A review of conduction phenomena in Li-ion batteries

This review provides a comprehensive evaluation of the state-of-knowledge of radiation effects in crystalline ceramics that may be used for the immobilization of high-level nuclear waste and plutonium. The current understanding of radiation damage processes, defect generation, microstructure development, theoretical methods, and experimental methods are reviewed. Fundamental scientific and technological issues that offer opportunities for research are identified. The most important issue is the need for an understanding of the radiation-induced structural changes at the atomic, microscopic, and macroscopic levels, and the effect of these changes on the release rates of radionuclides during corrosion.

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Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium

We describe four criteria for the selection of alloying elements capable of producing castable, precipitation-strengthened Al alloys with high-temperature stability and strength: these alloying elements must (i) be capable of forming a suitable strengthening phase, (ii) show low solid solubility in Al, (iii) low diffusivity in Al, and (iv) retain the ability for the alloy to be conventionally solidified. With regard to criterion (i), we consider those systems forming Al3M trialuminide compounds with a cubic L12 crystal structure, which are chemically and structurally analogous to Ni3Al in the Ni-based superalloys. Eight elements, clustered in the same region of the periodic table, fulfill criterion (i): the first Group 3 transition metal (Sc), the three Group 4 transition metals (Ti, Zr, Hf) and the four latest lanthanide elements (Er, Tm, Yb, Lu). Based on a review of the existing literature, these elements are assessed in terms of criteria (ii) and (iii), which satisfy the need for a dispersion...

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Criteria for developing castable, creep-resistant aluminum-based alloys - A review

At the forefront of nanochemistry, there exists a research endeavor centered around intermetallic nanocrystals, which are unique in terms of long-range atomic ordering, well-defined stoichiometry, and controlled crystal structure. In contrast to alloy nanocrystals with no elemental ordering, it is challenging to synthesize intermetallic nanocrystals with a tight control over their size and shape. Here, recent progress in the synthesis of intermetallic nanocrystals with controllable sizes and well-defined shapes is highlighted. A simple analysis and some insights key to the selection of experimental conditions for generating intermetallic nanocrystals are presented, followed by examples to highlight the viable use of intermetallic nanocrystals as electrocatalysts or catalysts for various reactions, with a focus on the enhanced performance relative to their alloy counterparts that lack elemental ordering. Within the conclusion, perspectives on future developments in the context of synthetic control, structure-property relationships, and applications are discussed.

Intermetallic Nanocrystals: Syntheses and Catalytic Applications

The plastic deformation of crystalline and non-crystalline solids incorporates microscopically localized deformation modes that can be precursors to shear localization. Shear localization has been found to be an important and sometimes dominant deformation and fracture mode in metals, fractured and granular ceramics, polymers, and metallic glasses at high strains and strain rates. Experiments involving the collapse of a thick walled cylinder enable controlled and reproducible application of plastic deformation at very high strain rates to specimens. These experiments were supplemented by hat-shaped specimens tested in a compression Hopkinson bar. The initiation and propagation of shear bands has been studied in metals (Ti, Ta, Ti–6Al–4V, and stainless steel), granular and prefractured ceramics (Al2O3 and SiC), a polymer (teflon) and a metallic glass (Co58Ni10Fe5Si11B16). The first aspect that was investigated is the microstructural evolution inside the shear bands. A fine recrystallized structure is observed in Ti, Cu, Al–Li, and Ta, and it is becoming clear that a recrystallization mechanism is operating. The fast deformation and short cooling times inhibit grain-boundary migration; it is shown, for the first time, that a rotational mechanism, presented in terms of dislocation energetics and grain-boundary reorientation, can operate within the time of the deformation process. In pre-fractured and granular ceramics, a process of comminution takes place when the particles are greater than a critical size ac. When they are smaller than ac, particle deformation takes place. For the granular SiC, a novel mechanism of shear-induced bonding was experimentally identified inside the shear bands. For all materials, shear bands exhibit a clear self-organization, with a characteristic spacing that is a function of a number of parameters. This self-organization is analyzed in terms of fundamental material parameters in the frame of Grady–Kipp (momentum diffusion), Wright–Ockendon, and Molinari (perturbation) models. © 2001 Elsevier Science B.V. All rights reserved.

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Shear localization in dynamic deformation of materials: microstructural evolution and self-organization

IN view of the interest attaching to the vaporisation and diffusion of solids, the following observations may be worthy of record.

John H. Howell

Papers

The Diffusion of Solids