K
Kees Goubitz
Researcher at University of Amsterdam
Publications - 181
Citations - 4191
Kees Goubitz is an academic researcher from University of Amsterdam. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 35, co-authored 181 publications receiving 4070 citations.
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Journal ArticleDOI
Electronic Effect on Rhodium Diphosphine Catalyzed Hydroformylation: The Bite Angle Effect Reconsidered
Lars A. van der Veen,Maarten D. K. Boele,Frank R. Bregman,Paul C. J. Kamer,Piet W. N. M. van Leeuwen,Kees Goubitz,Jan Fraanje,and Henk Schenk,Carles Bo +8 more
TL;DR: In this paper, a series of electronically modified thixantphos ligands were synthesized, and their effects on coordination chemistry and catalytic performance were studied. But the results were limited to the diphosphine-Rh(CO)H(PPh3) complexes.
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Alcoholysis of acylpalladium(II) complexes relevant to the alternating copolymerization of ethene and carbon monoxide and the alkoxycarbonylation of alkenes: the importance of Cis-coordinating phosphines.
Piet W. N. M. van Leeuwen,Martin Alexander Zuideveld,Bert H. G. Swennenhuis,Zoraida Freixa,Paul C. J. Kamer,Kees Goubitz,Jan Fraanje,Martin Lutz,Anthony L. Spek +8 more
TL;DR: It is concluded that ester elimination from acylpalladium complexes with alcohols requires cis geometry of the acyl group and coordinating alcohol.
Journal ArticleDOI
Bulky Diphosphite-Modified Rhodium Catalysts: Hydroformylation and Characterization
A. van Rooy,Paul C. J. Kamer,P.W.N.M. van Leeuwen,Kees Goubitz,Jan Fraanje,Nora Veldman,Anthony L. Spek +6 more
TL;DR: The rhodium-catalyzed hydroformylation with the diphosphites P[O(2,2‘-(4-X-6-Y-C6H2)2)OP][O(4-Z-C 6H4]2 as discussed by the authors.
Journal ArticleDOI
The coordination behaviour of large natural bite angle diphosphine ligands towards methyl and 4-cyanophenylpalladium(II) complexes †
Martin Alexander Zuideveld,Bert H. G. Swennenhuis,Maarten D. K. Boele,Yannick Guari,Gino P. F. van Strijdonck,Joost N. H. Reek,Paul C. J. Kamer,Kees Goubitz,Jan Fraanje,Martin Lutz,Anthony L. Spek,Piet W. N. M. van Leeuwen +11 more
TL;DR: In this paper, the structures of neutral and ionic 4-cyanophenylpalladium(II) and methyl palladium (II) complexes containing bidentate phosphine ligands were investigated in solution and in the solid state.
Journal ArticleDOI
Stable palladium(0), palladium(II) and platinum(II) complexes containing a new, multifunctional and hemilabile phosphino-imino-pyridyl ligand: Synthesis, characterization and reactivity
Richard E. Rülke,Vincent E. Kaasjager,P. Wehman,C.J. Elsevier,P.W.N.M. van Leeuwen,Kees Vrieze,Jan Fraanje,Kees Goubitz,A. L. Spek +8 more
TL;DR: The new, multifunctional, hemilabile phosphorus−bis(nitrogen) ligand N-(2-(diphenylphosphino)benzylidene)(2-(2-pyridyl)ethyl)amine, PNN, containing phosphine, imine, and pyridine donor groups was presented in this article.