Showing papers in "Journal of Inorganic and Nuclear Chemistry in 1979"
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TL;DR: The intercalation of n -propylamine, n -butylamine and ethylenediamine by the layered compound α-zirconium phosphate has been examined in this paper.
115 citations
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TL;DR: In this article, the crystal structure of tetrameric Al(OPr-iso) 3 has been determined by single crystal X-ray diffraction and a strucrural model of the polymerization equilibrium is suggested.
109 citations
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TL;DR: In this paper, the formation region of γ-zirconium phosphate (γ-ZrP) was determined by using zircinium phosphate gels heated in phosphate solutions with various pH values.
108 citations
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TL;DR: In this paper, the cobalt(II,III) oxide, Co3O4, was obtained by heating cobalt acetate solutions (10−3-10−2 M) at ∼100°C for a few hours.
82 citations
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TL;DR: Several complexes of palladium and nickel have been synthesized and subjected to a variety of in vitro/in vivo screens, and the most toxic complexes were (πC 3 H 5 PdCl) 2 and Ni(py) 4 (NCO) 2 as discussed by the authors.
80 citations
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63 citations
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TL;DR: In this paper, the reaction sequences mackinawite → (greigite) → pyrrhotite (pyrrhhotite), and troilite → polygonal (polygonal) pyrhotite → pyramids of pyrite have been established by X-ray powder diffractometry.
62 citations
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TL;DR: In this article, the influence of sulfate ions on the formation of an iron(III) oxide phase of colloidal size was studied by homogeneous titration of acidified iron (III) solutions with varying SO4/Fe ratios (0−2.4).
61 citations
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TL;DR: In this paper, the distribution ratios for nitric acid, actinides, fission products and corrosion products between PUREX HLW-solution and 50% tributylphosphate in an aliphatic diluent have been investigated in the range 0.1-6 M.
59 citations
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TL;DR: In this paper, the IR patterns of EuB4O7, Eu2B2O4, and eu2b2O5 were attributed to a three-dimensional network of BO4-tetrahedra, an endless chain of BO3 groups, and a B2O54− ion, respectively.
57 citations
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TL;DR: In this article, the crystal structure of Ti(HPO4)2·2H2O has been derived from the formation of intercalation compounds, X-ray powder patterns and density measurements, as well as from comparison with several acid salts of tetravalent metals.
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TL;DR: In this article, the extraction of titanium(IV), iron(III) and iron(II) by di-2-ethyl hexyl phosphoric acid in benzene has been studied as a function of contact time, the concentration of the extractant in the organic phase, the temperature, etc.
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TL;DR: In this article, the formation of these complexes obeys the law of mass action, contrary to previous interpretations, and a critical discussion of the different interpretations is proposed, which is based on the outer-sphere type.
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TL;DR: In this paper, the results indicate that the coordination sites strongly depend upon the pH of the solutions and the stoichiometry of the metal to ligand ratio, and suggested possible structures of the isolated complexes with respect to their IR spectra.
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TL;DR: In this article, the isotherms for hydrogen ion/alkali metal ions have been measured at 20 and 40°C, with a solution ionic strength of 0.1, in crystalline antimonic(V) acid as a cation-exchanger.
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TL;DR: In this article, the width parameter of the Gaussian charge distribution and the empirical most probable charge Zp for light and heavy fragments are obtained by treating experimental fractional cumulative yields.
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TL;DR: The structure of the title compound, UO2(CH2COO)2·H2O, has been determined from three-dimensional X-ray data as discussed by the authors.
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TL;DR: In this paper, the cubic form of indium trihydroxide was obtained by hydrothermal methods at varied concentrations and temperatures. But the final refinement based on 106 independent reflections yields a conventional R value of 1.48%.
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TL;DR: Tris(indole 3-acetates) and tris(tricyclic acid 3-butyrates) of lanthanum, praseodymium and samarium were prepared and characterized by elemental analysis, electronic and IR measurements as mentioned in this paper.
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TL;DR: In this paper, the equilibria of dioxouranium (VI) and carbonate ions in acid solution (log [H+] > −5) have been studied at 25°C by measuring, with a glass electrode, the hydrogen ion concentration of a series of UO2−2+ perchlorate solutions, saturated with CO2(g) at known partial pressure.
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TL;DR: In this article, the authors used a pre-equilibrium process to explain the observed isomer ratios in 93 Tc 96 Tc from the reactions 93 Nb( α, xn ) with a statistically-equilibrated compound nucleus.
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TL;DR: In this paper, the formation of the fluoro complexes of rare earth elements (REE) has been studied in 1 M NaCl-aqueous medium at 25°C and pH-rang ⩽ 5.
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TL;DR: The synthesis, thermal behaviour and crystal structure of lithium glutaratehydrogenglutaratedioxouranate (VI) tetrahydrate was described in this article, where the carboxylic groups were chelated on the uranium and monodentate on the lithium.
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TL;DR: In this paper, the 1:1 adduct UCl3(THF) has been isolated from a solution of trichloride and shown to react with NaH to yield UCl 3 (THFx)x. Unlike the parent material, this material is soluble in THF enabling the study of a variety of reactions.
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TL;DR: In this paper, the spectral properties of vanadium-IV complexes formed in the extractions by tricaprylmethylammonium chloride (R 3 R′NCl; Aliquat-336), tri-n -octylamine (R3 N; TOA), tri -n-octylphosphine oxide (TOPSOPO; TOPO) and tri- n -butylphophosphate ((RO) 3 PO: TBP) in benzene from either hydrochloric acid solutions or mixed solutions of hydrochlor
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TL;DR: In this article, the reaction between Zn(II) ion and the peripherally positively charged tetra-(p-trimethylammoniumphenyl)porphyrin (H2TAPP) was investigated at 30°C and 0.5°F ionic strength (NaNO3).
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TL;DR: In this article, two series of rare earth compounds of the anion 2-thiopyridine Noxide have been isolated and characterized (i.e. Ln = La, Pr, Sm, Eu, Tb and Er).
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TL;DR: The lattice constants for the trihydroxides of Pr, Er and Tm are a 0 = 6.456(1), 6.352(1, and 6.769(1) A and c 0 = 3.503(2) A.