Showing papers by "Masakazu Iwamoto published in 2003"
TL;DR: Mukaiyama-aldol reactions of carbonyl compounds with silyl enol ethers were well catalyzed on siliceous mesoporous materials (MCM-41) as discussed by the authors.
36 citations
TL;DR: Mukaiyama-aldol reactions of carbonyl compounds with silyl enol ethers were well catalyzed on siliceous mesoporous materials (MCM-41).
Abstract: Mukaiyama-aldol reactions of carbonyl compounds with silyl enol ethers were well catalyzed on siliceous mesoporous materials (MCM-41). The reactivity of acetals was much higher than that of aldehyde. The reactions proceeded selectively at 273–298 K on the catalyst of 30 mg per mmol of the substrate.