Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications

인공고관절의 세라믹 볼 헤드의 기계적 안정성 평가를 위한 3 차원 유한요소 해석

We developed two-step solution-phase reactions to form hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery applications. Mn3O4 nanoparticles grown selectively on RGO sheets over free particle growth in solution allowed for the electrically insulating Mn3O4 nanoparticles wired up to a current collector through the underlying conducting graphene network. The Mn3O4 nanoparticles formed on RGO show a high specific capacity up to ~900mAh/g near its theoretical capacity with good rate capability and cycling stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles grown atop. The Mn3O4/RGO hybrid could be a promising candidate material for high-capacity, low-cost, and environmentally friendly anode for lithium ion batteries. Our growth-on-graphene approach should offer a new technique for design and synthesis of battery electrodes based on highly insulating materials.

Mn3O4-Graphene Hybrid as a High Capacity Anode Material for Lithium Ion Batteries

Solution combustion is an exciting phenomenon, which involves propagation of self-sustained exothermic reactions along an aqueous or sol–gel media. This process allows for the synthesis of a variety of nanoscale materials, including oxides, metals, alloys, and sulfides. This Review focuses on the analysis of new approaches and results in the field of solution combustion synthesis (SCS) obtained during recent years. Thermodynamics and kinetics of reactive solutions used in different chemical routes are considered, and the role of process parameters is discussed, emphasizing the chemical mechanisms that are responsible for rapid self-sustained combustion reactions. The basic principles for controlling the composition, structure, and nanostructure of SCS products, and routes to regulate the size and morphology of the nanoscale materials are also reviewed. Recently developed systems that lead to the formation of novel materials and unique structures (e.g., thin films and two-dimensional crystals) with unusual...

Solution Combustion Synthesis of Nanoscale Materials

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A dual spiral sandwiched thin film inductor with a dimension of 5 mm /spl times/ 5 mm was fabricated by a LIGA-like micromachined process. FeBN magnetic films were used as a core material. The inductance and quality factor value of the inductor were measured approximately 1 /spl mu/H and 4 up to 5 MHz, respectively. Using the FeBN film inductor, a hybrid dc/dc converter (15 mm /spl times/ 12 mm /spl times/ 1.5 mm) was designed and fabricated. The circuit topology of the converter was a zero voltage switching clamp voltage (ZVS-CV) buck converter. An input of 3.6 V was bucked to 2.7 V at a switching frequency of 1.8 MHz. The maximum power was 1.5 W. The measured efficiency of the buck converter reached a maximum value of 80% and kept stable up to 300 mA of load currents at 1.8 MHz.

A megahertz switching DC/DC converter using FeBN thin film inductor

Soft magnetic materials application in the RF range

We demonstrated the radio-frequency (rf) noise suppressor using soft magnetic films on a coplanar transmission line from 0.1 to 20 GHz. The coplanar transmission line is composed of magnetic film/polyimide/Cu transmission line/seed layer (Cu/Ti)/glass substrate with the dimension of 50 μm width of the signal line and 3 μm thickness (characteristic impedance: 50 Ω). The magnetic films (CoPdAlO, CoZrO, and CoNbZr) as a noise suppressor are prepared by rf sputtering. The saturation magnetization of each magnetic film is about 10 kG. The magnetic anisotropy field and the ferromagnetic resonance frequency are 230, 89, and 6 Oe and 4.2, 2.5, and 0.7 GHz, respectively. The power loss of the coplanar line with magnetic films is significantly larger than without magnetic and nonmagnetic films due to ferromagnetic resonance losses.

Effect of radio-frequency noise suppression on the coplanar transmission line using soft magnetic thin films

Influence of processing methodology on the structural and magnetic behavior of MgFe2O4 nanopowders

Owing to high resistivity and high inplane uniaxial anisotropy, granular films are known to exhibit high permeability at radio frequencies. But this granular resistivity is not high enough to suppress eddy current when they are used at gigahertz frequencies. Recent developments to solve this problem are described. One is patterning the granular films. It is effective to control the inplane anisotropy and to suppress inplane eddy current. Another is deposition of granular films by evaporation. A peculiar fiber structure is formed for which very high resistivity and anisotropy are realized. Finally, a study of using these films as near-field electromagnetic noise absorbers is described, and it is demonstrated that they have high potential as micrometer-scale noise absorbing elements in the gigahertz frequency range.

Ki Hyeon Kim

Papers

A megahertz switching DC/DC converter using FeBN thin film inductor

Soft magnetic materials application in the RF range

Effect of radio-frequency noise suppression on the coplanar transmission line using soft magnetic thin films

Influence of processing methodology on the structural and magnetic behavior of MgFe2O4 nanopowders

Granular thin films with high RF permeability