Since the 1960s, Nb-Ti (superconducting transition temperature T/sub c/=9 K) and Nb/sub 3/Sn (T/sub c/=18 K) have been the materials of choice for virtually all superconducting magnets. However, the prospects for the future changed dramatically in 1987 with the discovery of layered cuprate superconductors with T/sub c/ values that now extend up to about 135 K. Fabrication of useful conductors out of the cuprates has been difficult, but a first generation of silver-sheathed composite conductors based on (Bi,Pb)/sub 2/Sr/sub 2/Ca/sub 2/Cu/sub 3/O/sub 10/ (T/sub c//spl sim/110 K) has already been commercialized. Recent progress on a second generation of biaxially aligned coated conductors using the less anisotropic YBa/sub 2/Cu/sub 3/O/sub 7/ structure has been rapid, suggesting that it too might enter service in the near future. The discovery of superconductivity in MgB/sub 2/ below 39 K in 2001 has brought yet another candidate material to the large-scale applications mix. Two distinct markets for superconductor wires exist-the more classical low-temperature magnet applications such as particle accelerators, nuclear magnetic resonance and magnetic resonance imaging magnets, and plasma-containment magnets for fusion power, and the newer and potentially much larger market for electric power equipment, such as motors, generators, synchronous condensers, power transmission cables, transformers, and fault-current limiters for the electric utility grid. We review key properties and recent progress in these materials and assess their prospects for further development and application.

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Superconducting materials for large scale applications

Development of high-field magnets using high temperature superconductors (HTS) is a core activity at the NHMFL. Magnet technology based on both YBCO-coated tape conductors and Bi-2212 round wires is being pursued. Two specific projects are underway. The first is a user magnet with a 17 T YBCO coil set which, inside an LTS outsert, will generate a combined field of 32 T. The second is a 7 T Bi2212 demonstration coil set to be operated in a large bore resistive magnet to generate a combined magnetic field of 25 T. Owing to the substantial technological differences of the two conductor types, each project faces different conductor and magnet technology challenges. Two small coils have been tested in a 38-mm cold bore cryostat inserted in a 31 T resistive magnet: a Bi2212 round-wire layer-wound insert coil that generated 1.1 T for a total of 32.1 T and a YBCO double-pancake insert that generated 2.8 T for a total central field of 33.8 T. Four larger layer-wound coils have been manufactured and tested in a 20 T, 186-mm cold bore resistive magnet: a sizeable Bi-2212 coil and three thin large-diameter YBCO coils. The test results are discussed. The current densities and stress levels that these coils tolerate underpin our conviction that >30 T all-superconducting magnets are viable.

High Field Magnets With HTS Conductors

Nb3Al has been considered as an alternative to Nb3Sn for high-field and large-scale applications, since an extremely high critical current density and excellent strain tolerance were demonstrated in Nb3Al by laboratory tests. Thus, there have been a great number of efforts in the exploration of new fabrication processes for Nb3Al. The processes explored can be classified into three groups: low-temperature processes (jelly-roll, powder metallurgy, clad chip extrusion, rod-in-tube), high-temperature processes (laser- or electron-beam irradiation), and transformation processes. This review describes Nb3Al conductors for each processing group, focusing on current topics relating to the rapid-heating, quenching and transformation method in which an excellent Nb3Al conductor can be obtained with a multifilamentary structure over several hundred metres in length.

https://iopscience.iop.org/article/10.1088/0953-2048/13/9/201/pdf

Nb3Al conductors for high-field applications

The 32-T superconducting magnet is envisioned as a 15-T low-temperature superconductor (LTS) magnet combined with a separately powered REBCO high-temperature superconductor (HTS) insert configured as two coil stacks generating 17 T. Progress was made in all aspects of this project and is reported in this work. The design concept, which has been quite stable, is presented, as well as key elements from recent developments such as increased voltage standoff requirements. In both factory testing and installation at the NHMFL, the 15-T/250-mm-bore outer magnet built by Oxford Instruments met all specifications, including a ramp time of 1 h to full field. The test protocol included a deliberately induced full-field quench, releasing 7 MJ. After the helium level recovered, the magnet was ramped again in 1 h to full field, demonstrating full recovery. Helium boiloffs during normal operation and quench were observed, as well as the current and field decay during quench. The latter information serves as one of many inputs for the numerical quench code developed specifically to model quench in coupled LTS-HTS coils. Results from the 32-T quench analysis and implications for quench protection are summarized. All HTS conductor lengths were subjected to an extensive quality assurance (QA) protocol, and SuperPower has now delivered all required conductor lengths within specifications. A summary of the QA data and its implications are presented. The prototype coils, which are very similar in design to the 32-T REBCO coils but of reduced height, have now been impregnated with paraffin to address winding motion observed in previous testing. The prototype test protocol includes a study of the effectiveness of the quench heaters in the HTS coils in both a constant background field as provided by the actual 15-T LTS outer magnet for 32 T and, uniquely, in case the outer magnet is deliberately quenched.

Progress in the Development and Construction of a 32-T Superconducting Magnet

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A review of commercial high temperature superconducting materials for large magnets: from wires and tapes to cables and conductors

The Nb tube process has recently been developed at NRIM(Japan) for fabricating Nb3Al multifilamentary superconductors,1–3 which are characterized by the heat treatment at low temperature ( 1700°C), many attempts were made to form Nb3A1 by heat treating Nb/AI composite at high temperatures.4–6 However, rapid grain growth decreased the density of pinning center (grain boundary) in Nb3A1 and thereby degraded Jc in particular at low magnetic fields. To overcome this problem, Nb3A1 conductors fabricated through a rapid-quenching process have been studied. In this process the A15 Nb3A1 phase with fine grain structure can be precipitated from the supersaturated Nb-Al bcc phase by aging at ~800°C. However, no attempt was made to fabricate a practical-structure conductor such as a long multifilamentary wire through continuous rapid-quenching and subsequent annealing (post annealing) process.

