Organic thin-film transistors (OTFTs) have lived to see great improvements in recent years. This review presents new insight into conduction mechanisms and performance characteristics, as well as opportunities for modeling properties of OTFTs. The shifted focus in research from novel chemical structures to fabrication technologies that optimize morphology and structural order is underscored by chapters on vacuum-deposited and solution-processed organic semiconducting films. Finally, progress in the growing field of the n-type OTFTs is discussed in ample detail. The Figure, showing a pentacene film edge on SiO2, illustrates the morphology issue.

Organic Thin Film Transistors for Large Area Electronics

Since the discovery of highly conducting polyacetylene by Shirakawa, MacDiarmid, and Heeger in 1977, π-conjugated systems have attracted much attention as futuristic materials for the development and production of the next generation of electronics, that is, organic electronics. Conceptually, organic electronics are quite different from conventional inorganic solid state electronics because the structural versatility of organic semiconductors allows for the incorporation of functionality by molecular design. This versatility leads to a new era in the design of electronic devices. To date, the great number of π-conjugated semiconducting materials that have either been discovered or synthesized generate an exciting library of π-conjugated systems for use in organic electronics. 11 However, some key challenges for further advancement remain: the low mobility and stability of organic semiconductors, the lack of knowledge regarding structure property relationships for understanding the fundamental chemical aspects behind the structural design, and realization of desired properties. Organic field-effect transistors (OFETs) are a kind of device consisting of an organic semiconducting layer, a gate insulator layer, and three terminals (drain, source, and gate electrodes). OFETs are not only essential building blocks for the next generation of cheap and flexible organic circuits, but they also provide an important insight into the charge transport of πconjugated systems. Therefore, they act as strong tools for the exploration of the structure property relationships of πconjugated systems, such as parameters of field-effect mobility (μ, the drift velocity of carriers under unit electric field), current on/off ratio (the ratio of the maximum on-state current to the minimum off-state current), and threshold voltage (the minimum gate voltage that is required to turn on the transistor). 17 Since the discovery of OFETs in the 1980s, they have attracted much attention. Research onOFETs includes the discovery, design, and synthesis of π-conjugated systems for OFETs, device optimization, development of applications in radio frequency identification (RFID) tags, flexible displays, electronic papers, sensors, and so forth. It is beyond the scope of this review to cover all aspects of π-conjugated systems; hence, our focus will be on the performance analysis of π-conjugated systems in OFETs. This should make it possible to extract information regarding the fundamental merit of semiconducting π-conjugated materials and capture what is needed for newmaterials and what is the synthesis orientation of newπ-conjugated systems. In fact, for a new science with many practical applications, the field of organic electronics is progressing extremely rapidly. For example, using “organic field effect transistor” or “organic field effect transistors” as the query keywords to search the Web of Science citation database, it is possible to show the distribution of papers over recent years as shown in Figure 1A. It is very clear

Semiconducting π-conjugated systems in field-effect transistors: a material odyssey of organic electronics.

At present, flexible displays are an important focus of research1,2,3 Further development of large, flexible displays requires a cost-effective manufacturing process for the active-matrix backplane, which contains one transistor per pixel One way to further reduce costs is to integrate (part of) the display drive circuitry, such as row shift registers, directly on the display substrate Here, we demonstrate flexible active-matrix monochrome electrophoretic displays based on solution-processed organic transistors on 25-μm-thick polyimide substrates The displays can be bent to a radius of 1 cm without significant loss in performance Using the same process flow we prepared row shift registers With 1,888 transistors, these are the largest organic integrated circuits reported to date More importantly, the operating frequency of 5 kHz is sufficiently high to allow integration with the display operating at video speed This work therefore represents a major step towards 'system-on-plastic'

Flexible active-matrix displays and shift registers based on solution-processed organic transistors.

Color Control in π-Conjugated Organic Polymers for Use in Electrochromic Devices

In this paper we review recent progress in materials, fabrication processes, device designs, and applications related to organic thin-film transistors (OTFTs), with an emphasis on papers published during the last three years. Some earlier papers that played an important role in shaping the OTFT field are included, and a number of previously published review papers that cover that early period more completely are referenced. We also review in more detail related work that originated at IBM during the last four years and has led to the fabrication of high-performance organic transistors on flexible, transparent plastic substrates requiring low operating voltages.

