The detection and measurement of gas concentrations using the characteristic optical absorption of the gas species is important for both understanding and monitoring a variety of phenomena from industrial processes to environmental change. This study reviews the field, covering several individual gas detection techniques including non-dispersive infrared, spectrophotometry, tunable diode laser spectroscopy and photoacoustic spectroscopy. We present the basis for each technique, recent developments in methods and performance limitations. The technology available to support this field, in terms of key components such as light sources and gas cells, has advanced rapidly in recent years and we discuss these new developments. Finally, we present a performance comparison of different techniques, taking data reported over the preceding decade, and draw conclusions from this benchmarking.

/pdf/optical-gas-sensing-a-review-4uaf589xiq.pdf

Optical gas sensing: a review

Lanthanide-doped upconversion nanoparticles (UCNPs) have attracted considerable interest due to their superior physicochemical features, such as large anti-Stokes shifts, low autofluorescence background, low toxicity and high penetration depth, which make them extremely suitable for use as alternatives to conventional downshifting luminescence bioprobes like organic dyes and quantum dots for various biological applications. A fundamental understanding of the photophysics of lanthanide-doped UCNPs is of vital importance for discovering novel optical properties and exploring their new applications. In this review, we focus on the most recent advances in the development of lanthanide-doped UCNPs as potential luminescent nano-bioprobes by means of our customized lanthanide photophysics measurement platforms specially designed for upconversion luminescence, which covers from their fundamental photophysics to bioapplications, including electronic structures (energy levels and local site symmetry of emitters), excited-state dynamics, optical property designing, and their promising applications for in vitro biodetection of tumor markers. Some future prospects and efforts towards this rapidly growing field are also envisioned.

Lanthanide-doped upconversion nano-bioprobes: electronic structures, optical properties, and biodetection

Nonlinear Optical Crystals: A Complete Survey

Within the field of spectral imaging, the vast majority of instruments used are scanning devices. Recently, several snapshot spectral imaging systems have become commercially available, providing new functionality for users and opening up the field to a wide array of new applications. A comprehensive survey of the available snapshot technologies is provided, and an attempt has been made to show how the new capabilities of snapshot approaches can be fully utilized.

https://www.spiedigitallibrary.org/journals/optical-engineering/volume-52/issue-9/090901/Review-of-snapshot-spectral-imaging-technologies/10.1117/1.OE.52.9.090901.pdf

Review of snapshot spectral imaging technologies

Autonomous navigation in cross-country environments presents many new challenges with respect to more traditional, urban environments. The lack of highly structured components in the scene complicates the design of even basic functionalities such as obstacle detection. In addition to the geometric description of the scene, terrain typing is also an important component of the perceptual system. Recognizing the different classes of terrain and obstacles enables the path planner to choose the most efficient route toward the desired goal.

This paper presents new sensor processing algorithms that are suitable for cross-country autonomous navigation. We consider two sensor systems that complement each other in an ideal sensor suite: a color stereo camera, and a single axis ladar. We propose an obstacle detection technique, based on stereo range measurements, that does not rely on typical structural assumption on the scene (such as the presence of a visible ground plane)s a color-based classification system to label the detected obstacles according to a set of terrain classess and an algorithm for the analysis of ladar data that allows one to discriminate between grass and obstacles (such as tree trunks or rocks), even when such obstacles are partially hidden in the grass. These algorithms have been developed and implemented by the Jet Propulsion Laboratory (JPL) as part of its involvement in a number of projects sponsored by the US Department of Defense, and have enabled safe autonomous navigation in high-vegetated, off-road terrain.

/pdf/obstacle-detection-and-terrain-classification-for-autonomous-56lyfce1fy.pdf

Obstacle Detection and Terrain Classification for Autonomous Off-Road Navigation

The measurement of branching ratios, cross sections and radiative lifetimes for rare earth ions in solids is considered The methods are applied to Tm and Ho in YLF as a test case De-activation rates for electric dipole and magnetic dipole emission are calculated for many of the lower lying manifolds in Tm:YLF and Ho:YLF in the context of the Judd-Ofelt theory to determine radiative lifetimes Measured values for the branching ratios as well as the absorption and emission cross sections are also presented for many of the excited state manifolds From these measurements, a methodology is developed to extract measured values for the radiative lifetimes These results are compared with the Judd-Ofelt theory as a guide for consistency and for determining the accuracy of the Judd-Ofelt theory in predicting branching ratios and radiative lifetimes The parameters generated by the methods covered here have potential applications for more accurate modeling of Tm:Ho laser systems

Branching ratios, cross sections, and radiative lifetimes of rare earth ions in solids: Application to Tm3+ and Ho3+ ions in LiYF4