Nb3Al Multifilamentary Wires Continuously Fabricated by Rapid-Quenching

The Nb tube process has recently been developed at NRIM (Japan) for fabricating Nb3Al multifilamentary superconductors containing more than one million continuous ultrafine filaments of less than 0.1 μm diameter. The adjustment of hardness of Al cores relative to Nb matrix by alloying Al cores with additives of Mg, Ag(-Ge), Cu(-Ge), Zn, etc. improved remarkably the cold workability of Nb/Al composites. Wires heat treated below 1000°C show superior properties to a commercial multifilamentary (Nb,Ti)3Sn conductor: (1) higherJ
c (4.2 K) (1.5×109 A/m2 at 10 T), (2) smaller degradation inJ
c with mechanical strain, and (3) smaller ac loss (resulting from a smaller effective superconducting filament diameter: about 2 μm). Furthermore, sensitivity to irradiation is nearly the same as that of (Nb,Ti)3Sn. Other techniques to produce Nb3Al are unsuitable for developing a conductor with multifilamentary structure, and thereby the Nb tube processed Nb3Al multifilamentary conductors is the best available for fusion reactor magnets.

Development of Nb tube processed Nb3Al multifilamentary superconductor

In order to enhance the current carrying capacity, we have developed an improved fabrication process where the wire diameter can be increased from 0.5 to 1.25 mm and the Nb-matrix ratio decreased from 1.5 to 0.52, without degrading the critical current density, J/sub c/, of Nb/sub 3/Al phase. The critical current for a monolithic conductor at 21 T and 4.2 K has now been enhanced to 166 A which used to be 15 A. The compacted-strand-cables were fabricated to investigate feasibility for large-scale application uses. We have found that stranding and flat-rolling the as-quenched Nb/Nb(Al)/sub ss/ composite cause no degradation in J/sub c/. Attempts were made to stabilize the resulting high current conductors.

Enhanced current capacity of jelly-roll processed and transformed Nb/sub 3/Al multifilamentary conductors

Development of a 1 GHz superconducting NMR magnet is in progress at the Tsukuba Magnet Laboratory (TML) of the National Research Institute for Metals (NRIM). This magnet will contain a BSCCO inner coil, which should generate a central field of 23.5 T in a backup field of 21.1 T. In order to accomplish this targeted field, we fabricated two Bi-2212 double-pancake coils (Coil A and Coil B). They were installed in the high-field superconducting magnet system at the TML/NRIM. Their performance was measured in a backup field of 18 T. Coil A was made of 20 double-pancakes wound with Ag sheathed Bi-2212 tape conductors. Ag-Mg tape was co-wound for mechanical support. Its winding was 147 mm in outer diameter and 220 mm in height. It generated a central field of 21.4 T in a clear bore of 61 mm. Coil B was located inside Coil A. Its 6 double-pancakes were wound with Bi-2212 tape conductors reinforced with Ag-Mg-Ni alloy sheath. The outer diameter and height of the winding were 48 mm and 63 mm, respectively. Coil B generated the highest field of 23.4 T in a backup field of 21.4 T. This study confirmed that the present performance of the Bi-2212 coils had already satisfied the required conditions for the inner coil of the 1 GHz NMR magnet from the viewpoint of high-field generation.

Generation of 23.4 T using two Bi-2212 insert coils

A rapid heating and quenching (RHQ) operation along a long-length of jellyroll Nb/Al precursor over 300 m has been established. The J/sub c/ varies sensitively with the joule-heating current (I/sub RHQ/) that determines the temperature from which a precursor wire is quenched, excluding the "plateau" region where the bcc supersaturated-solid solution (Nb(Al)/sub ss/) only forms. The RHQ operation using such a plateau condition can suppress a scatter of J/sub c/ from point to tail of a long-length of wire. The standard deviation of J/sub c/ (4.2 K) at 21 T along a long-length of wire was about 5%, which was less than the variation of J/sub c/ with I/sub RHQ/ in the plateau region (/spl plusmn/7%). The mechanical deformation process needed when incorporating the Cu stabilizer also plays an important role in ensuring uniform heat treatment of the coil that is wound with a long-length of wire and, hence, large heat capacity. Although a temperature ramp-up rate might differ from place to place in the coil, the deformation processing makes such a ramp-up rate insensitive to these critical parameters. The coils using 300.5 m and 254 m lengths of Cu-clad RHQT JR Nb/sub 3/Al conductor generated additional 2.3 T and 3.2 T in bores of 90.2 mm/spl phi/ and 64.6 mm/spl phi/, respectively, indicating that a long-length of RHQT JR Nb/sub 3/Al conductor can be trustworthy for practical coil applications.

http://ieeexplore.ieee.org/iel5/77/27269/01212371.pdf

Michio Kosuge

Papers

Nb3Al Multifilamentary Wires Continuously Fabricated by Rapid-Quenching

Development of Nb tube processed Nb3Al multifilamentary superconductor

Enhanced current capacity of jelly-roll processed and transformed Nb/sub 3/Al multifilamentary conductors

Generation of 23.4 T using two Bi-2212 insert coils

Transport properties of long-lengths of RHQT processed Nb/sub 3/Al conductor