L. Benedetti

TL;DR: In this paper, a linear relationship between theoretical predictions and experimental data is constructed and provided a mean unsigned error of about 0.19 V. The theoretical approach allows us also to discuss structural features related to the electron transfer process, like conformational changes found between the neutral and radical anion species (for instance, in the case of 4-4′dipyridyl a variation from 36° to almost zero of the ring-ring dihedral angle and a shortening of the single C-C bond when passing from the neutral to the radical anions).

TL;DR: In this article, the electrochemical behavior of polychlorobenzene derivatives is discussed on the basis of calculated quantum-mechanical indexes (CNDO/2, MNDO, AM1 methods) and of pure structural parameters reckoned by means of graph theory.

TL;DR: In this paper, the number and type of complex species present in solution and their stability constants were calculated using the polarographic method in aqueous and ethanolic solution, and the results indicated an amino acid coordination to the metal ion through different coordination sites in solvents examined.

TL;DR: In this paper, the overall reduction process on an Hg electrode depends on the protonicity of the solvent and on the number of substituents on the N1 nitrogen (mono- or disubstituted).

TL;DR: The electrochemical reduction of OSO 2 NH 2 and its ortho, para and meta amino derivatives was examined in aprotic medium (CH 3 CN) with varying experimental conditions, i.e. drop time, concentration and temperature.