A possible sighting of Majorana states Nearly 80 years ago, the Italian physicist Ettore Majorana proposed the existence of an unusual type of particle that is its own antiparticle, the so-called Majorana fermion. The search for a free Majorana fermion has so far been unsuccessful, but bound Majorana-like collective excitations may exist in certain exotic superconductors. Nadj-Perge et al. created such a topological superconductor by depositing iron atoms onto the surface of superconducting lead, forming atomic chains (see the Perspective by Lee). They then used a scanning tunneling microscope to observe enhanced conductance at the ends of these chains at zero energy, where theory predicts Majorana states should appear. Science, this issue p. 602; see also p. 547 Scanning tunneling microscopy is used to observe signatures of Majorana states at the ends of iron atom chains. [Also see Perspective by Lee] Majorana fermions are predicted to localize at the edge of a topological superconductor, a state of matter that can form when a ferromagnetic system is placed in proximity to a conventional superconductor with strong spin-orbit interaction. With the goal of realizing a one-dimensional topological superconductor, we have fabricated ferromagnetic iron (Fe) atomic chains on the surface of superconducting lead (Pb). Using high-resolution spectroscopic imaging techniques, we show that the onset of superconductivity, which gaps the electronic density of states in the bulk of the Fe chains, is accompanied by the appearance of zero-energy end-states. This spatially resolved signature provides strong evidence, corroborated by other observations, for the formation of a topological phase and edge-bound Majorana fermions in our atomic chains.

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Observation of Majorana fermions in ferromagnetic atomic chains on a superconductor

A topological superconductor A promising path toward topological quantum computing involves exotic quasiparticles called the Majorana bound states (MBSs). MBSs have been observed in heterostructures that require careful nanofabrication, but the complexity of such systems makes further progress tricky. Zhang et al. identified a topological superconductor in which MBSs may be observed in a simpler way by looking into the cores of vortices induced by an external magnetic field. Using angle-resolved photoemission, the researchers found that the surface of the iron superconductor FeTe0.55Se0.45 satisfies the required conditions for topological superconductivity. Science, this issue p. 182 Angle-resolved photoemission spectroscopy indicates that FeTe0.55Se0.45 harbors Dirac-cone–type spin-helical surface states. Topological superconductors are predicted to host exotic Majorana states that obey non-Abelian statistics and can be used to implement a topological quantum computer. Most of the proposed topological superconductors are realized in difficult-to-fabricate heterostructures at very low temperatures. By using high-resolution spin-resolved and angle-resolved photoelectron spectroscopy, we find that the iron-based superconductor FeTe1–xSex (x = 0.45; superconducting transition temperature Tc = 14.5 kelvin) hosts Dirac-cone–type spin-helical surface states at the Fermi level; the surface states exhibit an s-wave superconducting gap below Tc. Our study shows that the surface states of FeTe0.55Se0.45 are topologically superconducting, providing a simple and possibly high-temperature platform for realizing Majorana states.

Observation of topological superconductivity on the surface of iron-based superconductor

I review recent works on the symmetry and the structure of the superconducting gap in Fe-based superconductors and on the underlying pairing mechanism in these systems. The experimental data on superconductivity show very rich behavior, with potentially different symmetry of a superconducting state for different compositions of the same material. The variety of different pairing states raised the issue whether the physics of Fe-based superconductors is model-dependent or is universal, governed by a single underlying pairing mechanism. I argue that the physics is universal and that all pairing states obtained so far can be understood within the same universal pairing scenario and are well described by the effective low-energy model with a small number of input parameters.

Pairing mechanism in Fe-based superconductors

The topological property of a gapped odd-parity superconductor is jointly determined by its pairing nodes and Fermi surfaces in the normal state. We reveal that the contractibility of Fermi surfaces without crossing any time-reversal invariant momentum and the presence of nontrivial Berry phase on Fermi surfaces are two key conditions for the realization of higher-order topological odd-parity superconductors. When the normal state is a normal metal, we reveal the necessity of removable Dirac pairing nodes and provide a general and simple principle to realize higher-order topological odd-parity superconductors. Our findings can be applied to design new platforms of higher-order topological superconductors, as well as higher-order topological insulators owing to their direct analogy in Hamiltonian description.

