There is currently widespread use of drones and drone technology due to their rising applications that have come into fruition in the military, safety surveillance, agriculture, smart transportation, shipping, and delivery of packages in our Internet-of-Things global landscape. However, there are security-specific challenges with the authentication of drones while airborne. The current authentication approaches, in most drone-based applications, are subject to latency issues in real time with security vulnerabilities for attacks. To address such issues, we introduce a secure authentication model with low latency for drones in smart cities that looks to leverage blockchain technology. We apply a zone-based architecture in a network of drones, and use a customized decentralized consensus, known as drone-based delegated proof of stake (DDPOS), for drones among zones in a smart city that does not require reauthentication. The proposed architecture aims for positive impacts on increased security and reduced latency on the Internet of Drones (IoD). Moreover, we provide an empirical analysis of the proposed architecture compared to other peer models previously proposed for IoD to demonstrate its performance and security authentication capability. The experimental results clearly show that not only does the proposed architecture have low packet loss rate, high throughput, and low end-to-end delay in comparison to peer models but also can detect 97.5% of attacks by malicious drones while airborne.

Enabling Drones in the Internet of Things With Decentralized Blockchain-Based Security

The Internet of Drones (IoD) recently gained momentum due to its high adaptability to a wide variety of complex scenarios. Indeed, Unmanned Aerial Vehicles (UAVs) can successfully be employed in different applications, such as agriculture, search and rescue missions, surveillance systems, mission-critical services, among others, thanks to some technological and practical advantages: high mobility, capability to extend wireless coverage areas, or ability to reach places inaccessible to humans. Moreover, the employment of drones promisingly improves the performance parameters of different network architectures, e.g., reliability, connectivity, throughput, and delay. Nevertheless, the adoption of networks of drones gives rise to several issues related to the intrinsic unreliability of the wireless medium, the duration of batteries, and the high mobility degree, which may cause frequent topology changes. Also security and privacy issues need to be properly investigated. This explains the very large number of works produced in the recent literature on IoD-related topics. With respect to other surveys on IoD-related topics, the goal of the present work is to categorize the multifaceted aspects of IoD, proposing a classification approach of the IoD environment that develops along two main directions. The IoD is initially introduced according to the possible applications and reference operating scenarios. On top of that, this work discussed with its applicability with a dedicated focus on the economical/social implications that the adoption of drones at scale may have. At a macroscopic level, it follows the structure of the Internet protocol stack, starting from the physical layer and extending to the upper layers, without neglecting cross-layer and optimization approaches. At a finer level, all the most relevant works belonging to each layer of the stack are further classified, according to the different issues that propose a peculiar challenges for each layer, and highlighting the most relevant differences with the other surveys present in literature. To provide a deeper insight, the present work embraces many facets of the IoD, with a thorough examination of privacy and security considerations. Finally, a discussion on the main research challenges and possible future directions is carried out, focusing on both open issues and the most promising technologies that deserve to be further developed in the IoD field.

An extensive survey on the Internet of Drones

Donor–Acceptor Cyclopropanes as an Expedient Building Block Towards the Construction of Nitrogen-Containing Molecules: An Update

A new synthetic concept was suggested in the chemistry of substituted methylidenemalonates that enables their utilization as 1,2-zwitterionic synthons. This strategy is to generate liquid ionic Ga complexes from methylidenemalonates and GaHal3 with a strict 3/4 composition and then use them in further synthesis. A number of complexes with different metal halides have been synthesized and studied in detail. The unique properties of gallium among all metals have been demonstrated and explained. On the basis of the discovered new class of gallium complexes of methylidenemalonates, a number of novel reactions with acetylenes have been elaborated, which are unknown in the conventional chemistry of methylidenemalonates. The main demonstrated process is a three-component addition to a triple bond involving halide anions, leading to the formation of polyfunctional vinyl halides with high E-selectivity. The mechanism has been studied experimentally in fine detail. Application of specially optimized 71Ga NMR spectr...

Ionic Ga-Complexes of Alkylidene- and Arylmethylidenemalonates and Their Reactions with Acetylenes: An In-Depth Look into the Mechanism of the Occurring Gallium Chemistry.

