It is well known that urbanization and industrialization have resulted in the rapidly increasing emissions of volatile organic compounds (VOCs), which are a major contributor to the formation of secondary pollutants (e.g., tropospheric ozone, PAN (peroxyacetyl nitrate), and secondary organic aerosols) and photochemical smog. The emission of these pollutants has led to a large decline in air quality in numerous regions around the world, which has ultimately led to concerns regarding their impact on human health and general well-being. Catalytic oxidation is regarded as one of the most promising strategies for VOC removal from industrial waste streams. This Review systematically documents the progresses and developments made in the understanding and design of heterogeneous catalysts for VOC oxidation over the past two decades. It addresses in detail how catalytic performance is often drastically affected by the pollutant sources and reaction conditions. It also highlights the primary routes for catalyst deactivation and discusses protocols for their subsequent reactivation. Kinetic models and proposed oxidation mechanisms for representative VOCs are also provided. Typical catalytic reactors and oxidizers for industrial VOC destruction are further discussed. We believe that this Review will provide a great foundation and reference point for future design and development in this field.

/pdf/recent-advances-in-the-catalytic-oxidation-of-volatile-zw2c35dbg7.pdf

Recent Advances in the Catalytic Oxidation of Volatile Organic Compounds: A Review Based on Pollutant Sorts and Sources.

Impact of alcohol–gasoline fuel blends on the performance and combustion characteristics of an SI engine

Impact of alcohol-gasoline fuel blends on the exhaust emission of an SI engine

The effect of compression ratio on the performance, emissions and combustion of an SI (spark ignition) engine fueled with pure ethanol, methanol and unleaded gasoline

The use of pure methanol as fuel at high compression ratio in a single cylinder gasoline engine

Three typical methanol−gasoline blends M10, M20, and M85 containing 10%, 20%, and 85% of methanol by volume, respectively, were used to investigate the effects of different methanol/gasoline ratios on engine power, thermal efficiency, and emissions, especially the exhaust methanol emission. A three-cylinder, port fuel injection engine was applied. Experimental results show that the engine power/torque ratio under the wide open throttle condition mainly depends on the amount of heat delivered to the engine. The addition of methanol significantly improves the brake thermal efficiency, while the methanol/gasoline ratio has a slight effect on it. Engine out CO and NOx emissions decrease with the increase of the methanol/gasoline ratio. The use of M85 leads to a reduction of CO and NOx by about 25% and 80%, respectively. A gas chromatograph is calibrated and used to measure the methanol emission. Measurement indicates that the addition of methanol in gasoline results in an increase of the unburnt CH3OH emissio...

Li Hongsong

Papers

Effects of Methanol/Gasoline Blends on a Spark Ignition Engine Performance and Emissions