K
Koichiro Oshima
Researcher at Kyoto University
Publications - 115
Citations - 2325
Koichiro Oshima is an academic researcher from Kyoto University. The author has contributed to research in topics: Catalysis & Triethylborane. The author has an hindex of 29, co-authored 115 publications receiving 2197 citations.
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Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines
TL;DR: Pyridine undergoes addition of pinacolborane at 50 °C in the presence of a rhodium catalyst, giving N-boryl-1,2-dihydropyridine in a high yield, and the selective 1, 2-hydroboration takes place in the reactions of substituted pyridines.
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Alkylidenation of Ester Carbonyl Groups by means of a Reagent Derived from RCHBr2, Zn, TiCl4, and TMEDA. Stereoselective Preparation of (Z)-Alkenyl Ethers
TL;DR: In the presence of zinc-dust and titanium tetrachloride, yielding the 1-alkenyl ethers (III) with predominance of the Z-isomers.
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Triethylborane-induced stereoselective radical addition of perfluoroalkyl iodides to acetylenes
TL;DR: In this paper, the perfluoroalkyl iodides were used for the treatment of terminal or internal acetylenes bearing a variety of substituents, in the presence of a catalytic amount of triethylborane.
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Trialkylborane as an initiator and terminator of free radical reactions. Facile routes to boron enolates via α-carbonyl radicals and aldol reaction of boron enolates
TL;DR: In this article, a variety of trialkylborane-induced reactions were examined for the preparation of α-carbonyl radicals: (1) addition of alkyl radical to methyl vinyl ketone, (2) reduction of α -halo ketone and (3) intramolecular radical addition to α,β-unsaturated carbonyl moiety.
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Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination
TL;DR: A reaction mechanism for the change of regioselectivity that involves reversible insertion/beta-boryl elimination steps is proposed.