Electrochemical behaviour of 2,4-dinitrophenylhydrazi(o)ne as multi-redox centre DNA label at mercury meniscus modified silver solid amalgam electrode

Preparation of Organomercury Compounds

1.

A comparative investigation was made of two methods for the synthesis of organomercury compounds — the diazoaliphatic method and the oxidation of hydrazone complexes of mercuric halides with mercuric oxide — for the case of 2,3-bornanedione and benzil derivatives.




2.

In the case of 2,3-bornanedione both methods lead to the formation of the same types of organomercury compound in approximately the same yields.




3.

In the case of benzil the method of synthesizing organomercury compounds by the oxidation of complexes formed by the monohydrazone with mercuric halides is inapplicable.

Interaction of hydrazones and azines with metal salts Communication 7. Comparative investigation of the diazoaliphatic and hydrazone methods for the synthesis of organomercury compounds

1.

The oxidation of mercuric halide complexes of alicyclic and aliphatic hydrazones with yellow mercuric oxide leads to the formation of organomercury compounds whose structures depend on the oxidation medium.




2.

A new method was developed for the synthesis of organomercury compounds from complexes of acetaldehyde, acetone, cyclopentanone, cyclohexanone, and camphor hydrazones.

M. Ya. Aleinikova

Papers

Interaction of hydrazones and azines with metal salts Communication 7. Comparative investigation of the diazoaliphatic and hydrazone methods for the synthesis of organomercury compounds

Reactions of hydrazones and azines with metal salts Communication 6. Synthesis of organomercury compounds from mercuric halide complexes of hydrazones

Complexes of azines and hydrazones with mercury halides