. In spring 2006, the European Arctic was abnormally warm, setting new historical temperature records. During this warm period, smoke from agricultural fires in Eastern Europe intruded into the European Arctic and caused the most severe air pollution episodes ever recorded there. This paper confirms that biomass burning (BB) was indeed the source of the observed air pollution, studies the transport of the smoke into the Arctic, and presents an overview of the observations taken during the episode. Fire detections from the MODIS instruments aboard the Aqua and Terra satellites were used to estimate the BB emissions. The FLEXPART particle dispersion model was used to show that the smoke was transported to Spitsbergen and Iceland, which was confirmed by MODIS retrievals of the aerosol optical depth (AOD) and AIRS retrievals of carbon monoxide (CO) total columns. Concentrations of halocarbons, carbon dioxide and CO, as well as levoglucosan and potassium, measured at Zeppelin mountain near Ny Alesund, were used to further corroborate the BB source of the smoke at Spitsbergen. The ozone (O3) and CO concentrations were the highest ever observed at the Zeppelin station, and gaseous elemental mercury was also elevated. A new O3 record was also set at a station on Iceland. The smoke was strongly absorbing – black carbon concentrations were the highest ever recorded at Zeppelin – and strongly perturbed the radiation transmission in the atmosphere: aerosol optical depths were the highest ever measured at Ny Alesund. We furthermore discuss the aerosol chemical composition, obtained from filter samples, as well as the aerosol size distribution during the smoke event. Photographs show that the snow at a glacier on Spitsbergen became discolored during the episode and, thus, the snow albedo was reduced. Samples of this polluted snow contained strongly elevated levels of potassium, sulphate, nitrate and ammonium ions, thus relating the discoloration to the deposition of the smoke aerosols. This paper shows that, to date, BB has been underestimated as a source of aerosol and air pollution for the Arctic, relative to emissions from fossil fuel combustion. Given its significant impact on air quality over large spatial scales and on radiative processes, the practice of agricultural waste burning should be banned in the future.

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Arctic smoke – record high air pollution levels in the European Arctic due to agricultural fires in Eastern Europe in spring 2006

Trend analyses were performed on several indicators of Arctic haze using data from sites located in the North American, Norwegian, Finnish and Russian Arctic for the spring months of March and April. Concentrations of nonseasalt (nss) SO 4 = in the Canadian, Norwegian and Finnish Arctic were found to have decreased by 30–70% from the early 1990s to present. The magnitude of the decrease depended on location. The trend in nss SO 4 = at Barrow, Alaska from 1997 to present, is unclear. Measurements at Barrow of light scattering by aerosols show a decrease of about 50% between the early 1980s and the mid-1990s for both March and April. Restricting the analysis to the more recent period of 1997 to present indicates an increase in scattering of about 50% during March. Aerosol NO 3 - measured at Alert, Canada has increased by about 50% between the early 1990s and 2003. Nss K + and light absorption, indicators of forest fires, have a seasonal maximum during the winter and spring and minimum during the summer and fall at both Alert and Barrow. Based on these data, the impact of summertime forest fire emissions on low-altitude surface sites within the Arctic is relatively small compared to winter/spring emissions. Key uncertainties about the impact of long range transport of pollution to the Arctic remain including the certainty of the recent detected trends; sources, transport and trends of soot; and radiative effects due to complex interactions between aerosols, clouds and radiation in the Arctic. DOI: 10.1111/j.1600-0889.2006.00238.x

/pdf/arctic-haze-current-trends-and-knowledge-gaps-37v0moyk15.pdf

Arctic haze: current trends and knowledge gaps

Samples, 17 in total, from the EDML core drilled at Kohnen station Antarctica are analysed for 14 CO and 14 CO2 with a dry-extraction technique in combination with accelerator mass spectrometry. Results of the in situ produced 14 CO fraction show a very low concentration of in situ produced 14 CO. Despite these low levels in carbon monoxide, a significant in situ production is observed in the carbon dioxide fraction. For the first time we found background values for the ice samples which are equal to line blanks. The data set is used to test a model for the production of 14 C in the ice matrix, in combination with a degassing as 14 CO2 and possibly as 14 CO into the air bubbles. Application of the model, for which no independent validation is yet possible, offers the opportunity to use radiocarbon analysis as dating technique for the air bubbles in the ice. Assigning an arbitrary error of 25% to the calculation of the in situ production leads to age estimates, after correction for the in situ production, which are in agreement with age estimates based on a volcanic layer match of EDML to the Dome C timescale in combination with a correction for firn diffusion.

