N
Nidal Saleh
Researcher at University of Rennes
Publications - 29
Citations - 935
Nidal Saleh is an academic researcher from University of Rennes. The author has contributed to research in topics: Helicene & Phosphine. The author has an hindex of 15, co-authored 29 publications receiving 730 citations. Previous affiliations of Nidal Saleh include Centre national de la recherche scientifique & Institut de Chimie des Substances Naturelles.
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Journal ArticleDOI
Helicene-based transition metal complexes: synthesis, properties and applications
TL;DR: The coordination and/or organometallic chemistry of π-helicenic ligands is a powerful tool to generate multifunctional molecules displaying optimized chiroptical properties combined with new properties furnished by the metallic center.
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Acid/Base‐Triggered Switching of Circularly Polarized Luminescence and Electronic Circular Dichroism in Organic and Organometallic Helicenes
Nidal Saleh,Barry Moore,Monika Srebro,Nicolas Vanthuyne,Loïc Toupet,J. A. Gareth Williams,Christian Roussel,Kirandeep K. Deol,Gilles Muller,Jochen Autschbach,Jeanne Crassous +10 more
TL;DR: The very large bathochromic shift of the emission observed upon protonation of azahelicene-bipyridine 1 a has been attributed to the decrease in aromaticity (promoting a charge-transfer-type transition rather than a π-π* transition) as well as an increase in the HOMO-LUMO character of the transition and stabilization of the LUMO level upon proptonation.
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enantio-Enriched CPL-active helicene–bipyridine–rhenium complexes
Nidal Saleh,Monika Srebro,Thibault Reynaldo,Nicolas Vanthuyne,Loïc Toupet,Victoria Y. Chang,Gilles Muller,J. A. Gareth Williams,Christian Roussel,Jochen Autschbach,Jeanne Crassous +10 more
TL;DR: The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes as discussed by the authors.
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Synthesis of 9H-Pyrrolo[1,2-a]indole and 3H-Pyrrolizine Derivatives via a Phosphine-Catalyzed Umpolung Addition/Intramolecular Wittig Reaction
Nidal Saleh,Arnaud Voituriez +1 more
TL;DR: The first umpolung addition/intramolecular Wittig reaction, catalytic in phosphine, is described and is applicable to the synthesis of a wide range of functionalized 9H-pyrrolo[1,2-a]indoles and pyrrolizines.
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From phosphine-promoted to phosphine-catalyzed reactions by in situ phosphine oxide reduction
Arnaud Voituriez,Nidal Saleh +1 more
TL;DR: In this paper, the regeneration of the active catalyst was possible by means of reagents that reduce in situ the phosphine oxide formed during the reaction, and the results on newly developed phosphine-catalyzed reactions were summarized.