Showing papers by "Martin L. Gorbaty published in 2002"

Characterization of Organically Bound Oxygen Forms in Lignites, Peats, and Pyrolyzed Peats by X-ray Photoelectron Spectroscopy (XPS) and Solid-State 13C NMR Methods

Abstract: A combination of XPS and solid-state 13C NMR techniques have been used to characterize organic oxygen species and carbon chemical/structural features in peats, pyrolyzed peats, lignites, and other coals. Both the 13C NMR and XPS results show the same ordering for the amount of aromatic carbon, higher ranking coals > lignites > peats. In general the value for H/C decreases as the percent of aromatic carbon increases. For pyrolyzed peats, the H/C level is higher than lignites and other coals of comparable levels of aromatic carbon. This is likely due to significant differences in the carbon structural framework of these materials. A van Krevelen plot, based on elemental H/C data and XPS derived O/C data, shows the well-established pattern for peats, lignites, and other coals. In general, O/C decreases as the percent of aromatic carbon increases, with the expected magnitude ordering, peats > lignites > higher ranking coals. Most of the H/C values of pyrolyzed peats are higher than coals at comparable O/C. A ...

Delayed coking process for producing anisotropic free-flowing shot coke

Abstract: A delayed coking process wherein substantially all of the coke produced is free-flowing anisotropic shot coke. A coker feedstock, such as a vacuum residuum, is treated with an oxidizing agent, such as air, to increase the level of one or more of asphaltenes, polars, and organically bound oxygen groups. The oxidized feedstock is then heated to coking temperatures and passed to a coker drum for an effective amount of time to allow volatiles to evolve and to produce a substantially free-flowing anisotropic shot coke.

Method of generating heat and vibration in a subterranean hydrocarbon-bearing formation

Abstract: A method for recovering oil in a reservoir by generating chemical microexplosions in the reservoir. The invention treats the hydrocarbon-bearing reservoir by decomposing in situ at least one PEH-3CO, thereby generating heat, shock, and CO 2 . A preferred method comprises the steps of depositing PEH-3CO into the formation and depositing an acid into the formation to cause the PEH-3CO to decompose and generate heat and gas.