Review of the application of gasification and combustion technology and waste-to-energy technologies in sewage sludge treatment

The growing volume of municipal solid waste (MSW) generated worldwide often undergoes open dumping, landfilling, or uncontrolled burning, releasing massive pollutants and pathogens into the soil, water, and air. On the other hand, MSW can be used as a valuable feedstock in biological and thermochemical conversion processes to produce bioenergy carriers, biofuels, and biochemicals in line with the United Nations’ Sustainable Development Goals (SDGs). Valorizing MSW using advanced technologies is highly energy-intensive and chemical-consuming. Therefore, robust and holistic sustainability assessment tools should be considered in the design, construction, and operation phases of MSW treatment technologies. Exergy-based methods are promising tools for achieving SDGs due to their capability to locate, quantify, and comprehend the thermodynamic inefficiencies, cost losses, and environmental impacts of waste treatment systems. Therefore, the present review paper aims to comprehensively summarize and critically discuss the use of exergetic indicators for the sustainability assessment of MSW treatment systems. Generally, consolidating thermochemical processes (mainly incineration and gasification) with material recycling methods (plastic waste recovery), heat and power plants (steam turbine cycle and organic Rankine cycle), modern power technologies (fuel cells), and carbon capture and sequestration processes could improve the exergetic performance of MSW treatment systems. Typically, the overall exergy efficiency values of integrated MSW treatment systems based on the incineration and gasification processes were found to be in the ranges of 17–40% and 22–56%, respectively. The syngas production through the plasma gasification process could be a highly favorable waste disposal technique due to its low residues and rapid conversion rate; however, it suffers from relatively low exergy efficiency resulting from its high torch power consumption. The overall exergy efficiency values of integrated anaerobic digestion-based MSW processing systems (34–73%) were generally higher than those based on the thermochemical processes. Exergy destruction and exergy efficiency were the most popular exergetic indicators used for decision-making in most published works. However, exergoeconomic and exergoenvironmental indices have rarely been used in the published literature to make decisions on the sustainability of waste treatment pathways. Future studies need to focus on developing and realizing integrated waste biorefinery systems using advanced exergy, exergoeconomic, and exergoenvironmental methods. 

Exergetic sustainability analysis of municipal solid waste treatment systems: A systematic critical review

Low-rank coal pyrolysis polygeneration technology with semi-coke heat carrier based on the dual-fluidized bed to co-produce electricity, oil and chemical products: Process simulation and techno-economic evaluation

Low-Rank Coal Pyrolysis Polygeneration Technology with Semi-Coke Heat Carrier Based on the Dual-Fluidized Bed to Co-Produce Electricity, Oil and Chemical Products: Process Simulation and Techno-Economic Evaluation

Experimental and kinetic study on the catalytic effect of AAEMs on coal char combustion under O2/CO2 atmospheres

Effects of alkali and alkaline earth metal species on the combustion characteristics and synergistic effects: Sewage sludge and its blend with coal.

Process simulation and comprehensive evaluation of a system of coal power plant coupled with waste incineration.

Two-phase heterostructures have received tremendous attention in energy-related fields as high-performance electrode materials. However, heterogeneous interfaces are usually constructed by introducing foreign elements, which disturbs the investigation of the intrinsic effect of the two-phase heterostructure. Herein, unique heterostructures constructed with orthorhombic NiSe2 and cubic NiSe2 phases are developed, which are embedded in in situ formed porous carbon from metal-organic frameworks (MOFs) (O/C-NiSe2@C). Precisely-controlled selenylation of MOFs is crucial for the formation of the O/C-NiSe2 heterostructure. The heterogeneous interfaces with lattice dislocations and charge distribution are conducive to the high-speed transfer of electrons and ions during electrochemical processes, so as to improve the electrochemical reaction kinetics for lithium-ion storage and the hydrogen evolution reaction (HER). When used as the anode of lithium-ion batteries (LIBs), O/C-NiSe2@C shows a superior electrochemical performance to the counterparts with only the cubic phase (C-NiSe2@C), in view of the cycling performance (719.3 mA h g-1 at 0.1 A g-1 for 100 cycles; 456.3 mA h g-1 at 1 A g-1 for 1000 cycles) and rate capabilities (344.8 mA h g-1 at 4 A g-1). Furthermore, O/C-NiSe2@C also exhibits better HER properties than C-NiSe2@C, that is, much lower overpotentials of 154 mV and 205 mV in 0.5 M H2SO4 and 1 M KOH, respectively, at 10 mA cm-2, a smaller Tafel slope as well as stable electrocatalytic activities for 2000 cycles/10 h. Preliminary observations indicate that the unique orthorhombic/cubic two-phase heterostructure could significantly improve the electrochemical performance of NiSe2 without additional modifications such as doping, suggesting the O/C-NiSe2 heterostructure as a promising bifunctional electrode for energy conversion and storage applications.

Lijuan Zhang

Papers

Effects of alkali and alkaline earth metal species on the combustion characteristics and synergistic effects: Sewage sludge and its blend with coal.

Process simulation and comprehensive evaluation of a system of coal power plant coupled with waste incineration.

A unique two-phase heterostructure with cubic NiSe2 and orthorhombic NiSe2 for enhanced lithium ion storage and electrocatalysis.

The study of co-combustion characteristics of coal and duckweed by single particle and TGA methods