Episulfonium ions: myth and reality

Competitive binding of nucleofugal anions in carbocationic-like processes

Regioselective Additions of Electrophiles to Olefins Remotely Perturbed - the Carbonyl Group as a Homoconjugated Electron Donating Substituent

The title compound, the condensation product of sulfur dichloride and 1,5-cyclooctadiene, is a reliable acceptor of a wide variety of heteroatom nucleophiles, sometimes in reversible fashion. Optical resolution of the core structure has been achieved and preserved in succeeding transformations. The high reactivity and reliable stereochemical control afforded by this system illustrates the power of neighboring-group participation by the sulfur center.

2,6-Dichloro-9-thiabicyclo[3.3.1]nonane: A Privileged, Bivalent Scaffold for the Display of Nucleophilic Components

This review is not meant to be exhaustive. Several reviews on the synthesis, physical properties, and reactivity of thiiranes have appeared in the past 17 years. This effort is to update previous work on thiiranes with an emphasis on research reported from 1985 to September, 1992.

Recent aspects of thiirane chemistry

New method for increasing of effective electrophilicity of weak electrophiles in addition reactions. Rearrangements and cis-addition in reactions of sulphenyl chlorides with norbornene and dimethoxybenzonorbornadiene

L.A. Novgorodtseva

Papers

New method for increasing of effective electrophilicity of weak electrophiles in addition reactions. Rearrangements and cis-addition in reactions of sulphenyl chlorides with norbornene and dimethoxybenzonorbornadiene

New method for increasing of electrophilicity of weak electrophiles in addition reactions

Reactivity of cyclooctene derived episulfonium ions toward nucleophiles and the course of sulfenyl halide addition to cyclooctene