Preface to the second edition. About the author. 1 There is no substitute for water. 2 How long is long?. 3 Sediments: an ecosystem's memory. 4 Retrieving the sedimentary archive and establishing the geochronological clock: collecting and dating sediment cores. 5 Reading the records stored in sediments: the present is a key to the past. 6 The paleolimnologist's Rosetta Stone: calibrating indicators to environmental variables using surface-sediment training sets. 7 Acidification: finding the "smoking gun". 8 Metals, technological development, and the environment. 9 Persistent organic pollutants: industrially synthesized chemicals "hopping" across the planet. 10 Mercury - "the metal that slipped away". 11 Eutrophication: the environmental consequences of over-fertilization. 12 Erosion: tracking the accelerated movement of material from land to water. 13 Species invasions, biomanipulations, and extirpations. 14 Greenhouse gas emissions and a changing atmosphere: tracking the effects of climatic change on water resources. 15 Ozone depletion, acid rain, and climatic warming: the problems of multiple stressors. 16 New problems, new challenges. 17 Paleolimnology: a window on the past, a key to our future. Glossary. References. Index

Pollution of Lakes and Rivers: A Paleoenvironmental Perspective

Sub-nanometer-sized metal clusters, having dimensions between metal atoms and nanoparticles, have attracted tremendous attention in the recent past due to their unique physical and chemical properties. As properties of such materials depend strongly on size, development of synthetic routes that allows precise tuning of the cluster cores with high monodispersity and purity is an area of intense research. Such materials are also interesting owing to their wide variety of applications. Novel sensing strategies based on these materials are emerging. Owing to their extremely small size, low toxicity, and biocompatibility, they are widely studied for biomedical applications. Primary focus of this review is to provide an account of the recent advances in their applications in areas such as environment, energy, and biology. With further experimental and theoretical advances aimed at understanding their novel properties and solving challenges in their synthesis, an almost unlimited field of applications can be foreseen.

Noble Metal Clusters: Applications in Energy, Environment, and Biology

Recent advances in wide bandgap semiconductor biological and gas sensors

Surface-enhanced Raman scattering (SERS) is one of the most straightforward applications of the so-called nanoplasmonics. This powerful molecular spectroscopy technique is based on the enhancement of the inelastic scattering from molecules located near nanostructured metallic surfaces when these are illuminated and surface plasmons are excited. The analytical applications of SERS are hindered when the Raman cross-section of the analyte is too low, which is often the case in inorganic molecular species. This problem is even more serious when atomic species are to be identified, since these cannot display a vibrational signal. Herein we discuss the recent advancements toward the SERS detection of small inorganic compounds, including both molecular and atomic species.

SERS Detection of Small Inorganic Molecules and Ions

Biosensors, combining a selective biological recognition element and a sensitive transducer, are versatile analytical tools applied more and more in different fields, such as medicine, food quality and safety control, and environment pollution monitoring. They are expected to play an increasingly important role in the improvement of life quality. In this context, the present work covers recent approaches in design and development of biosensors applied for analysis of real samples of medical, environmental or industrial relevance. The described sensors meet the sensitivity, selectivity, and response time required by their applications. Moreover, they are designed to avoid contamination of the monitored systems with undesirable components and to minimise the damage of living organisms (when it comes to in vivo monitoring). (C) 2004 Elsevier B.V. All rights reserved. (Less)

Biosensors for life quality. Design, development and applications

Atomic Absorption, Atomic Emission, and Flame Emission Spectrometry

Mechanism of modification by palladium in graphite furnace atomic absorption spectrometry

Simultaneous determination of seven trace metals in potable water using a vidicon atomic absorption spectrometer.

Modification by palladium in the analysis of slurries by graphite furnace atomic absorption spectrometry: a physical mechanism

A multichannel atomic absorption spectrometer with a silicon-target vidicon detector was used for the simultaneous determination of trace metals in aqueous solution and in used lubricating oils. In most cases sensitivities were similar to those obtained by conventional single channel atomic absorption. Iron, magnesium, copper, and silver were simultaneously determined in lubricating oils, and, although precision was somewhat poorer than that normally attained by atomic absorption, it was adequate for this application. Good correlation was obtained between the vidicon method and a single channel method using a commercial atomic absorption spectrometer.

Kenneth W. Jackson

Papers

Atomic Absorption, Atomic Emission, and Flame Emission Spectrometry

Mechanism of modification by palladium in graphite furnace atomic absorption spectrometry

Simultaneous determination of seven trace metals in potable water using a vidicon atomic absorption spectrometer.

Modification by palladium in the analysis of slurries by graphite furnace atomic absorption spectrometry: a physical mechanism

Simultaneous Determination of Trace Wear Metals in Used Lubricating Oils by Atomic Absorption Spectrometry Using a Silicon-Target Vidicon Detector