Lanthanide series ions are considered in the context of acquiring spectroscopic parameters and their application to modelling of quasifour-level lasers. Tm:Ho codoped crystals of YLiF4 (YLF) and the isomorphs LuLiF4 (LuLF) and GdLiF4 (GdLF) as 2.0 μm lasers are used for illustration of the experimental and theoretical techniques presented here. While these materials have similar physical properties, they differ in the strength of the crystal field at the site of optically active lanthanide dopant ions such as Tm3+ and Ho3+. This is due in part to the size of the Lu3+, Y3+, and Gd3+ ions, which comprise part of the host lattice, but ionicity plays a role as well. This selection of lanthanide: host materials provides a useful basis on which to assess laser materials with regards to changes in the strength of the crystal field at the dopant ion site. It is demonstrated that Tm:Ho:LuLF has a larger crystal field splitting than Tm:Ho:YLF and Tm:Ho:GdLF, leading to smaller thermal populations in the Ho lower laser level. To assess this effect quantitatively, the energy levels of the first ten manifolds in Ho:LuLF have been determined. Measurement of Ho:XLiF4 (X=Y,Lu,Gd) emission cross sections at 2.0 μm, Tm:XLiF4 pump absorption cross sections around 0.78 μm, manifold to manifold decay times and energy transfer parameters in Tm:Ho:XLiF4 systems are also determined to provide a consistent set of parameters to use in laser modeling. The techniques presented here are applicable to any lanthanide series ion in a crystalline host. A theoretical laser model has been developed that is easily adapted to any lanthanide ion in a crystal host. The model is used to predict diode side-pumped laser performance of Tm:Ho:LuLF and Tm:Ho:YLF using input parameters determined from the spectroscopy presented here. An explanation is presented for the improved performance of Tm:Ho:LuLF over Tm:Ho:YLF by modeling the laser. A demonstration that small changes in lower laser thermal population can substantially alter laser performance is noted, an effect that has not been fully appreciated previously.

Spectroscopy and modeling of solid state lanthanide lasers: Application to trivalent Tm3+ and Ho3+ in YLiF4 and LuLiF4

Tm-doped ZBLAN and Tm-doped silica glass are compared spectroscopically and the fiber lasing of the Tm 3
F
4 →3
H
6 transition around 1.9 μm in ZBLAN and silica fibers is compared. The spectroscopy of these materials indicates that Tm:ZBLAN possesses advantages over Tm:silica glass due to the lower phonon energies. The phonon energy in these glass hosts influences both the pump manifold lifetime, the Tm 3
H
4, and the upper laser manifold lifetime, the Tm 3
F
4. The maximum phonon energy in Tm:ZBLAN, ∼500 cm-1 , compared to Tm:silica, ∼1100 cm-1, leads to better Tm–Tm self quenching towards populating the Tm 3
F
4, as well as better Tm 3
F
4→3
H
6 quantum efficiency. A spectroscopic analysis using the Judd–Ofelt theory and measured lifetimes are used to assess the merits of Tm:ZBLAN over Tm:silica as a fiber laser material. Diode-pumped fiber lasing experiments show that Tm:ZBLAN possesses advantages over Tm:silica that are believed to be due to a lower phonon energy. Data is presented for launched pump energy versus laser energy, fiber length versus slope efficiency, and output mirror reflectivity versus slope efficiency. Tm:ZBLAN is demonstrated to possess higher slope efficiencies and lower thresholds, than Tm:silicate. A grating tuned Tm:ZBLAN laser is also demonstrated for tunable operation between 1.893 μm and 1.955 μm.

Comparison of Tm:ZBLAN and Tm:Silica fiber lasers; Spectroscopy and tunable pulsed laser operation around 1.9 μm

Mid infrared lasers for remote sensing applications

A compact, lightweight, and efficient fiber laser lidar system has been developed to measure water vapor profiles in the lower atmosphere of Earth or Mars. The line narrowed laser consist of a Tm:germanate fiber pumped by two 792 nm diode arrays. The fiber laser transmits ~0.5 mJ Q- switched pulses at 5 Hz and can be tuned to water vapor lines near 1.94 μm with linewidth of ~20 pm. A lightweight lidar receiver telescope was constructed of carbon epoxy fiber with a 30 cm Fresnel lens and an advanced HgCdTe APD detector. This system has made preliminary atmospheric measurements.

Norman P. Barnes

Papers

Branching ratios, cross sections, and radiative lifetimes of rare earth ions in solids: Application to Tm3+ and Ho3+ ions in LiYF4

Spectroscopy and modeling of solid state lanthanide lasers: Application to trivalent Tm3+ and Ho3+ in YLiF4 and LuLiF4

Comparison of Tm:ZBLAN and Tm:Silica fiber lasers; Spectroscopy and tunable pulsed laser operation around 1.9 μm

Mid infrared lasers for remote sensing applications

Profiling atmospheric water vapor using a fiber laser lidar system