During the past decade, enormous progress has been made in growing ultrathin organic films and multilayer structures with a wide range of exciting optoelectronic properties. This progress has been made possible by several important advances in our understanding of organic films and their modes of growth. Perhaps the single most important advance has been the use of ultrahigh vacuum (UHV) as a means to achieve, for the first time, monolayer control over the growth of organic thin films with extremely high chemical purity and structural precision.1-3 Such monolayer control has been possible for many years using well-known techniques such as Langmuir-Blodgett film deposition,4 and more recently, self-assembled monolayers from solution have also been achieved.5 However, ultrahighvacuum growth, sometimes referred to as organic molecular beam deposition (OMBD) or organic molecular beam epitaxy (OMBE), has the advantage of providing both layer thickness control and an atomically clean environment and substrate. When combined with the ability to perform in situ highresolution structural diagnostics of the films as they are being deposited, techniques such as OMBD have provided an entirely new prospect for understanding many of the fundamental structural and optoelectronic properties of ultrathin organic film systems. Since such systems are both of intrinsic as well as practical interest, substantial effort worldwide has been invested in attempting to grow and investigate the properties of such thin-film systems. This paper is a review of recent progress made in organic thin films grown in ultrahigh vacuum or using other vapor-phase deposition methods. We will describe the most important work which has been published in this field since the emergence of OMBD in the mid-1980s. Both the nature of thin-film growth and structural ordering will be discussed, as well as some of the more interesting consequences to the physical properties of such organic thin-film systems will be considered both from a theoretical as well as an experimental viewpoint. Indeed, it will 1793 Chem. Rev. 1997, 97, 1793−1896

Ultrathin Organic Films Grown by Organic Molecular Beam Deposition and Related Techniques.

It is shown that the ordinary semiclassical theory of the absorption of light by exciton states is not completely satisfactory (in contrast to the case of absorption due to interband transitions). A more complete theory is developed. It is shown that excitons are approximate bosons, and, in interaction with the electromagnetic field, the exciton field plays the role of the classical polarization field. The eigenstates of the system of crystal and radiation field are mixtures of photons and excitons. The ordinary one-quantum optical lifetime of an excitation is infinite. Absorption occurs only when "three-body" processes are introduced. The theory includes "local field" effects, leading to the Lorentz local field correction when it is applicable. A Smakula equation for the oscillator strength in terms of the integrated absorption constant is derived.

a Quantum-Mechanical Theory of the Contribution of Excitons to the Complex Dielectric Constant of Crystals.

Squeezed states of the electromagnetic field have been generated by nondegenerate four-wave mixing due to Na atoms in an optical cavity. The optical noise in the cavity, comprised of primarily vacuum fluctuations and a small component of spontaneous emission from the pumped Na atoms, is amplified in one quadrature of the optical field and deamplified in the other quadrature. These quadrature components are measured with a balanced homodyne detector. The total noise level in the deamplified quadrature drops below the vacuum noise level.

Observation of squeezed states generated by four-wave mixing in an optical cavity

Seventy five years ago, three remarkable papers by Schr¨ odinger, Kennard and Darwin were published. They were devoted to the evolution of Gaussian wave packets for an oscillator, a free particle and a particle moving in uniform constant electric and magnetic fields. From the contemporary point of view, these packets can be considered as prototypes of the coherent and squeezed states, which are, in a sense, the cornerstones of modern quantum optics. Moreover, these states are frequently used in many other areas, from solid state physics to cosmology. This paper gives a review of studies performed in the field of so-called ‘nonclassical states’ (squeezed states are their simplest representatives) over the past seventy five years, both in quantum optics and in other branches of quantum physics. My starting point is to elucidate who introduced different concepts, notions and terms, when, and what were the initial motivations of the authors. Many new references have been found which enlarge the ‘standard citation package’ used by some authors, recovering many undeservedly forgotten (or unnoticed) papers and names. Since it is practically impossible to cite several thousand publications, I have tried to include mainly references to papers introducing new types of quantum states and studying their properties, omitting many publications devoted to applications and to the methods of generation and experimental schemes, which can be found in other well known reviews. I also mainly concentrate on the initial period, which terminated approximately at the border between the end of the 1980s and the beginning of the 1990s, when several fundamental experiments on the generation of squeezed states were performed and the first conferences devoted to squeezed and ‘nonclassical’ states commenced. The 1990s are described in a more ‘squeezed’ manner: I have confined myself to references to papers where some new concepts have been introduced, and to the most recent reviews or papers with extensive bibliographical lists.

