (168 h at 120 °C). Finally, an additional test carried out with unaged cellulose in contact with a fresh solution of methanol in oil (cellulose/oil weight–volume ratio of 1:18) shows that at equilibrium, over 58% of the species is lost from the solution due to penetration into the fibres. Such results reveal the importance of the species partitioning in establishing the true correspondence between the molecules of CH3OH produced and the scissions.

Kinetics of the production of chain-end groups and methanol from the depolymerization of cellulose during the ageing of paper/oil systems. Part 1: Standard wood kraft insulation

In order to go further in demonstrating that methanol can be used as a universal cellulose degradation indicator in power transformers, the ageing study of standard wood kraft specimens in oil in the range of 60–130 °C (Gilbert et al. in Cellulose 16:327–338, 2009) has been extended to thermally-upgraded (TU) papers. The kinetic model that best tracks the ageing patterns was shown to be a function that can accelerate or decelerate the pseudo-zero kinetics by the adjustment of a free parameter. The results showed a non-negligible contribution of 1,4-β-glycosidic bond breaking in the crystalline regions suggesting that the degradation at this level is not necessary occurring through a quantum mode mechanism. The results also showed a significant error in the determination of the rate constants when obtained from isotherms of varying degree of depolymerization. In the case of TU papers, provided that there is a sufficient amount of stabilizers in the fibrous structure, not only could the self-catalyzing nature of the cellulose ageing process as well as the effect of an external supply of catalysts be lost but the chain-breaking could decrease to nearly zero for an undetermined period well before reaching the levelling-off degree of polymerization. The initial rate constants (k
 1o) for the depolymerization and methanol formation of these papers were found to be very near those of standard cellulose (giving about the same activation energy), which indicates that they are obtained from the ageing patterns well before the retardant action has fully taken place. The life extension of TU papers is achieved by a reduction with time of the frequency at which the bonds are ruptured. Moreover, the production of methanol and chain-end groups showed about the same value for the frequency factor, which introduces the possibility that the rate of production of CH3OH from chopped chains is much higher than the rate of depolymerization, so that the latter becomes the rate determining step of the overall reaction. On the other hand, the apparent yield of CH3OH molecules per scission is seen to increase substantially with the amount of stabilizers (from ~0.4 to 0.8 and to 1.4 for a paper containing 0 to 1.15 and to 3.9% (w/w) N2) and to a lesser extent, with the moisture in the specimens. However, these variations could either be attributed to a modification of the CH3OH paper/oil partitioning by the stabilizers and moisture in fibrous structure. Finally, pre-aged systems (130 °C for 168 h) conditioned at 20 °C for variable lengths of time provided further evidence that O2 is not necessarily involved in CH3OH production.

Kinetics of the production of chain-end groups and methanol from the depolymerization of cellulose during the ageing of paper/oil systems. Part 2: Thermally-upgraded insulating papers

Jocelyn Jalbert

Papers

Identification of a chemical indicator of the rupture of 1,4-β-glycosidic bonds of cellulose in an oil-impregnated insulating paper system

Alternative Dielectric Fluids for Transformer Insulation System: Progress, Challenges, and Future Prospects

Methanol: A Novel Approach to Power Transformer Asset Management

Kinetics of the production of chain-end groups and methanol from the depolymerization of cellulose during the ageing of paper/oil systems. Part 1: Standard wood kraft insulation

Kinetics of the production of chain-end groups and methanol from the depolymerization of cellulose during the ageing of paper/oil systems. Part 2: Thermally-upgraded insulating papers