Department of Materials Science, University of Patras, 26504 Rio Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Avenue, 116 35 Athens, Greece, Institut de Biologie Moleculaire et Cellulaire, UPR9021 CNRS, Immunologie et Chimie Therapeutiques, 67084 Strasbourg, France, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Trieste, Italy

Chemistry of Carbon Nanotubes

Recent interest in aspects common to quantum information and condensed matter has prompted a flurry of activity at the border of these disciplines that were far distant until a few years ago. Numerous interesting questions have been addressed so far. Here an important part of this field, the properties of the entanglement in many-body systems, are reviewed. The zero and finite temperature properties of entanglement in interacting spin, fermion, and boson model systems are discussed. Both bipartite and multipartite entanglement will be considered. In equilibrium entanglement is shown tightly connected to the characteristics of the phase diagram. The behavior of entanglement can be related, via certain witnesses, to thermodynamic quantities thus offering interesting possibilities for an experimental test. Out of equilibrium entangled states are generated and manipulated by means of many-body Hamiltonians.

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Entanglement in many-body systems

Energy transfer within photosynthetic systems can display quantum effects such as delocalized excitonic transport. Recently, direct evidence of long-lived coherence has been experimentally demonstrated for the dynamics of the Fenna-Matthews-Olson (FMO) protein complex [Engel et al., Nature (London) 446, 782 (2007)]. However, the relevance of quantum dynamical processes to the exciton transfer efficiency is to a large extent unknown. Here, we develop a theoretical framework for studying the role of quantum interference effects in energy transfer dynamics of molecular arrays interacting with a thermal bath within the Lindblad formalism. To this end, we generalize continuous-time quantum walks to nonunitary and temperature-dependent dynamics in Liouville space derived from a microscopic Hamiltonian. Different physical effects of coherence and decoherence processes are explored via a universal measure for the energy transfer efficiency and its susceptibility. In particular, we demonstrate that for the FMO complex, an effective interplay between the free Hamiltonian evolution and the thermal fluctuations in the environment leads to a substantial increase in energy transfer efficiency from about 70% to 99%.

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Environment-assisted quantum walks in photosynthetic energy transfer.

Transport phenomena at the nanoscale are of interest due to the presence of both quantum and classical behavior. In this work, we demonstrate that quantum transport efficiency can be enhanced by a dynamical interplay of the system Hamiltonian with pure dephasing induced by a fluctuating environment. This is in contrast to fully coherent hopping that leads to localization in disordered systems, and to highly incoherent transfer that is eventually suppressed by the quantum Zeno effect. We study these phenomena in the Fenna–Matthews–Olson protein complex as a prototype for larger photosynthetic energy transfer systems. We also show that the disordered binary tree structures exhibit enhanced transport in the presence of dephasing.

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Environment-assisted quantum transport

Quantum control is concerned with active manipulation of physical and chemical processes on the atomic and molecular scale. This work presents a perspective of progress in the field of control over quantum phenomena, tracing the evolution of theoretical concepts and experimental methods from early developments to the most recent advances. Among numerous theoretical insights and technological improvements that produced the present state-of- the-art in quantum control, there have been several breakthroughs of foremost importance. On the technology side, the current experimental successes would be impossible without the development of intense femtosecond laser sources and pulse shapers. On the theory side, the two most critical insights were (i) realizing that ultrafast atomic and molecular dynamics can be controlled via manipulation of quantum interferences and (ii) understanding that optimally shaped ultrafast laser pulses are the most effective means for producing the desired quantum interference patterns in the controlled system. Finally, these theoretical and experimental advances were brought together by the crucial concept of adaptive feedback control (AFC), which is a laboratory procedure employing measurement-driven, closed-loop optimization to identify the best shapes of femtosecond laser control pulses for steering quantum dynamics towards the desired objective. Optimization in AFC experiments is guided by a learning algorithm, with stochastic methods proving to be especially effective. AFC of quantum phenomena has found numerous applications in many areas of the physical and chemical sciences, and this paper reviews the extensive experiments. Other subjects discussed include quantum optimal control theory, quantum control landscapes, the role of theoretical control

https://iopscience.iop.org/article/10.1088/1367-2630/12/7/075008/pdf

Control of quantum phenomena: past, present and future

Enhanced quantum entanglement in the non-Markovian dynamics of biomolecular excitons

The dynamical evolution of a quantum register of arbitrary length coupled to an environment of arbitrary coherence length is predicted within a relevant model of decoherence. The results are reported for quantum bits (qubits) coupling individually to different environments (``independent decoherence'') and qubits interacting collectively with the same reservoir (``collective decoherence''). In both cases, explicit decoherence functions are derived for any number of qubits. The decay of the coherences of the register is shown to strongly depend on the input states: We show that this sensitivity is a characteristic of both types of coupling (collective and independent) and not only of the collective coupling, as has been reported previously. A nontrivial behavior (``recoherence'') is found in the decay of the off-diagonal elements of the reduced density matrix in the specific situation of independent decoherence. Our results lead to the identification of decoherence-free states in the collective decoherence limit. These states belong to subspaces of the system's Hilbert space that do not get entangled with the environment, making them ideal elements for the engineering of ``noiseless'' quantum codes. We also discuss the relations between decoherence of the quantum register and computational complexity based on the dynamical results obtained for the register density matrix.

Decoherence of quantum registers

We give three methods for entangling quantum states in quantum dots. We do this by showing how to tailor the resonant energy (Forster-Dexter) transfer mechanisms and the biexciton binding energy in a quantum dot molecule. We calculate the magnitude of these two electrostatic interactions as a function of dot size, interdot separation, material composition, confinement potential, and applied electric field by using an envelope function approximation in a two-cuboid dot molecule. In the first implementation, we show that it is desirable to suppress the Forster coupling and to create entanglement by using the biexciton energy alone. We show how to perform universal quantum logic in a second implementation which uses the biexciton energy together with appropriately tuned laser pulses: by selecting appropriate material parameters high-fidelity logic can be achieved. The third implementation proposes generating quantum entanglement by switching the Forster interaction itself. We show that the energy transfer can be fast enough in certain dot structures that switching can occur on a time scale which is much less than the typical decoherence times.

Optical schemes for quantum computation in quantum dot molecules

We show how optically driven coupled quantum dots can be used to prepare maximally entangled Bell and Greenberger-Horne-Zeilinger states. Manipulation of the strength and duration of the selective light pulses needed for producing these highly entangled states provides us with crucial elements for the processing of solid-state-based quantum information. Theoretical predictions suggest that several hundred single quantum bit rotations and controlled-NOT gates could be performed before decoherence of the excitonic states takes place.

Quantum entanglement and information processing via excitons in optically driven quantum dots

We consider two coupled generic quantum dots, each modeled by a simple potential which allows the derivation of an analytical expression for the interdot Forster coupling, in the dipole-dipole approximation. We investigate the energy level behavior of this coupled two-dot system under the influence of an external applied electric field and predict the presence of anticrossings in the optical spectra due to the Forster interaction.

John H. Reina

Papers

Enhanced quantum entanglement in the non-Markovian dynamics of biomolecular excitons

Decoherence of quantum registers

Optical schemes for quantum computation in quantum dot molecules

Quantum entanglement and information processing via excitons in optically driven quantum dots

Anticrossings in Förster coupled quantum dots