Organic thin-film transistors: a review of recent advances

It has for many years been an ambition of researchers in display media to create a flexible low-cost system that is the electronic analogue of paper. In this context, microparticle-based displays1,2,3,4,5 have long intrigued researchers. Switchable contrast in such displays is achieved by the electromigration of highly scattering or absorbing microparticles (in the size range 0.1–5 μm), quite distinct from the molecular-scale properties that govern the behaviour of the more familiar liquid-crystal displays6. Microparticle-based displays possess intrinsic bistability, exhibit extremely low power d.c. field addressing and have demonstrated high contrast and reflectivity. These features, combined with a near-lambertian viewing characteristic, result in an ‘ink on paper’ look7. But such displays have to date suffered from short lifetimes and difficulty in manufacture. Here we report the synthesis of an electrophoretic ink based on the microencapsulation of an electrophoretic dispersion8. The use of a microencapsulated electrophoretic medium solves the lifetime issues and permits the fabrication of a bistable electronic display solely by means of printing. This system may satisfy the practical requirements of electronic paper.

An electrophoretic ink for all-printed reflective electronic displays

An electrophoretic display has a substantially two-dimensional arrangement of microcapsules each having therein an electrophoretic composition of a dielectric fluid and a suspension of particles that visually contrast with the dielectric liquid and also exhibit surface charges; a pair of electrodes, at least one of which is visually transparent, disposed on and covering opposite sides of the microcapsule arrangement; and means for creating a potential difference between the two electrodes, the potential difference causing the particles to migrate toward one of the electrodes. The display may be powered by one or more piezoelectric elements, which are also suitable for powering other types of nonemissive displays.

Nonemissive displays and piezoelectric power supplies therefor

An application-ready electrophoresis material includes a carrier and a dispersion of microcapsules therein, the microcapsules each containing a plurality of phases therein. At least some of the phases contrast visually and and exhibit differential responsiveness to an electric field, such that application of the field determines the visual appearance of the microcapsules. The material exhibits stability such the visual appearance persists despite removal of the field. In one aspect, the invention provides for enhanced stability of the visual appearance. In another aspect, the reflectivity of at least one of the phases is enhanced. In another aspect, one of the phases is particulate in nature and emits visible radiation.

Microencapsulated electrophoretic display

Electrically (and, possibly, mechanically) active patterns are applied using a colloidal suspension of nanoparticles that exhibit a desired electrical characteristic. The nanoparticles are surrounded by an insulative shells that may be removed by therefrom by application of energy (e.g., in the form of electromagnetic radiation or heat). The nanoparticle suspension is applied to a surface, forming a layer that is substantially insulative owing to the nanoparticle shells. The applied suspension is exposed to energy to remove the capping groups and fuse the particles into cohesion. If the nanoparticle suspension was deposited as a uniform film, the energy is applied in a desired pattern so that unexposed areas remain insulative while exposed areas exhibit the electrical behavior associated with the nanoparticles. If the nanoparticle suspension was deposited in a desired pattern, it may be uniformly exposed to energy. Additional layers may be applied in the same manner, one over the other, to form a multilayer device.

Methods for manufacturing electronic and electromechanical elements and devices by thin-film deposition and imaging

An application-ready electrophoresis material includes a carrier and a dispersion of microcapsules therein, the microcapsules each containing a plurality of phases therein. At least some of the phases contrast visually and exhibit differential responsiveness to an electric field, such that application of the field determines the visual appearance of the microcapsules. The material exhibits stability such that the visual appearance persists despite removal of the field. In one aspect, the invention provides for enhanced stability of the visual appearance. In another aspect, the reflectivity of at least one of the phases is enhanced. In another aspect, one of the phases is particulate in nature and emits visible radiation.

Joseph M. Jacobson

Papers

An electrophoretic ink for all-printed reflective electronic displays

Nonemissive displays and piezoelectric power supplies therefor

Microencapsulated electrophoretic display

Methods for manufacturing electronic and electromechanical elements and devices by thin-film deposition and imaging

Improved microencapsulated electrophoretic display