/pdf/radiocarbon-analyses-along-the-edml-ice-core-in-antarctica-7i9pkd2ene.pdf

Radiocarbon analyses along the EDML ice core in Antarctica

[1] During summer of 2004, about 2.7 million hectare of boreal forest burned in Alaska, the largest annual area burned on record, and another 3.1 million hectare burned in Canada. This study explores the impact of emissions from these fires on light absorbing aerosol concentration levels, aerosol optical depths (AOD), and albedo at the Arctic stations Barrow (Alaska), Alert (Canada), Summit (Greenland), and Zeppelin/Ny Alesund on Spitsbergen (Norway). The Lagrangian particle dispersion model FLEXPART was run backward from these sites to identify periods that were influenced by forest fire pollution plumes. It is shown that the fires led to enhanced values of particle light absorption coefficients (σap) at all of these sites. Barrow, about 1000 km away from the fires, was affected by several fire pollution plumes, one leading to spectacularly high 3-hour mean σap values of up to 32 Mm−1, more than the highest values measured in Arctic Haze. AOD measurements for a wavelength of 500 nm saturated but were estimated at above 4–5 units, unprecedented in the station records. Fire plumes were transported through the atmospheric column over Summit continuously for 2 months, during which all measured AOD values were enhanced, with maxima up to 0.4–0.5 units. Equivalent black carbon concentrations at the surface at Summit were up to 600 ng m−3 during two major episodes, and Alert saw at least one event with enhanced σap values. FLEXPART results show that Zeppelin was located in a relatively unaffected part of the Arctic. Nevertheless, there was a 4-day period with daily mean σap > 0.3 Mm−1, the strongest episode of the summer half year, and enhanced AOD values. Elevated concentrations of the highly source-specific compound levoglucosan positively confirmed that biomass burning was the source of the aerosols at Zeppelin. In summary, this paper shows that boreal forest fires can lead to elevated concentrations of light absorbing aerosols throughout the entire Arctic. Enhanced AOD values suggest a substantial impact of these plumes on radiation transmission in the Arctic atmosphere. During the passage of the largest fire plume, a pronounced drop of the albedo of the snow was observed at Summit. We suggest that this is due to the deposition of light absorbing particles on the snow, with further potentially important consequences for the Arctic radiation budget.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2006JD007216

Pan-Arctic enhancements of light absorbing aerosol concentrations due to North American boreal forest fires during summer 2004

Large sets of filtered actinometer, filtered pyrheliometer and Sun photometer measurements have been carried out over the past 30 years by various groups at different Arctic and Antarctic sites and ...

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2007JD008432

Aerosols in polar regions: A historical overview based on optical depth and in situ observations

[1] Ground-based measurements of total aerosol optical depth (AOD), e.g., tropospheric and stratospheric aerosol, have been established at the Koldewey station in Ny-Alesund, Spitzbergen (Norway, 78.95°N, 11.93°E), since 1991. The basic instrumentation is a multichannel photometer using sunlight. New instruments have been developed to extend the measurement period to polar night. The new instruments are a Sun and Moon photometer (1995) and a star photometer (1996). The instruments and applied methods for aerosol optical depth retrieval for Sun, Moon, and star measurements are briefly discussed. The year-round measurements made it possible to study in detail the interannual and seasonal variations of total AOD in the Arctic. The seasonal variation and the long-term trend of tropospheric aerosol optical depth are discussed, taking into account the stratospheric AOD measured by the Stratospheric Aerosol and Gas Experiment (SAGE II). The lowest tropospheric aerosol optical depth values occur in late summer and fall. Each year, strong Arctic haze events were recorded not only during spring but also in late winter as the first star photometer measurements clearly show. Five-day backward trajectories were used to analyze possible sources for high tropospheric AOD. Elevated tropospheric aerosol optical depth appears for northeasterly, easterly, or westerly winds. Finally, the long-term changes of tropospheric AOD have been assessed. A small positive trend of the tropospheric aerosol optical depth is found for the vicinity of Spitzbergen during the measurement period.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2001JD000536

K. H. Schulz

Papers

Continuous day and night aerosol optical depth observations in the Arctic between 1991 and 1999

Measurements of the spectral optical depth of aerosols with moon and star light during polar night 1994/95 and 1995/96 in Ny-Ålesund, Spitsbergen

Starphotometry at two High Arctic stations