Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

Phd by thesis

____ : ..... '"i-t.-

A delamination mechanism for thermal barrier coatings subject to calcium-magnesium-alumino-silicate (CMAS) infiltration

Utilization of polymers as biomaterials has greatly impacted the advancement of modern medicine. Specifically, polymeric biomaterials that are biodegradable provide the significant advantage of being able to be broken down and removed after they have served their function. Applications are wide ranging with degradable polymers being used clinically as surgical sutures and implants. To fit functional demand, materials with desired physical, chemical, biological, biomechanical, and degradation properties must be selected. Fortunately, a wide range of natural and synthetic degradable polymers has been investigated for biomedical applications with novel materials constantly being developed to meet new challenges. This review summarizes the most recent advances in the field over the past 4 years, specifically highlighting new and interesting discoveries in tissue engineering and drug delivery applications.

Biomedical applications of biodegradable polymers

Materials Science and Technology

Discrete dislocation dynamics modelling of mechanical deformation of nickel-based single crystal superalloys

A micromechanical study of residual stress and its effect on transverse failure in polymer–matrix composites

Process-induced residual stress in fibre-reinforced thermoset polymer–matrix composites was analysed using a thermo-viscoelastic micromechanical model and the finite element method. A three-dimensional unit cell with glass fibre and epoxy polymer–matrix, representing the periodic microstructure of unidirectional fibre-reinforced composites, was considered to compute cure residual stress of fibre composites induced by chemical shrinkage of the epoxy resin and thermal cooling contraction of the whole fibre and resin system. The constitutive behaviour of the epoxy matrix was described by a cure and temperature-dependent viscoelastic material model. Compared to an elasticity solution, a reduction in residual stress was predicted due to the stress-relaxation caused by the viscoelastic behaviour of the epoxy matrix. Calculated residual stress shows strong dependency on the fibre volume fraction and fibre packing. After the cure process is complete, residual stress tends to relax to a constant value. The effect of residual stress on damage and failure of the model was also studied using the maximum stress failure criterion combined with a post-failure stiffness reduction technique. Damage onset, in terms of the location and the load level, was shown to be clearly influenced by the residual stress for both normal and shear loading. Initial and final failure envelopes, predicted for biaxial normal (longitudinal and transverse) loading and combined shear (longitudinal) and normal (transverse) loading, were shown to be shifted and contracted by the inclusion of residual stress. For final failure, residual stress was seen to have little effect on the load levels for longitudinal failure but greatly affected the load levels for transverse and shear failure. Residual stress could be detrimental or beneficial depending on the state of existing residual stress and the loading conditions.

A thermo-viscoelastic analysis of process-induced residual stress in fibre-reinforced polymer–matrix composites

The evolution of the stress-strain fields near a stationary crack tip under cyclic loading at selected R-ratios has been studied in a detailed elastic-plastic finite element analysis. The material behaviour was described by a full constitutive model of cyclic plasticity with both kinematic and isotropic hardening variables. Whilst the stress/strain range remains mostly constant during the cyclic loading and scales with the external load range, progressive accumulation of tensile strain occurs, particularly at high R-ratios. These results may be of significance for the characterization of crack growth, particularly near the fatigue threshold. Elastic-plastic finite element simulations of advancing fatigue cracks were carried out under plane-stress, plane-strain and generalized plane-strain conditions in a compact tension specimen. Physical contact of the crack flanks was observed in plane stress but not in the plane-strain and generalized plane-strain conditions. The lack of crack closure in plane strain was found to be independent of the material studied. Significant crack closure was observed under plane-stress conditions, where a displacement method was used to obtain the actual stress intensity variation during a loading cycle in the presence of crack closure. The results reveal no direct correlation between the attenuation in the stress intensity factor range estimated by the conventional compliance method and that determined by the displacement method. This finding seems to cast some doubts on the validity of the current practice in crack-closure measurement, and indeed on the role of plasticity-induced crack closure in the reduction of the applied stress intensity factor range.

Liguo Zhao

Papers

Discrete dislocation dynamics modelling of mechanical deformation of nickel-based single crystal superalloys

A micromechanical study of residual stress and its effect on transverse failure in polymer–matrix composites

A thermo-viscoelastic analysis of process-induced residual stress in fibre-reinforced polymer–matrix composites

The evolution of the stress–strain fields near a fatigue crack tip and plasticity‐induced crack closure revisited

A crystal plasticity study of cyclic constitutive behaviour, crack-tip deformation and crack-growth path for a polycrystalline nickel-based superalloy