Higher-Order Topological Odd-Parity Superconductors.

We investigate higher-order Weyl semimetals (HOWSMs) having bulk Weyl nodes attached to both surface and hinge Fermi arcs We identify a new type of Weyl node, which we dub a 2nd-order Weyl node, that can be identified as a transition in momentum space in which both the Chern number and a higher order topological invariant change As a proof of concept we use a model of stacked higher order quadrupole insulators (QI) to identify three types of WSM phases: 1st order, 2nd order, and hybrid order The model can also realize type-II and hybrid-tilt WSMs with various surface and hinge arcs After a comprehensive analysis of the topological properties of various HOWSMs, we turn to their physical implications that show the very distinct behavior of 2nd-order Weyl nodes when they are gapped out We obtain three remarkable results: (i) the coupling of a 2nd-order Weyl phase with a conventional 1st-order one can lead to a hybrid-order topological insulator having coexisting surface cones and flat hinge arcs that are independent and not attached to each other (ii) A nested 2nd-order inversion-symmetric WSM by a charge-density wave (CDW) order generates an insulating phase having coexisting flatband surface and hinge states all over the Brillouin zone (iii) A CDW order in a time-reversal symmetric higher-order WSM gaps out a 2nd-order node with a 1st-order node and generates an insulating phase having coexisting surface Dirac cone and hinge arcs Moreover, we show that a measurement of charge density in the presence of magnetic flux can help to identify some classes of 2nd-order WSMs Finally, we show that periodic driving can be utilized as a way for generating HOWSMs Our results are relevant to metamaterials as well as various phases of ${\mathrm{Cd}}_{3}{\mathrm{As}}_{2}$, KMgBi, and rutile-structure ${\mathrm{PtO}}_{2}$ that have been predicted to realize higher order Dirac semimetals

Higher-Order Weyl Semimetals.

The combination of spin-orbit coupling with interactions results in many exotic phases of matter. In this Letter, we investigate the superconducting pairing instability of the two-dimensional extended Hubbard model with both Rashba and Dresselhaus spin-orbit coupling within the mean-field level at both zero and finite temperature. We find that both first- and second-order time-reversal symmetry breaking topological gapped phases can be achieved under appropriate parameters and temperature regimes due to the presence of a favored even-parity s+id-wave pairing even in the absence of an external magnetic field or intrinsic magnetism. This results in two branches of chiral Majorana edge states on each edge or a single zero-energy Majorana corner state at each corner of the sample. Interestingly, we also find that not only does tuning the doping level lead to a direct topological phase transition between these two distinct topological gapped phases, but also using the temperature as a highly controllable and reversible tuning knob leads to different direct temperature-driven topological phase transitions between gapped and gapless topological superconducting phases. Our findings suggest new possibilities in interacting spin-orbit coupled systems by unifying both first- and higher-order topological superconductors in a simple but realistic microscopic model.

First- and Second-Order Topological Superconductivity and Temperature-Driven Topological Phase Transitions in the Extended Hubbard Model with Spin-Orbit Coupling.

The band topology of a superconductor is known to have profound impact on the existence of Majorana zero modes in vortices. As iron-based superconductors with band inversion and ${s}_{\ifmmode\pm\else\textpm\fi{}}$-wave pairing can give rise to time-reversal invariant second-order topological superconductivity, manifested by the presence of helical Majorana hinge states in three dimensions, we are motivated to investigate the interplay between the second-order topology and the vortex lines in both weak- and strong-Zeeman-field regimes. In the weak-Zeeman-field regime, we find that vortex lines far away from the hinges are topologically nontrivial in the weakly doped regime, regardless of whether the second-order topology is present or not. However, when the superconductor falls into the second-order topological phase and a topological vortex line is moved close to the helical Majorana hinge states, we find that their hybridization will trivialize the vortex line and transfer robust Majorana zero modes to the hinges. Furthermore, when the Zeeman field is large enough, we find that the helical Majorana hinge states are changed into chiral Majorana hinge modes and thus a chiral second-order topological superconducting phase is realized. In this regime, the vortex lines are always topologically trivial, no matter how far away they are from the chiral Majorana hinge modes. By incorporating a realistic assumption of inhomogeneous superconductivity, our findings can explain the recent experimental observation of the peculiar coexistence and evolution of topologically nontrivial and trivial vortex lines in iron-based superconductors.

