Mariusz Michalczyk

TL;DR: Various types of σ-hole bond complexes were formed with FX, HFY, H2FZ, and H3FT as Lewis acid in order to examine their interactions with a protein, N-methylacetamide (NMA), a model of the peptide linkage was used as the base.

TL;DR: The monomer rearrangement aids in the binding by intensifying its σ-hole by a factor of 1.5-2.9, and the total reaction energy of binding is significantly lower than the interaction energy, although remaining quite high, particularly for the larger Sn and Sb central atoms.

TL;DR: In this article, a review summarizes the current state of knowledge about the complexes of anions with ligands that engage in these sorts of noncovalent bonds, and how the geometry of the fully coordinated complex varies as the number of surrounding ligands increases.

TL;DR: The σ-hole tetrel bonds formed by a tetravalent molecule are compared with those involving a π-hole above the tetrel atom in a trivalent bonding situation, and the former are modeled by TH4, TH3F, and TH2F2 and the latter by TH2=CH 2, THF=CH2, and TF2= CH2.

TL;DR: In the closed-shell clusters, the interaction energies are highly dependent upon the intensity of the MEP, but this correlation fades for the open-shell systems studied in this work, and the strength of the interaction is closely related to the basicity of the nucleophile.