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'Nonclassical' states in quantum optics: a 'squeezed' review of the first 75 years

We report the creation of thermal, Fock, coherent, and squeezed states of motion of a harmonically bound {sup 9}Be{sup +} ion. The last three states are coherently prepared from an ion which has been initially laser cooled to the zero point of motion. The ion is trapped in the regime where the coupling between its motional and internal states, due to applied (classical) radiation, can be described by a Jaynes-Cummings-type interaction. With this coupling, the evolution of the internal atomic state provides a signature of the number state distribution of the motion. {copyright} {ital 1996 The American Physical Society.}

Generation of Non-classical Motional States of a Trapped Atom

We use the approach of ``transitionless quantum driving'' proposed by Berry to construct shortcuts to the population transfer and the creation of maximal entanglement between two $\ensuremath{\Lambda}$-type atoms based on the cavity quantum electronic dynamics system. An effective Hamiltonian is designed by resorting to an auxiliary excited level, a classical driving field, and an extra cavity field mode to supplement or substitute the original reference Hamiltonian, and steer the system evolution along its instantaneous eigenstates in an arbitrarily short time, speeding up the rate of population transfer and creation of maximal entanglement between the two atoms inside a cavity. Numerical simulation demonstrates that our shortcuts are robust against the decoherences caused by atomic spontaneous emission and cavity photon leakage.

Shortcuts to adiabatic passage for population transfer and maximum entanglement creation between two atoms in a cavity

We construct a genuine $(2N+1)$-qubit entangled state to perform controlled teleportation of an arbitrary $N$-qubit state. The constructed state is a complementarity to the genuine $2N$-qubit entangled state constructed by Yeo and Chua for $N=2$ [Phys. Rev. Lett. 96, 060502 (2006)] and by Chen, Zhu, and Guo for any $N$ [Phys. Rev. A 74, 032324 (2006)]. We also quantify the entanglement of the state and classify it with the well-known $GHZ$ and $W$ states by means of the recently proposed generalized global entanglement and the associated auxiliary measures [Phys. Rev. A 74, 022314 (2006)]. Our study is of general importance with respect to exploring and exploiting the genuine multiqubit entanglement.

Genuine multiqubit entanglement and controlled teleportation

We propose a set of novel protocols to remotely prepare a general two-qubit state by joint actions of two separate people who independently share the classical knowledge of the state, without and with quantum control of a supervisor. Various quantum resources are used as the quantum channel. Although the execution complexity differs for different protocols, the total success probability is protocol independent.

https://iopscience.iop.org/article/10.1088/0953-4075/42/12/125501/pdf

Joint remote preparation of a general two-qubit state

Joint remote state preparation via W and W-type states

We propose a protocol for teleporting an unknown coherent-state superposition within a network consisting of ${2}^{N}$ parties with N an arbitrary positive integer. We show explicitly that for moderate and high intensity fields the probability of success is 50%, i.e. the same as in the case of $N=1.$

Nguyen Ba An

Papers

Shortcuts to adiabatic passage for population transfer and maximum entanglement creation between two atoms in a cavity

Genuine multiqubit entanglement and controlled teleportation

Joint remote preparation of a general two-qubit state

Joint remote state preparation via W and W-type states

Teleportation of coherent-state superpositions within a network