Zinc oxide is a unique material that exhibits semiconducting and piezoelectric dual properties. Using a solid–vapour phase thermal sublimation technique, nanocombs, nanorings, nanohelixes/nanosprings, nanobelts, nanowires and nanocages of ZnO have been synthesized under specific growth conditions. These unique nanostructures unambiguously demonstrate that ZnO probably has the richest family of nanostructures among all materials, both in structures and in properties. The nanostructures could have novel applications in optoelectronics, sensors, transducers and biomedical sciences. This article reviews the various nanostructures of ZnO grown by the solid–vapour phase technique and their corresponding growth mechanisms. The application of ZnO nanobelts as nanosensors, nanocantilevers, field effect transistors and nanoresonators is demonstrated.

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Zinc oxide nanostructures: growth, properties and applications

Using molecules as electronic components is a powerful new direction in the science and technology of nanometre-scale systems1. Experiments to date have examined a multitude of molecules conducting in parallel2,3, or, in some cases, transport through single molecules. The latter includes molecules probed in a two-terminal geometry using mechanically controlled break junctions4,5 or scanning probes6,7 as well as three-terminal single-molecule transistors made from carbon nanotubes8, C60 molecules9, and conjugated molecules diluted in a less-conducting molecular layer10. The ultimate limit would be a device where electrons hop on to, and off from, a single atom between two contacts. Here we describe transistors incorporating a transition-metal complex designed so that electron transport occurs through well-defined charge states of a single atom. We examine two related molecules containing a Co ion bonded to polypyridyl ligands, attached to insulating tethers of different lengths. Changing the length of the insulating tether alters the coupling of the ion to the electrodes, enabling the fabrication of devices that exhibit either single-electron phenomena, such as Coulomb blockade, or the Kondo effect.

Coulomb blockade and the Kondo effect in single-atom transistors

The petrology record on the Moon suggests that a cataclysmic spike in the cratering rate occurred approximately 700 million years after the planets formed; this event is known as the Late Heavy Bombardment (LHB). Planetary formation theories cannot naturally account for an intense period of planetesimal bombardment so late in Solar System history. Several models have been proposed to explain a late impact spike, but none of them has been set within a self-consistent framework of Solar System evolution. Here we propose that the LHB was triggered by the rapid migration of the giant planets, which occurred after a long quiescent period. During this burst of migration, the planetesimal disk outside the orbits of the planets was destabilized, causing a sudden massive delivery of planetesimals to the inner Solar System. The asteroid belt was also strongly perturbed, with these objects supplying a significant fraction of the LHB impactors in accordance with recent geochemical evidence. Our model not only naturally explains the LHB, but also reproduces the observational constraints of the outer Solar System.

/pdf/origin-of-the-cataclysmic-late-heavy-bombardment-period-of-3t3659zr9t.pdf

Origin of the cataclysmic Late Heavy Bombardment period of the terrestrial planets

A collection of three papers in this issue, tackling seemingly unrelated planetary phenomena, marks a notable unification of Solar System dynamics. The three problems covered are the hard-to-explain orbits of giant planets, the evolution of the orbits of Jupiter's Trojan asteroids, and the cause of the ‘Late Heavy Bombardment’ that peppered the Moon with meteors, comets and asteroids some 700 million years after the planets were formed. Key to all these events, on this new model, was a rapid migration of the giant planets (Saturn, Jupiter, Neptune and Uranus) after a long period of stability within the Solar System. Planetary formation theories1,2 suggest that the giant planets formed on circular and coplanar orbits. The eccentricities of Jupiter, Saturn and Uranus, however, reach values of 6 per cent, 9 per cent and 8 per cent, respectively. In addition, the inclinations of the orbital planes of Saturn, Uranus and Neptune take maximum values of ∼2 degrees with respect to the mean orbital plane of Jupiter. Existing models for the excitation of the eccentricity of extrasolar giant planets3,4,5 have not been successfully applied to the Solar System. Here we show that a planetary system with initial quasi-circular, coplanar orbits would have evolved to the current orbital configuration, provided that Jupiter and Saturn crossed their 1:2 orbital resonance. We show that this resonance crossing could have occurred as the giant planets migrated owing to their interaction with a disk of planetesimals6,7. Our model reproduces all the important characteristics of the giant planets' orbits, namely their final semimajor axes, eccentricities and mutual inclinations.

http://www.ifa.hawaii.edu/~meech/a740/2006/spring/papers/nature03539.pdf

Origin of the orbital architecture of the giant planets of the Solar System.

http://vigarano.ep.sci.hokudai.ac.jp/shogo/adv_geochemistry2015/Week%204/Background%20reading/Bus%20and%20Binzel%202002.pdf

Paolo Farinella

Papers

Asteroid Families. I. Identification by Hierarchical Clustering and Reliability Assessment

Meteorite Delivery via Yarkovsky Orbital Drift

Collisional Evolution of Edgeworth–Kuiper Belt Objects

Non-gravitational perturbations and satellite geodesy

Collision rates and impact velocities in the Main Asteroid Belt