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Nessan J. Kerrigan
Researcher at Dublin City University
Publications - 59
Citations - 716
Nessan J. Kerrigan is an academic researcher from Dublin City University. The author has contributed to research in topics: Enantioselective synthesis & Ketene. The author has an hindex of 16, co-authored 57 publications receiving 625 citations. Previous affiliations of Nessan J. Kerrigan include University of Rochester & Eastern Illinois University.
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Phosphine-catalyzed asymmetric synthesis of beta-lactones from arylketoketenes and aromatic aldehydes.
TL;DR: The development of a chiral phosphine-catalyzed formal [2 + 2] cycloaddition of aldehydes and ketoketenes that provides access to a variety of highly substituted beta-lactones is reported.
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BINAPHANE-catalyzed asymmetric synthesis of trans-β-lactams from disubstituted ketenes and N-tosyl arylimines.
TL;DR: The development of a BINAPHANE-catalyzed formal [2 + 2]-cycloaddition of disubstituted ketenes and inexpensive N-tosyl arylimines that provides access to a variety of highly substituted β-lactams is described.
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Josiphos-catalyzed asymmetric homodimerization of ketoketenes.
TL;DR: A chiral phosphine-catalyzed homodimerization ofketoketenes that provides access to a variety of highly substituted ketoketene dimer β-lactones is reported.
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Recent Developments in Vinylsulfonium and Vinylsulfoxonium Salt Chemistry
TL;DR: This review describes advances in the literature since 2000 in the area of reactions of Vinylsulfonium and vinylsulfoxonium salts, with a particular emphasis on stereoselective examples.
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Development of a solid-phase 'asymmetric resin-capture-release' process: application of an ephedrine chiral resin in an approach to gamma-butyrolactones.
TL;DR: The potential of a solid-phase asymmetric resin-capture-release strategy for high-throughput synthesis has been evaluated and it is shown that the ephedrine resin can be conveniently recovered and recycled although in some cases lower yields were obtained on reuse of the chiral resin.