Showing papers by "John A. Cherry published in 1984"

An Advection‐Diffusion Concept for Solute Transport in Heterogeneous Unconsolidated Geological Deposits

Abstract: In layered permeable deposits with flow predominately parallel to the bedding, advection causes rapid solute transport in the more permeable layers. As the solute advances more rapidly in these layers, solute mass is continually transferred to the less permeable layers as a result of molecular diffusion due to the concentration gradient between the layers. The interlayer solute transfer causes the concentration to decline along the permeable layers at the expense of increasing the concentration in the less permeable layers, which produces strongly dispersed concentration profiles in the direction of flow. The key parameters affecting the dispersive capability of the layered system are the diffusion coefficients for the less permeable layers, the thicknesses of the layers, and the hydraulic conductivity contrasts between the layers. Because interlayer solute transfer by transverse molecular diffusion is a time-dependent process, the advection-diffusion concept predicts a rate of longitudinal spreading during the development of the dispersion process that is inconsistent with the classical Fickian dispersion model. A second consequence of the solute-storage effect offered by transverse diffusion into low-permeability layers is a rate of migration of the frontal portion of a contaminant in the permeable layers that is less than the groundwater velocity. Although various lines of evidence are presented in support of the advection-diffusion concept, more work is required to determine the range of geological materials for which it is applicable and to develop mathematical expressions that will make it useful as a predictive tool for application to field cases of contaminant migration.

A Comparative Study of Specific Yield Determinations for a Shallow Sand Aquifer

Abstract: Using the type-curve methods of Boulton (1963) and Neuman (1972), and comparisons, at various times, of the cumulative volume of water pumped to the volume of the water-table drawdown cone (volume-balance method), values of specific yield were obtained from pumping test data from numerous piezometers in an unconfined sand aquifer. The long-term value of specific yield for the aquifer was determined from measurements of the laboratory drainage curve of the aquifer material. The volume-balance method gave specific yield values of 0.02, 0.05, 0.12, 0.20, 0.23, and 0.25 at times of 0.25, 0.66, 10, 26, 45, and 65 hours, respectively, indicating a gradual increase in specific yield and an asymptotic approach to the long-term value of 0.30 determined from the laboratory method. The type-curve methods provided values of 0.07 and 0.08, which correspond to the volume-balance values at early times, but which are less than one-third of the value obtained from the laboratory method and from the volume-balance method applied at the end of the pumping test (2.7 days). The type-curve procedures therefore provide unrealistically low values of specific yield for application to problems concerning the long-term yield characteristics of the aquifer. The observed trend towards increasing values of specific yield with increasing duration of pumping, and the vertical hydraulic head profiles that were measured during the pumping test indicate that both delayed drainage from above the water table and downward hydraulic gradients in the saturated zone can be important hydraulic effects contributing to the delayed-drawdown segment that is characteristic of time-drawdown graphs for unconfined aquifers.

Matrix Diffusion Effects on Contaminant Migration from an Injection Well in Fractured Sandstone

Abstract: Deep-well injection into fractured sandstone is an option for the disposal of contaminated mine dewatering discharge from an open pit uranium mine. As part of the assessment of potential contaminant migration from deep-well injection, the effect of matrix diffusion was evaluated. An analytical mathematical model was developed for the simulation of the radial movement of a contaminant front away from an injection point under steady flow conditions in a planar fracture with uniform properties. The model includes the effects of advection in the fracture, diffusion of contaminants from the fracture into the rock matrix, and equilibrium adsorption on the fracture surface as well as in the rock matrix. Effective diffusion coefficients obtained from laboratory experiments on 11 intact core samples varied from 3.4 × 10−8 to 3.2 × 10−7 cm2/s. Model simulations were made with diffusion coefficient values in this range and with single-fracture injection rates estimated from fracture frequencies in boreholes, and from bulk hydraulic conductivity values obtained from field tests. Because of matrix diffusion, the rate of outward movement of the front of the nonreactive contaminants from the injection well is much slower than the rate of water flow in the fractures. Simulations of the movement of contaminants that undergo adsorption indicate that even a small distribution coefficient for the rock matrix causes the contaminants to remain very close to the injection well during the one-year period. The results of the simplified model demonstrate that matrix diffusion is an important process that cannot be neglected in the assessment of a waste disposal scheme located in fractured porous rock. However, in order to make a definitive assessment of the capability of matrix diffusion and associated matrix adsorption to significantly limit the extent of contaminant migration around injection wells, it would be necessary to conduct field tests such as a preliminary or experimental injection.

Geochemical reactions associated with low-temperature thermal energy storage in aquifers

Abstract: The geochemical mass transfer model WATEGM-SE is used to illustrate by example potential chemical reactions that can occur at a hypothetical low-temperature thermal energy aquifer storage facility....

A Syringe and Cartridge Method for Down‐Hole Sampling for Trace Organics in Ground Water

Abstract: A newly developed technique which allows the down-hole sampling and subsequent analysis of ground water for trace organic contaminants was tested during an investigation of contaminant migration at an inactive landfill site in Burlington, Ontario, Canada. The sampling device, which is lowered down piezometers with a tube, consists of a small cylindrical cartridge of sorbent material attached to a syringe. Vacuum or pressure applied at the surface controls the movement of the plunger in the syringe. The volume of the syringe determines the volume of sample water that passes through the cartridge. The cartridge is removed from the syringe at the surface. One cartridge is used for each sampling; the syringe is reusable. The residual water in the cartridge is removed in the laboratory, and the cartridge is desorbed to a fused silica capillary column for analysis by gas chromatography (GC). The analyses discussed here were performed on a GC/mass spectrometer/data system (GC/MS/DS). Of the many organic compounds that were identified in the samples, three compounds were clearly landfill-related: 1,1,1-trichloroethane, chlorobenzene, and para-dichlorobenzene. The three compounds were found at levels substantially above blank levels in 9, 5, and 5 piezometers, respectively. The average concentrations were 14., 5.3, and 0.88μg/1 (ppb), respectively. The pooled coefficients of variation for the analyses for the three compounds were 27., 6.9, and 6.4%, respectively. The volatility of 1,1,1-trichloroethane was probably the cause of the greater variability in its analytical data. The main advantages of the technique over most conventional sampling methods include: (1) down-hole sampling in a manner which minimizes the potential for volatilization losses; (2) avoidance of passage of the sample through long sections of tubing that may contaminate the sample or cause adsorptive losses; (3) convenience of sample handling, storage, and shipping; and (4) high sensitivity.