We propose a new concept of the triple role of protic ionic liquids with nucleophilic anions: a) a regenerable solvent, b) a Bronsted acid inducing diverse transformations via general acid catalysis, and c) a source of a nucleophile. The efficiency of this strategy was demonstrated using thiocyanate-based protic ionic liquids for the ring-opening of donor-acceptor cyclopropanes. A wide variety of activated cyclopropanes were found to react with 1-methylimidazolium thiocyanate under mild metal-free conditions via unusual nitrogen attack of the ambident thiocyanate ion on the electrophilic center of the three-membered ring affording pyrrolidine-2-thiones bearing donor and acceptor substituents at the C(5) and C(3) atoms, respectively, in a single time-efficient step. The ability of 1-methylimidazolium thiocyanate to serve as a triplex reagent was exemplarily illustrated by (4+2)-annulation with 1-acyl-2-(2-hydroxyphenyl)cyclopropane, epoxide ring-opening and other organic transformations.

https://www.onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202016593

Protic Ionic Liquid as Reagent, Catalyst, and Solvent: 1-Methylimidazolium Thiocyanate

In this report, a facile synthesis of tetrahydropyridazines via a Lewis acid catalyzed annulation reaction of cyclopropane carbaldehydes and aryl hydrazines has been demonstrated. Moreover, the generated tetrahydropyridazine further participated in a cycloaddition reaction with donor–acceptor cyclopropanes to furnish hexahydropyrrolo[1,2-b]pyridazines. We also performed these two steps in one pot in a consecutive manner. In addition, a monodecarboxylation reaction of hexahydropyrrolo[1,2-b]pyridazine was achieved with a good yield.

Lewis Acid Catalyzed Annulation of Cyclopropane Carbaldehydes and Aryl Hydrazines: Construction of Tetrahydropyridazines and Application Toward a One-Pot Synthesis of Hexahydropyrrolo[1,2-b]pyridazines

Exploitation of Cyclopropane Carbaldehydes to Prins Cyclization: Quick Access to ( E)-Hexahydrooxonine and Octahydrocyclopenta[ b]pyran.

In this paper, use of drone as a relay node in Network Coded Cooperation (NCC) for upcoming wireless networks is proposed to achieve additional diversity as well as improve throughput. Unlike static relay cases, in drone assisted scenarios, better performance can be achieved simply by changing the position of relay. In order to quantify the network performance in drone assisted NCC, analytical closed form expression of outage probability has been calculated using two approaches namely, Analytical and Semi-analytical. Using a generalized system model, Probability Density Function (PDF) of Signal to Noise Ratio (SNR) of the path from source to destination via drone (relay) is derived. Closed form expression for outage probability in absence of direct link is also investigated. By analyzing Analog Network Coding (ANC) noise, statistical parameters of variance of ANC-noise have been obtained. Analytical findings have been verified through extensive simulations using MATLAB. Effects of drone height on system performance is also investigated through simulations. Framework presented here can be useful while analysing networks having resource constraint devices. PDF of SNR of relay path can be utilized for performing diversity calculations. Two outage expressions derived may be useful in determining system parameters for achieving any particular Quality of Service (QoS) in next generation wireless networks. Valuable insights obtained through the analysis of optimum height of drone are conducive while deploying the nodes in deterministic fashion for NCC.

Analysis of Drone Assisted Network Coded Cooperation for Next Generation Wireless Network

A convenient additive-free synthesis of dihydro-4H-1,2-oxazines via a Cloke-Wilson-type ring expansion of the aryl-substituted cyclopropane carbaldehydes with the hydroxylamine salt is introduced. Comparatively less active cyclopropyl ketones also follow a similar protocol if supplemented by catalytic p-toluene sulfonic acid monohydrate. The transformation is performed in an open-to-air flask as it shows negligible sensitivity toward air/moisture. Dihydro-4H-1,2-oxazines when subjected to cycloaddition with the cyclopropane diester afford a trouble-free formulation of the valued hexahydro-2H-pyrrolo[1,2-b][1,2]oxazine derivatives. A cascade one-pot variant of this two-step strategy offers a comparable overall yield of the final product.

Accessing Dihydro-1,2-oxazine via Cloke-Wilson-Type Annulation of Cyclopropyl Carbonyls: Application toward the Diastereoselective Synthesis of Pyrrolo[1,2-b][1,2]oxazine.

https://ietresearch.onlinelibrary.wiley.com/doi/pdf/10.1049/cmu2.12134

Pankaj Kumar

Papers

Lewis Acid Catalyzed Annulation of Cyclopropane Carbaldehydes and Aryl Hydrazines: Construction of Tetrahydropyridazines and Application Toward a One-Pot Synthesis of Hexahydropyrrolo[1,2-b]pyridazines

Exploitation of Cyclopropane Carbaldehydes to Prins Cyclization: Quick Access to ( E)-Hexahydrooxonine and Octahydrocyclopenta[ b]pyran.

Analysis of Drone Assisted Network Coded Cooperation for Next Generation Wireless Network

Accessing Dihydro-1,2-oxazine via Cloke-Wilson-Type Annulation of Cyclopropyl Carbonyls: Application toward the Diastereoselective Synthesis of Pyrrolo[1,2-b][1,2]oxazine.

Drone assisted device to device cooperative communication for critical environments