Experimental, DFT and MD evaluation of Nandina domestica Thunb. extract as green inhibitor for carbon steel corrosion in acidic medium

Choline amino acid ionic liquids as green corrosion inhibitors of mild steel in acidic medium

Insight into the anti–corrosion behavior of Reineckia Carnea leaves extract as an eco–friendly and high–efficiency corrosion inhibitor

Two azo derivatives, 4-((4-hydroxy-3-((4-oxo-2-thioxothiazolidin-5-ylidene)methyl)phenyl) diazinyl) benzenesulfonic acid (TODB) and 4-((3-((4,4-dimethyl-2,6-dioxocyclohexylidene) methyl)-4-hydroxyphenyl)diazinyl) benzenesulfonic acid (DODB) were synthesized and characterized using Fourier-transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (1H-NMR) and mass spectral studies. Gravimetric methods, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM) techniques and inductive coupled plasma-optical emission spectroscopy were used to verify the above two compounds' ability to operate as mild steel (MS) corrosion inhibitors in 1 M HCl. Tafel data suggest that TODB and DODB have mixed-type characteristics, and EIS findings demonstrate that increasing their concentration not only alters the charge transfer (Rct) of mild steel from 6.88 Ω cm2 to 112.9 Ω cm2 but also changes the capacitance of the adsorbed double layer (Cdl) from 225.36 to 348.36 μF cm-2. At 7.5 × 10-4 M concentration, the azo derivatives showed the highest corrosion inhibition of 94.9% and 93.6%. The inhibitory molecule adsorption on the metal substrate followed the Langmuir isotherm. The thermodynamic activation functions of the dissolution process were also calculated as a function of inhibitor concentration. UV-vis, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX) techniques were used to confirm the adsorption phenomenon. The quantum chemical parameters, inductively coupled plasma atomic emission spectroscopy (ICPE) measurements, and the anti-bacterial effect of these new derivatives against sulfate-reducing bacteria (SRB) were also investigated. Taken together, the acquired results demonstrate that these compounds can create an appropriate preventing surface and regulate the corrosion rate. 

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Insights into the adsorption and corrosion inhibition properties of newly synthesized diazinyl derivatives for mild steel in hydrochloric acid: synthesis, electrochemical, SRB biological resistivity and quantum chemical calculations

Fructus cannabis protein extract powder as a green and high effective corrosion inhibitor for Q235 carbon steel in 1 M HCl solution.

Insight into the anti–corrosion performance of Artemisia argyi leaves extract as eco–friendly corrosion inhibitor for carbon steel in HCl medium

Insight into anti–corrosion behavior of Centipeda minima leaves extract as high–efficiency and eco–friendly inhibitor

Biogenic manganese oxides (Bio-MnOx) have attracted considerable attention for removing pharmaceutical contaminants (PhCs) due to their high oxidation capacity and environmental friendliness. Mn-oxidizing microalgae (MnOMs) generate Bio-MnOx with low energy and organic nutrients input and degrade PhCs. The combined process of MnOMs and Bio-MnOx exhibits good prospects for PhCs removal. However, the synergistic effects of MnOMs and Bio-MnOx in PhCs removal are still unclear. The performance of MnOMs/Bio-MnOx towards diclofenac (DCF) removal was evaluated, and the mechanism was revealed. Our results showed that the Bio-MnOx produced by MnOMs were amorphous nanoparticles, and these MnOMs have a good Mn2+ tolerance and oxidation efficiency (80–90%) when the Mn2+ concentration is below 1.00 mmol/L. MnOMs/Bio-MnOx significantly promotes DCF (1 mg/L) removal rate between 0.167 ± 0.008 mg/L·d (by MnOMs alone) and 0.125 ± 0.024 mg/L·d (by Bio-MnOx alone) to 0.250 ± 0.016 mg/L·d. The superior performance of MnOMs/Bio-MnOx could be attributed to the continuous Bio-MnOx regeneration and the sharing of DCF degradation intermediates between Bio-MnOx and MnOMs. Additionally, the pathways of DCF degradation by Bio-MnOx and MnOMs were proposed. This work could shed light on the synergistic effects of MnOMs and Bio-MnOx in PhCs removal and guide the development of MnOMs/Bio-MnOx processes for removing DCF or other PhCs from wastewater.

https://www.mdpi.com/2305-6304/10/5/230/pdf?version=1652243123

Combined Process of Biogenic Manganese Oxide and Manganese-Oxidizing Microalgae for Improved Diclofenac Removal Performance: Two Different Kinds of Synergistic Effects

In recent years, the frequent outbreaks of cyanobacterial blooms have caused severe water pollution in many rivers and lakes at home and abroad, endangering drinking water safety and human health. How to remove cyanobacteria from water bodies safely, quickly, and economically has attracted the attention of many scientists. Currently, the typical treatment methods for algae in algae-bearing water bodies are physical, biological, and chemical methods. The physical method of algae removal is for both the symptoms and the root cause, but the workload is extensive, with high input costs, and should not be used on a large scale. The biological method is low-cost, but the removal efficiency is slow and unsuitable for the treatment of sudden water bloom. The chemical method can kill algae quickly, but it is easy to cause secondary pollution. These methods are relatively independent of each other, so the choice of a practical combination of technologies is essential for algal bloom removal and eutrophication management. This paper reviews the current application status and advantages and disadvantages of algae removal technologies at home and abroad; classifies them from physical, chemical, biological, and combined methods; and provides an outlook on the future development direction of algae removal technologies.

https://www.mdpi.com/2073-4441/15/6/1104/pdf?version=1678785417

Comparison of the Advantages and Disadvantages of Algae Removal Technology and Its Development Status

Peroxymonosulfate (PMS) activation is an intriguing technology for refractory organic pollutant removal in wastewater treatment. Herein, a highly dispersed Mn-Ce bimetallic oxide on carbon nanotubes (MCC) was synthesized and applied to catalyze PMS for the degradation of phenol. The material was well characterized using a transmission electron microscope (TEM), N2 adsorption–desorption isotherms, X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The synthesized MCC showed superior activity for PMS activation. The k value of phenol removal with MCC is 0.135 min−1, which is greatly superior to that of CNT (6.17 × 10−5 min−1) and Mn-Ce bimetallic oxide (3.18 × 10−4 min−1). Electron paramagnetic resonance (EPR), along with radical quenching experiments, revealed that the activation of PMS by MCC for phenol degradation involves both radical and non-radical reaction pathways. Moreover, a synergic effect between Mn-Ce bimetallic oxide and CNT was identified to be responsible for the outstanding catalytic activity.

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Pei Gao

Papers

Insight into the anti–corrosion performance of Artemisia argyi leaves extract as eco–friendly corrosion inhibitor for carbon steel in HCl medium

Insight into anti–corrosion behavior of Centipeda minima leaves extract as high–efficiency and eco–friendly inhibitor

Combined Process of Biogenic Manganese Oxide and Manganese-Oxidizing Microalgae for Improved Diclofenac Removal Performance: Two Different Kinds of Synergistic Effects

Comparison of the Advantages and Disadvantages of Algae Removal Technology and Its Development Status

Enhanced PMS Activation by Highly Dispersed Mn-Ce Bimetallic Oxide on Carbon Nanotubes for Degradation of Phenol