Embodiments of the present invention relate to article comprising 1) a functionalized component, 2) tackifier, and 3) an olefin polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 5 mole % of ethylene having a Dot T-Peel of 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer; and an Mw of 100,000 or less; where the functional component is selected from the group consisting of functionalized polymers, functionalized oligomers and beta nucleating agents; and where the Gardner color of the adhesive does not change by more than 7 Gardner units when the adhesive has been heat aged at 180° C. for 48 hours as compared to the Gardner color of the unaged composition.

Polyolefin adhesive compositions and articles made therefrom

Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.

Propylene olefin copolymers

An adhesive blend is described that can include a semi-crystalline copolymer of propylene and at least one comonomer selected from the group consisting of ethylene and at least one C4 to C20 α-olefin, the copolymer having a weight average molecular weight (Mw) from about 15,000 to about 200,000; a melt index (MI) from about 7dg/min to about 3000 dg/min as measured by ASTM D 1238(B), and a (Mw/Mn) of approximately 2. Various production processes are also described. Also described are adhesive compositions and methods for making adhesive compositions having polymers or polymer blends with melt flow rates (MFRs) equal to and above 250 dg/min at 230NC. Certain specific embodiments of the invention involve the use of a free radical initiator, e.g., a peroxide.

Polypropylene-based adhesive compositions

The disclosed ethylene polymer compositions have et least one homogeneously branched substantially linear ethylene/α-olefin interpolymer and at least one heterogeneously branched ethylene polymer. The homogeneously branched linear or substantially linear ethylene/α-olefin interpolymer has a density from about 0.88 to about 0.935 g/cm3 and a slope of strain hardening coefficient greater than or equal to about 1.3. Films made from such formulated compositions have surprisingly good impact and tensile properties, and have an especially good combination of modulus and toughness.

Fabricated articles made from ethylene polymer blends

Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers

Thermoplastic adhesive compositions such as hot melts containing conventional components are improved considerably by the inclusion of acid or acid derivative grafted polyolefins particularly acrylic acid-grafted polypropylene, polyethylene and/or ethylene-propylene polymer substances. Alternatively, novel adhesive compositions are prepared in which the polyolefin constituent is entirely a grafted polyolefin.

Thermoplastic adhesive compositions

Compatibilized blends of polypropylene, linear low density polyethylene and a low molecular weight plastomer are disclosed. The blend preferably contains at least about 50 percent by weight of crystalline polypropylene, from about 10 to about 50 percent by weight of LLDPE dispersed in a matrix of the polypropylene, and a compatibilizing amount of an ethylene/alpha-olefin plastomer having a weight average molecular weight between about 5,000 to about 50,000, a density of less than about 0.90 g/cm3, and a melt index of at least about 50 dg/min. The blend is useful in the formation of melt spun and melt blown fibers. Also disclosed are spun bonded-melt blown-spun bonded fabrics made from the blends.

Plastomer compatibilized polyethylene/polypropylene blends

The rheology of C3 + polyolefins, eg polypropylene can be economically and conveniently controlled by injecting under pressure certain critical quantities of oxygen in an inert gas, eg, air into melted polymer as it is being processed within an extruder

Process for controlling rheology of c3+ polyolefins

Improved fastener articles, comprising a plurality of preferably rod-shaped fastener elements, such as nails or staples, are maintained in a predetermined configuration by bonding them together with one or more of either strips, films, or powdered particles of a specially formulated, adherent polyolefin copolymer. These fastener articles are especially adapted for use in automatic dispensers, i.e. nailers or staplers.

Use of chemically modified polyolefins for bonding nails together in a configuration suitable for use in a power driven nailer

Polyolefins, in particular polypropylene, are stabilized against UV degradation by a system of ethylene vinyl acetate, containing at least 20% by weight vinyl acetate and one or more of a nickel or zinc-N,N'-dialkyldithiocarbamate or a piperidine derivative such as bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate.

Kenneth W. Bartz

Papers

Thermoplastic adhesive compositions

Plastomer compatibilized polyethylene/polypropylene blends

Process for controlling rheology of c3+ polyolefins

Use of chemically modified polyolefins for bonding nails together in a configuration suitable for use in a power driven nailer

UV Stabilizer system and UV stabilized polyolefins