Vortex-line topology in iron-based superconductors with and without second-order topology

In this paper we find that confining a second-order topological superconductor with a harmonic potential leads to a proliferation of Majorana corner modes. As a consequence, this results in the formation of Majorana corner flat bands which have a fundamentally different origin from that of the conventional mechanism. This is due to the fact that they arise solely from the one-dimensional gapped boundary states of the hybrid system that become gapless without the bulk gap closing under the increase of the trapping potential magnitude. The Majorana corner states are found to be robust against the strength of the harmonic trap and the transition from Majorana corner states to Majorana flat bands is merely a smooth crossover. As a harmonic trap can potentially be realized in heterostructures, this proposal paves a way to observe these Majorana corner flat bands in an experimental context.

Majorana corner flat bands in two-dimensional second-order topological superconductors

Bound states at sharp corners have been widely viewed as the hallmark of two-dimensional second-order topological insulators and superconductors. In this work, we show that the existence of sublattice degrees of freedom can enrich the tunability of bound states on the boundary and hence lift the constraint on their locations. We take the Kane-Mele model with honeycomb-lattice structure to illustrate the underlying physics. With the introduction of an in-plane exchange field to the model, we find that the boundary Dirac mass induced by the exchange field has a sensitive dependence on the boundary sublattice termination. We find that the sensitive sublattice dependence can lead bound states to emerge at a specific type of boundary defects named as sublattice domain walls if the exchange field is of ferromagnetic nature, even in the absence of any sharp corner on the boundary. Remarkably, this sensitive dependence of the boundary Dirac mass on the boundary sublattice termination allows the positions of bound states to be manipulated to any place on the boundary for an appropriately-designed sample. With a further introduction of conventional s-wave superconductivity to the model, we find that, no matter whether the exchange field is ferromagnetic, antiferromagnetic, or ferrimagnetic, highly controllable Majorana zero modes can be achieved at the sublattice domain walls. Our work reshapes the understanding of boundary physics in second-order topological phases, and meanwhile opens potential avenues to realize highly controllable bound states for potential applications.

Sublattice-enriched tunability of bound states in second-order topological insulators and superconductors

In a ﬁrst-order topological phase with sublattice degrees of freedom, a change in the boundary sublattice termination has no eﬀect on the existence of gapless boundary states in dimensions higher than one. However, such a change may strongly aﬀect the physical properties of those boundary states. Motivated by this observation, we perform a systematic study of the impact of sublattice terminations on the boundary physics on the two-dimensional kagome lattice. We ﬁnd that the energies of the Dirac points of helical edge states in two-dimensional ﬁrst-order topological kagome insulators sensitively depend on the terminating sublattices at the edge. Remarkably, this property admits the realization of a time-reversal invariant second-order topological superconducting phase with highly controllable Majorana Kramers pairs at the corners and sublattice domain walls by putting the topological kagome insulator in proximity to a d -wave superconductor. Moreover, substituting the d -wave superconductor with a conventional s -wave superconductor, we ﬁnd that highly controllable Majorana zero modes can also be realized at the corners and sublattice domain walls if an in-plane Zeeman ﬁeld is additionally applied. Our study reveals promising platforms to implement highly controllable Majorana zero modes.

Majid Kheirkhah

Papers

First- and Second-Order Topological Superconductivity and Temperature-Driven Topological Phase Transitions in the Extended Hubbard Model with Spin-Orbit Coupling.

Vortex-line topology in iron-based superconductors with and without second-order topology

Majorana corner flat bands in two-dimensional second-order topological superconductors

Sublattice-enriched tunability of bound states in second-order topological insulators and superconductors

Corner- and sublattice-sensitive Majorana zero modes on the kagome lattice