The formability and mechanical properties of many engineering alloys are intimately related to the formation and growth of twins. Understanding the structure and chemistry of twin boundaries at the atomic scale is crucial if we are to properly tailor twins to achieve a new range of desired properties. We report an unusual phenomenon in magnesium alloys that until now was thought unlikely: the equilibrium segregation of solute atoms into patterns within fully coherent terraces of deformation twin boundaries. This ordered segregation provides a pinning effect for twin boundaries, leading to a concomitant but unusual situation in which annealing strengthens rather than weakens these alloys. The findings point to a platform for engineering nano-twinned structures through solute atoms. This may lead to new alloy compositions and thermomechanical processes.

Periodic Segregation of Solute Atoms in Fully Coherent Twin Boundaries

Towards magnesium alloys for high-volume automotive applications

Recent research and developments on wrought magnesium alloys

Pure magnesium exhibits poor ductility owing to pyramidal [Formula: see text] dislocation transformations to immobile structures, making this lowest-density structural metal unusable for many applications where it could enhance energy efficiency. We show why magnesium can be made ductile by specific dilute solute additions, which increase the [Formula: see text] cross-slip and multiplication rates to levels much faster than the deleterious [Formula: see text] transformation, enabling both favorable texture during processing and continued plastic straining during deformation. A quantitative theory establishes the conditions for ductility as a function of alloy composition in very good agreement with experiments on many existing magnesium alloys, and the solute-enhanced cross-slip mechanism is confirmed by transmission electron microscopy observations in magnesium-yttrium. The mechanistic theory can quickly screen for alloy compositions favoring conditions for high ductility and may help in the development of high-formability magnesium alloys.

http://science.sciencemag.org/content/sci/359/6374/447.full.pdf

Mechanistic origin and prediction of enhanced ductility in magnesium alloys.

The current study examines the influence of select rare earth elements; Gd, Nd, Ce, La and mischmetal (MM) on the sheet texture modification during warm rolling and annealing of a ZEK100 magnesium alloy, and the resulting formability and anisotropy during subsequent tensile testing at room temperature. It was found that all the investigated RE elements led to weak sheet textures and hence promoted enhanced ductility and reduced anisotropy over conventional Mg sheet. Gd was of a particular interest because it gave rise to a desired Mg sheet texture despite its coarsest grain size resulting in promising mechanical properties. It is suggested that solute related effects on the grain boundary migration and the relative strengths of different deformation mechanisms are responsible for altering the common concepts of recrystallization and grain growth during annealing, and the activation scenarios of slip and twinning during deformation.

Sheet texture modification in magnesium-based alloys by selective rare earth alloying

Effect of rare earth additions on microstructure and texture development of magnesium alloy sheets

Although conventional Mg alloys develop strong crystallographic textures during deformation that persist during annealing, the addition of rare earth (RE) elements can induce comparably weaker textures. The texture weakening effect is explored using hot-rolled Mg-Y alloys of a single phase to focus on the possibility of solute effects. Of the studied compositions, the richer alloys (≥0.17 at. pct) show the weakening effect, whereas the most dilute alloy (≤0.03 at. pct) does not. Electron backscattered diffraction (EBSD) analysis of intragranular misorientation axes (IGMA) indicate that the geometrically necessary dislocation (GND) content in dilute, hot-rolled alloys contain primarily basal 〈a〉 dislocations. At higher concentrations, the dislocations are predominantly prismatic 〈a〉 type. This change in the GND content suggests a change in dynamic recrystallization (DRX) mode. For example, nonbasal cross slip has been associated with continuous DRX. Furthermore, nonbasal slip might also promote more homogenous shear banding/twinning. Both of these mechanisms have been shown previously to give rise to more randomly oriented nuclei during DRX. Energy dispersive X-ray spectroscopy performed through transmission electron microscopy shows that Mg-Y exhibits significant grain boundary solute segregation, consistent with recent observations of solute clustering. Slow grain growth may be explained by solute drag. It is hypothesized that limited grain boundary mobility suppresses conventional discontinuous DRX, which has been shown to retain the deformation texture. The promotion of nonbasal slip and suppression of grain boundary mobility are proposed as solid solution-based mechanisms responsible for the observed texture weakening phenomenon in Mg rare earth alloys.

Role of Solute in the Texture Modification During Hot Deformation of Mg-Rare Earth Alloys

Hot-rolled, binary Mg-Nd alloys with compositions ≥0.095 at. pct undergo the texture weakening phenomenon that has been reported in a number of Mg–rare earth (RE) alloys. However, alloys with compositions ≤0.01 at. pct retain a strong basal texture typical of pure Mg and other Mg alloys. Measurements of intragranular misorientation axes obtained using electron backscatter diffraction (EBSD) show that more dilute alloys contain predominantly basal $$ $$
 dislocations, while richer alloys contain primarily prismatic $$ $$
 dislocations. It is suggested that this change in dislocation content is related to a change in the dynamic recrystallization (DRX) mechanism. Metastable second-phase Mg
 x
 Nd1–x
 intermetallic particles are present within the alloys, and an annealing study indicates that the alloys undergoing texture weakening have grain sizes well predicted by classical Zener drag theory. Even though the more dilute alloys also contain second-phase particles, they are not sufficient to induce pinning. The promotion of nonbasal slip and the reduction in grain boundary mobility due to Zener drag are suggested as controlling mechanisms that promote the observed texture weakening phenomena.

Effects of Solute and Second-Phase Particles on the Texture of Nd-Containing Mg Alloys

The purpose of the present study is to elucidate the cause of a texture transition observed in hot-rolled Mg-Ce alloys, with increasing Ce content. More dilute compositions show a predominance of basal 〈a〉 dislocations, while the more concentrated alloys are shown to contain significant populations of 〈c+a〉 and non-basal 〈a〉 dislocations in the as-rolled and the recovery-annealed conditions. Like Mg-Nd, the grain size in Mg-Ce decreases with increasing Ce. Unlike Mg-Nd, the second-phase particles observed are of the equilibrium phase, and the equilibrium solid solubility at the hot working temperature corresponds to the composition above which weak textures form. The significances of both non-basal slip and Zener pinning as contributors to texture randomization are discussed.

Texture Weakening Effects in Ce-Containing Mg Alloys

The paper addresses the relationship between microstructure, texture, and mechanical properties of rolled magnesium sheets. The effect of rolling temperature and alloying elements on texture development and mechanical properties is demonstrated. Special focus is paid to the potential of rare earth elements to modify the anisotropic behavior and to weaken the strong basal texture of magnesium sheets. Alloy design that considers these possibilities together with appropriate selection of process parameters show the road to magnesium sheets with improved forming properties.

Kerstin Hantzsche

Papers

Effect of rare earth additions on microstructure and texture development of magnesium alloy sheets

Role of Solute in the Texture Modification During Hot Deformation of Mg-Rare Earth Alloys

Effects of Solute and Second-Phase Particles on the Texture of Nd-Containing Mg Alloys

Texture Weakening Effects in Ce-Containing Mg Alloys

Mg sheet: the effect of process parameters and alloy composition on texture and mechanical properties