P
Philip J. Bailey
Researcher at University of Edinburgh
Publications - 66
Citations - 1906
Philip J. Bailey is an academic researcher from University of Edinburgh. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 22, co-authored 66 publications receiving 1834 citations.
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Journal ArticleDOI
The coordination chemistry of guanidines and guanidinates
Philip J. Bailey,Stuart Pace +1 more
TL;DR: Guanidines have attracted increasing attention as electronically and sterically flexible ligands as mentioned in this paper, exhibiting a variety of coordination modes and a range of donor properties leading to compatibility with a remarkably wide range of metal ions from all parts of the periodic table.
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The first structural characterisation of a Group 2 metal alkylperoxide complex: Comments on the cleavage of dioxygen by magnesium alkyl complexes
Philip J. Bailey,Robert A. Coxall,Caroline M. Dick,Sylvie Fabre,Louise C. Henderson,Christian Herber,Stephen T. Liddle,Daniel Loroño-González,Andrew Parkin,Simon Parsons +9 more
TL;DR: The formation of a 1:2 mixture of the benzylperoxo and benzyloxo species indicates that the rate of the insertion is faster than that of the metathesis, and this is shown to be consistent with a radical mechanism for the insertion process.
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Synthesis and characterisation of magnesium methyl complexes with monoanionic chelating nitrogen donor ligands and their reaction with dioxygen
TL;DR: In this article, the Grignard reagent MeMgCl with the lithiates Li[L-X] (Li[L−X] = lithium β-diketiminate [HC{C(Me)NAr′}2Li] (Ar′) = 2,6-diisopropylphenyl) or lithium N,N′-diiscopropylaminotroponiminate, Li[(iPr2)ATI]) in THF provided four-coordinate methylmagnesium complexes [Mg(
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A New Bridging Ligand for the [Mo2]4+ Dimer: Syntheses and X-ray Crystal Structures of the Redox Pair [Mo2{μ-η2-(NPh)2CNHPh}4]0/+
Philip J. Bailey,Simon F. Bone,L A Mitchell,Simon Parsons,Kenneth J. Taylor,Lesley J. Yellowlees +5 more
TL;DR: The quadruply bonded molybdenum dimer [Mo2{μ-η2-(NPh)2CNHPh}4] (1), bridged by four triphenylguanidine anion ligands, has been synthesized and structurally characterized.
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Hydridotris(thioxotriazolyl)borate (Tt), an ambidentate (N(3)/S(3)) tripodal ligand. X-ray crystal structures of sodium, bismuth(III), tin(IV), and manganese(I) complexes.
TL;DR: Treatment of the heterocycle 5-thioxo-4,5-dihydro-3,4-dimethyl-1,2, 4-triazole with sodium tetrahydroborate at 210 degrees C provides the new [N(3)/S(3)] ambidentate tripod ligand hydridotris(thioxotriazolyl)borate (Tt) as its sodium complex salt.