Applications of the dicarbollylcobaltate(III) anion in the water/nitrobenzene extraction system.

C-arylation and C-heteroarylation of icosahedral carboranes via their copper(I) derivatives

Using 1H and 13C NMR, FT IR spectroscopy together with quantum mechanical DFT calculations, we show that tetraethyl p-tert-butylcalix[4]arene tetraacetate (1) forms a stable equimolecular complex with proton in the form of hydroxonium ion in acetonitrile-d 3. Protons for this complex were offered by hydrogen bis(1,2-dicarbollyl) cobaltate (HDCC) and converted to hydroxonium ions by traces of water. The complex 1·H3O+ adopts a slightly asymmetric conformation, which is distinctly more cone-like than ligand 1. According to spectral evidence, the hydroxonium ion H3O+ is bound mainly to three of the phenoxy oxygen atoms of 1 by strong hydrogen bonds leaving the ester carbonyl groups, which are the usual coordination site for metal cations, free. Theoretical DFT calculations support the bonding to phenoxy oxygen atoms but slightly prefer a structure with one of the carbonyls being involved in the coordination.

/pdf/experimental-evidence-for-unusual-protonation-of-tetraethyl-300vhjqkqp.pdf

Experimental Evidence for Unusual Protonation of Tetraethyl p-tert-Butylcalix[4]arene Tetraacetate and the Most Probable Structure of the Resulting Complex

M. Kyrš

Papers

Hydration of alkali metal cations and protons in polar organic solvents