Marine Carbon BiogeochemistryBiogeochemical Cycles and ClimateGlobal Biogeochemical Cycles in the Climate SystemOcean Dynamics and the Carbon CycleLive Long and EvolveBiogeochemistry of Marine Dissolved Organic MatterOcean Biogeochemical DynamicsMarine Ecosystems and Global ChangeBiological OceanographyNitrogen in the SeaBiogeochemistry of EstuariesInteractions of C, N, P and S Biogeochemical Cycles and Global ChangeGlobal EnvironmentComputational Science — ICCS 2004The Oceans and ClimateMarine Microbiome and Biogeochemical Cycles in Marine Productive AreasMetal Ions in Biological Systems, Volume 43 Biogeochemical Cycles of ElementsNitrogen in the Marine EnvironmentIntroduction to Marine BiogeochemistryOcean Circulation and ClimatePrimary Productivity and Biogeochemical Cycles in the SeaThe Biogeochemical Cycle of Silicon in the OceanChemical OceanographyTowards a Model of Ocean Biogeochemical ProcessesOcean Dynamics and the Carbon CycleOcean BiogeochemistryParticle Analysis in OceanographyBiogeochemical CyclesBiogeochemical Dynamics at Major River-Coastal InterfacesThe Ocean Carbon Cycle and ClimateSensitivity of global ocean biogeochemical dynamics to ecosystem structure in a future climateModeling Methods for Marine ScienceAn Introduction to the Chemistry of the SeaEncyclopedia of Ocean SciencesCO2 in Seawater: Equilibrium, Kinetics, IsotopesThe Biogeochemical Cycle of Silicon in the OceanKuroshio CurrentThe Mediterranean Sea in the Era of Global Change 1Ocean Biogeochemical DynamicsOcean Mixing

Ocean Biogeochemical Dynamics

In tissue engineering, three-dimensional (3D) printing is an emerging approach to producing functioning tissue constructs to repair wounds and repair or replace sick tissue/organs. It allows for precise control of materials and other components in the tissue constructs in an automated way, potentially permitting great throughput production. An ink made using one or multiple biomaterials can be 3D printed into tissue constructs by the printing process; though promising in tissue engineering, the printed constructs have also been reported to have the ability to lead to the emergence of unforeseen illnesses and failure due to biomaterial-related infections. Numerous approaches and/or strategies have been developed to combat biomaterial-related infections, and among them, natural biomaterials, surface treatment of biomaterials, and incorporating inorganic agents have been widely employed for the construct fabrication by 3D printing. Despite various attempts to synthesize and/or optimize the inks for 3D printing, the incidence of infection in the implanted tissue constructs remains one of the most significant issues. For the first time, here we present an overview of inks with antibacterial properties for 3D printing, focusing on the principles and strategies to accomplish biomaterials with anti-infective properties, and the synthesis of metallic ion-containing ink, chitosan-containing inks, and other antibacterial inks. Related discussions regarding the mechanics of biofilm formation and antibacterial performance are also presented, along with future perspectives of the importance of developing printable inks.

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A Review on Antibacterial Biomaterials in Biomedical Applications: From Materials Perspective to Bioinks Design

The Arctic Ocean has experienced rapid warming and sea ice loss in recent decades, becoming the first open-ocean basin to experience widespread aragonite undersaturation [saturation state of aragonite (Ωarag) < 1]. However, its trend toward long-term ocean acidification and the underlying mechanisms remain undocumented. Here, we report rapid acidification there, with rates three to four times higher than in other ocean basins, and attribute it to changing sea ice coverage on a decadal time scale. Sea ice melt exposes seawater to the atmosphere and promotes rapid uptake of atmospheric carbon dioxide, lowering its alkalinity and buffer capacity and thus leading to sharp declines in pH and Ωarag. We predict a further decrease in pH, particularly at higher latitudes where sea ice retreat is active, whereas Arctic warming may counteract decreases in Ωarag in the future. Description Acceleration in the Arctic The Arctic is warming at a rate faster than any comparable region on Earth, with a consequently rapid loss of sea ice there. Qi et al. found that this sea ice loss is causing more uptake of atmospheric carbon dioxide by surface water and driving rapid acidification of the western Arctic Ocean, at a rate three to four times higher than that of the other ocean basins. They attribute this finding to melt-driven addition of freshwater and the resulting changes in seawater chemistry. —HJS The western Arctic Ocean is rapidly acidifying due to sea ice loss.

Climate change drives rapid decadal acidification in the Arctic Ocean from 1994 to 2020

China’s Recent Progresses in Polar Climate Change and Its Interactions with the Global Climate System

Recent studies suggest that the formation and motion of the North Pacific subtropical mode water (STMW) play an important role in oceanic uptake, transport and storage of anthropogenic CO2 (CANT). However, the variability of STMW acidification rate and its control mechanisms remain unclear. Here we show that the STMW acidification rate during 2005–2020 is about two times of that during 1993–2005, which is due to the cooling‐driven enhanced CANT accumulation in the formation waters in the recent period. The rapid rates of CANT accumulation and acidification are consistently observed in the entire region across 137°–149°E regulated by STMW transport. Moreover, the tracer‐based (Δ14C and δ13C) analyses also indicate that the accelerated accumulation of CANT could be traced back to the surface formation waters via STMW formation. The vertical and horizontal consistencies imply the memory function of mode waters in retaining the anthropogenic carbon fingerprint during its formation and transport.

Accelerated Accumulation of Anthropogenic CO2 Drives Rapid Acidification in the North Pacific Subtropical Mode Water During 1993–2020

Contrasting Controls of Acidification Metrics Across Environmental Gradients in the North Pacific and the Adjunct Arctic Ocean: Insight From a Transregional Study

To address trade-off and membrane-fouling challenges during the development of nanofiltration membranes, a thin-film composite membrane was prepared on the basis of interfacial polymerization regulated by adjusting the capsaicin-derived self-polymer poly N-(2-hydroxy-5-(methylthio) benzyl) acrylamide (PHMTBA) on the polysulfone substrate in this study. Through the self-polymerization of the monomer HMTBA with varied contents, microwave-assisted technology was employed to develop a variety of PHMTBAs. It was discovered that PHMTBA is involved in the interfacial polymerization process. Piperazine and PHMTBA competed for the reaction with trimesoyl chloride, resulting in a flatter and looser membrane surface. The PHMTBA-modified membrane presented a typical double-layer structure: a thicker support layer and a thinner active layer. The addition of PHMTBA to membranes improved their hydrophilicity and negative charge density. As a result, the PHMTBA-modified membrane showed dependable separation performance (water flux of 159.5 L m−2 h−1 and rejection of 99.02% for Na2SO4) as well as enhanced anti-fouling properties (flux recovery ratio of more than 100% with bovine serum albumin-fouling and antibacterial efficiency of 93.7% against Escherichia coli). The performance of the prepared membranes was superior to that of most other modified TFC NF membranes previously reported in the literature. This work presents the application potential of capsaicin derivatives in water treatment and desalination processes.

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Lu Cao

Papers

Contrasting Controls of Acidification Metrics Across Environmental Gradients in the North Pacific and the Adjunct Arctic Ocean: Insight From a Transregional Study

Dependable Performance of Thin Film Composite Nanofiltration Membrane Tailored by Capsaicin-Derived Self-Polymer