We present models for the optical functions of 11 metals used as mirrors and contacts in optoelectronic and optical devices: noble metals (Ag, Au, Cu), aluminum, beryllium, and transition metals (Cr, Ni, Pd, Pt, Ti, W). We used two simple phenomenological models, the Lorentz-Drude (LD) and the Brendel-Bormann (BB), to interpret both the free-electron and the interband parts of the dielectric response of metals in a wide spectral range from 0.1 to 6 eV. Our results show that the BB model was needed to describe appropriately the interband absorption in noble metals, while for Al, Be, and the transition metals both models exhibit good agreement with the experimental data. A comparison with measurements on surface normal structures confirmed that the reflectance and the phase change on reflection from semiconductor-metal interfaces (including the case of metallic multilayers) can be accurately described by use of the proposed models for the optical functions of metallic films and the matrix method for multilayer calculations.

Optical properties of metallic films for vertical-cavity optoelectronic devices.

http://nathan.instras.com/documentDB/paper-69.pdf

Porous silicon: a quantum sponge structure for silicon based optoelectronics

Optical coatings usually consist of many multilayers of thin films to achieve the desired properties A new approach using interference effects between an absorbing dielectric film and a metallic substrate now enables ultrathin optical coatings that could also find applications as thin solar cells or photodetectors

Nanometre optical coatings based on strong interference effects in highly absorbing media

There is an increasing interest in using graphene(1, 2) for optoelectronic applications.(3-19) However, because graphene is an inherently weak optical absorber (only ≈2.3% absorption), novel concepts need to be developed to increase the absorption and take full advantage of its unique optical properties. We demonstrate that by monolithically integrating graphene with a Fabry-Perot microcavity, the optical absorption is 26-fold enhanced, reaching values >60%. We present a graphene-based microcavity photodetector with responsivity of 21 mA/W. Our approach can be applied to a variety of other graphene devices, such as electro-absorption modulators, variable optical attenuators, or light emitters, and provides a new route to graphene photonics with the potential for applications in communications, security, sensing and spectroscopy.

http://pubs.acs.org/doi/pdf/10.1021/nl204512x

Microcavity-Integrated Graphene Photodetector

The modification and control of exciton–photon interactions in semiconductors is of both fundamental1,2,3,4 and practical interest, being of direct relevance to the design of improved light-emitting diodes, photodetectors and lasers5,6,7. In a semiconductor microcavity, the confined electromagnetic field modifies the optical transitions of the material. Two distinct types of interaction are possible: weak and strong coupling1,2,3,4. In the former perturbative regime, the spectral and spatial distribution of the emission is modified but exciton dynamics are little altered. In the latter case, however, mixing of exciton and photon states occurs leading to strongly modified dynamics. Both types of effect have been observed in planar microcavity structures in inorganic semiconductor quantum wells and bulk layers1,2,3,4,5,6,7,8. But organic semiconductor microcavities have been studied only in the weak-coupling regime9,10,11,12,13,14,15,16,17,18. Here we report an organic semiconductor microcavity that operates in the strong-coupling regime. We see characteristic mixing of the exciton and photon modes (anti-crossing), and a room-temperature vacuum Rabi splitting (an indicator of interaction strength) that is an order of magnitude larger than the previously reported highest values for inorganic semiconductors. Our results may lead to new structures and device concepts incorporating hybrid states of organic and inorganic excitons19, and suggest that polariton lasing20,21,22 may be possible.

Strong exciton–photon coupling in an organic semiconductor microcavity

We review the family of optoelectronic devices whose performance is enhanced by placing the active device structure inside a Fabry‐Perot resonantmicrocavity. Such resonantcavity enhanced (RCE) devices benefit from the wavelength selectivity and the large increase of the resonant optical field introduced by the cavity. The increased optical field allows RCE photodetector structures to be thinner and therefore faster, while simultaneously increasing the quantum efficiency at the resonant wavelengths. Off‐resonance wavelengths are rejected by the cavity making RCE photodetectors promising for low crosstalk wavelength division multiplexing(WDM) applications. RCE optical modulators require fewer quantum wells so are capable of reduced voltage operation. The spontaneous emission spectrum of RCE light emitting diodes(LED) is drastically altered, improving the spectral purity and directivity. RCE devices are also highly suitable for integrated detectors and emitters with applications as in optical logic and in communication networks. This review attempts an encyclopedic overview of RCE photonicdevices and systems. Considerable attention is devoted to the theoretical formulation and calculation of important RCE device parameters. Materials criteria are outlined and the suitability of common heteroepitaxial systems for RCE devices is examined. Arguments for the improved bandwidth in RCE detectors are presented intuitively, and results from advanced numerical simulations confirming the simple model are provided. An overview of experimental results on discrete RCE photodiodes, phototransistors, modulators, and LEDs is given. Work aimed at integrated RCE devices,optical logic and WDM systems is also covered. We conclude by speculating what remains to be accomplished to implement a practical RCE WDM system.

M. Selim Ünlü

Papers

Resonant cavity enhanced photonic devices