Hydrothermal carbonization is an important thermochemical conversion process that can be used as an energy-efficient alternative to enhance the dewaterability of sewage sludge and meanwhile to convert sewage sludge into high value-added products, such as clean biofuel, organic fertilizer and precursors of functional materials. This paper presents an overview of the latest development of hydrothermal carbonization in the field of sewage sludge treatment, with a particular focus on critical hydrothermal parameters, physicochemical characteristics of products streams, current understanding on hydrochar formation mechanisms, sewage sludge dewaterability improvement and techno-economic advantages. Recent advances have shown that hydrothermal carbonization of sewage sludge is an exothermal process, which is governed by temperature to a large extent. Both polymerizations of highly reactive intermediates derived from degradation of biopolymers in sewage sludge and solid-solid conversion of their undissolved fractions are regarded as the major mechanisms of hydrochar formation. The high ash content of hydrochar is probably the limiting factor for its potential applications in energy and functional materials. The chemistry in hydrothermal carbonization of sewage sludge, closely related to the process parameters and the chemical composition of sewage sludge, offers huge potential to influence the products distribution and characteristics and the process energetics as desired, which provides a promising opportunity to construct a high-efficiency industrial chain for energy and resources recovery from sewage sludge by a controlled hydrothermal process. This review identifies the current challenges and knowledge gaps, and provides new perspectives for future research efforts targeting at sustainable treatment of sewage sludge by hydrothermal carbonization.

Hydrothermal carbonization for energy-efficient processing of sewage sludge: A review

The energy demand of the world is expected to reach 739 quadrillions BTU in 2040, which therefore demand for exploring more alternative source of renewable energy. Waste biomass though vast in reserve for generating renewable energy has its own downside. High moisture, fibrous nature, high bulk volume, hydrophilic nature and low calorific value are some of the inferior quality of waste biomass which creates bottleneck for easy renewable energy generation. Pre-treatment of biomass to overcome these challenges has created a new research interest. Among the treatment options available, the hydrothermal carbonization (HTC) method, which can process wet waste has become the most preferred choice among researchers recently. The HTC eliminates energy-intensive pre-drying process needed for other treatment methods such as pyrolysis, dry torrefaction and incineration. Through this article, we attempt to provide a detailed review of how renewable biomass can be effectively used to produce renewable energy by improving their inherent inferior characteristics. The review also highlights bottlenecks that constrain the deployment of renewable energy using HTC methods. The scope of further research direction is well identified in this review. The paper also present recent advancements which are filling the knowledge gap of HTC technology that were there earlier. Critical analysis of microwave assisted HTC and conventional heated HTC is also presented in this review. The analysis in this paper reveals that biomass is a valuable resource, and should be explored to take advantage of its renewable energy generation potential. The HTC method of biomass upgradation improves transport, storage and fuel characteristics by improving grindability, pellets durability, hydrophobicity, energy density, combustion behaviour and calorific value, and also helps in improving the environmental performance of solid fuel produced. Despite the fact that the technology is in the early stage of development and there still exist knowledge gap and shortcomings, the vast literature reviewed suggests that it has a potential of being future technology. Therefore, it needs further investigation which should fill existing shortcoming of the technology.

Hydrothermal carbonization of renewable waste biomass for solid biofuel production: A discussion on process mechanism, the influence of process parameters, environmental performance and fuel properties of hydrochar

Impact of hydrothermal carbonization conditions on the formation of hydrochars and secondary chars from the organic fraction of municipal solid waste

Sustainable wineries through waste valorisation: A review of grape marc utilisation for value-added products

Hydrothermal carbonization of Opuntia ficus-indica cladodes: Role of process parameters on hydrochar properties.

In this paper, a hydrothermal carbonization (HTC) process is designed and modeled on the basis of experimental data previously obtained for two representative organic waste materials: off-specification compost and grape marc. The process accounts for all the steps and equipment necessary to convert raw moist biomass into dry and pelletized hydrochar. By means of mass and thermal balances and based on common equations specific to the various equipment, thermal energy and power consumption were calculated at variable process conditions: HTC reactor temperature T: 180, 220, 250 °C; reaction time θ: 1, 3, 8 h. When operating the HTC plant with grape marc (65% moisture content) at optimized process conditions (T = 220 °C; θ = 1 h; dry biomass to water ratio = 0.19), thermal energy and power consumption were equal to 1170 kWh and 160 kWh per ton of hydrochar produced, respectively. Correspondingly, plant efficiency was 78%. In addition, the techno-economical aspects of the HTC process were analyzed in detail, considering both investment and production costs. The production cost of pelletized hydrochar and its break-even point were determined to be 157 €/ton and 200 €/ton, respectively. Such values make the use of hydrochar as a CO2 neutral biofuel attractive.

Hydrothermal Carbonization of Waste Biomass: Process Design, Modeling, Energy Efficiency and Cost Analysis

One stage olive mill waste streams valorisation via hydrothermal carbonisation

Does hydrothermal carbonization as a biomass pretreatment reduce fuel segregation of coal-biomass blends during oxidation?

Olive trimmings (OT) were used as feedstock for an in-depth experimental study on the reaction kinetics controlling hydrothermal carbonization (HTC). OT were hydrothermally carbonized for a residence time τ of up to 8 h at temperatures between 180 and 250 °C to systematically investigate the chemical and energy properties changes of hydrochars during HTC. Additional experiments at 120 and 150 °C at τ = 0 h were carried out to analyze the heat-up transient phase required to reach the HTC set-point temperature. Furthermore, an original HTC reaction kinetics model was developed. The HTC reaction pathway was described through a lumped model, in which biomass is converted into solid (distinguished between primary and secondary char), liquid, and gaseous products. The kinetics model, written in MATLABTM, was used in best fitting routines with HTC experimental data obtained using OT and two other agro-wastes previously tested: grape marc and Opuntia Ficus Indica. The HTC kinetics model effectively predicts carbon distribution among HTC products versus time with the thermal transient phase included; it represents an effective tool for R&D in the HTC field. Importantly, both modeling and experimental data suggest that already during the heat-up phase, biomass greatly carbonizes, in particular at the highest temperature tested of 250 °C.

Michela Lucian

Papers

Hydrothermal Carbonization of Waste Biomass: Process Design, Modeling, Energy Efficiency and Cost Analysis

Impact of hydrothermal carbonization conditions on the formation of hydrochars and secondary chars from the organic fraction of municipal solid waste

One stage olive mill waste streams valorisation via hydrothermal carbonisation

Does hydrothermal carbonization as a biomass pretreatment reduce fuel segregation of coal-biomass blends during oxidation?

Hydrothermal Carbonization Kinetics of Lignocellulosic Agro-Wastes: Experimental Data and Modeling