Most PET bottles used as beverage containers become waste after their usage, causing environmental problems. To address this issue, a method to recycle wasted PET bottles is presented, in which short fibers made from recycled PET are used within structural concrete. To verify the performance capacity of recycled PET fiber reinforced concrete, it was compared with that of polypropylene (PP) fiber reinforced concrete for fiber volume fractions of 0.5%, 0.75%, and 1.0%. Appropriate tests were performed to measure material properties such as compressive strength, elastic modulus, and restrained drying shrinkage strain. Flexural tests were performed to measure the strength and ductility capacities of reinforced concrete (RC) members cast with recycled PET fiber reinforced concrete. The results show that compressive strength and elastic modulus both decreased as fiber volume fraction increased. Cracking due to drying shrinkage was delayed in the PET fiber reinforced concrete specimens, compared to such cracking in non-reinforced specimens without fiber reinforcement (NF), which indicates crack controlling and bridging characteristics of the recycled PET fibers. Regarding structural member performance, ultimate strength and relative ductility of PET fiber reinforced RC beams are significantly larger than those of companion specimens without fiber reinforcement.

Material and structural performance evaluation of recycled pet fiber reinforced concrete

Natural zeolite, a type of frame-structured hydrated aluminosilicate mineral, is used abundantly as a type of natural pozzolanic material in some regions of the world. In this work, the effectiveness of a locally quarried zeolite in enhancing mechanical and durability properties of concrete is evaluated and is also compared with other pozzolanic admixtures. The experimental tests included three parts: In the first part, the pozzolanic reactivity of natural zeolite and silica fume were examined by a thermogravimetric method. In this case, the results indicated that natural zeolite was not as reactive as silica fume but it showed a good pozzolanic reactivity. In the second part, zeolite and silica fume were substituted for cement in different proportions in concrete mixtures, and several physical and durability tests of concrete were performed. These experimental tests included slump, compressive strength, water absorption, oxygen permeability, chloride diffusion, and electrical resistivity of concrete. Based on these results, the performance of concretes containing different contents of zeolite improved and even were comparable to or better than that of concretes prepared with silica fume replacements in some cases. Finally, a comparative study on effect of zeolite and fly ash on limiting ASR expansion of mortar was performed according to ASTM C 1260 and ASTM C 1567. Expansion tests on mortar prisms showed that zeolite is as effective as fly ash to prevent deleterious expansion due to ASR.

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Use of natural zeolite as a supplementary cementitious material

We describe a method that can be used to produce concrete-reinforcing PET fiber from used PET bottles. Using this method, the concrete and PET fibers are easily mixed at a fiber contents as high as 3%. The primary characteristic of the PET fiber is that it is easy to handle. The issue of concern in the development of PET fiber is its alkali resistance; however, we encountered no problems when using the fiber in normal concrete. The wetting tension of PET was found to be lower than that of PVA but higher than that of PP. No toxic gas was generated during a combustion test of the PET fiber. We describe two example applications: a gateway support at Hishikari Mine, Japan, and the pavement of bush roads.

Development of recycled PET fiber and its application as concrete-reinforcing fiber

The current widespread use of calcium silicate or aluminate hydrate binder systems in the construction industry finds its roots in the Antique world where mixtures of calcined lime and finely ground reactive (alumino-)silicate materials were pioneered and developed as competent inorganic binders. Architectural remains of the Minoan civilization (2000-1500 BC) on Crete have shown evidence of the combined use of slaked lime and additions of finely ground potsherds to produce stronger and more durable lime mortars suitable for water-proof renderings in baths, cisterns and aqueducts (Spence and Cook 1983). It is not clear when and where mortar technology evolved to incorporate volcanic pumice and ashes as a functional supplement. A plausible site would be the Akrotiri settlement at Santorin (Greece), where archeological indications of strong ties with the Minoan culture were found and large quantities of suitable highly siliceous volcanic ash were present. This so-called Santorin earth has been used as a pozzolan in the Eastern Mediterranean until recently (Kitsopoulos and Dunham 1996). Evidence of the deliberate use of this and other volcanic materials by the ancient Greeks dates back to at least 500-400 BC, as uncovered at the ancient city of Kamiros, Rhodes (Efstathiadis 1978; Idorn 1997). In the subsequent centuries the technological knowledge was spread to the mainland (Papayianni and Stefanidou 2007) and was eventually adopted and improved by the Romans (Mehta 1987). The Roman alternatives for Santorin earth were volcanic pumices or tuff found in neighboring territories, the most famous ones found in Pozzuoli (Naples), hence the name pozzolan, and in Segni (Latium). Preference was given to natural pozzolan sources, but crushed ceramic waste was frequently used when natural deposits were not locally available. The exceptional lifetime and preservation condition of some of the most famous Roman buildings such as the Pantheon or the Pont du …

Supplementary Cementitious Materials

Use of macro plastic fibres in concrete: A review

http://users.metu.edu.tr/mcgoncu/papers/Uzal-2010.pdf

Pozzolanic activity of clinoptilolite: A comparative study with silica fume, fly ash and a non-zeolitic natural pozzolan

Use of ground clay brick as a pozzolanic material to reduce the alkali-silica reaction

Effect of large amounts of natural pozzolan addition on properties of blended cements

In this study, properties and hydration characteristics as well as paste microstructure of blended cements containing 55% by weight zeolitic tuff composed mainly of clinoptilolite mineral were investigated. Free Ca(OH)2 content, crystalline hydration products and decomposition of zeolite crystal structure, pore size distribution and microstructural architecture of hydrated cement pastes were examined. Superplasticizer requirement and compressive strength development of blended cement mortars were also determined. The blended cements containing high volume of natural zeolites were characterized with the following properties; (i) no free Ca(OH)2 in hardened pastes at the end of 28 days of hydration, (ii) less proportion of the pores larger than 50 nm when compared to portland cement paste, (iii) complete decomposition of crystal structure of zeolite at the end of 28 days of hydration, (iv) presence of tetra calcium aluminate hydrate as a crystalline product of pozzolanic reaction, (v) more compatibility with the melamine-based superplasticizer when compared to the naphthalene based product, and (vi) similar 28 days compressive strength of mortars to that of reference portland cement.

Lutfullah Turanli

Papers

Pozzolanic activity of clinoptilolite: A comparative study with silica fume, fly ash and a non-zeolitic natural pozzolan

Use of ground clay brick as a pozzolanic material to reduce the alkali-silica reaction

Effect of large amounts of natural pozzolan addition on properties of blended cements

Blended cements containing high volume of natural zeolites: Properties, hydration and paste microstructure

Studies on blended cements containing a high volume of natural pozzolans