P
Philip Magnus
Researcher at University of Texas at Austin
Publications - 224
Citations - 4114
Philip Magnus is an academic researcher from University of Texas at Austin. The author has contributed to research in topics: Ring (chemistry) & Indole test. The author has an hindex of 38, co-authored 224 publications receiving 3948 citations. Previous affiliations of Philip Magnus include Indiana University.
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Hypervalent Iodine Chemistry: New Oxidation Reactions Using the Iodosylbenzene−Trimethylsilyl Azide Reagent Combination. Direct α- and β-Azido Functionalization of Triisopropylsilyl Enol Ethers
TL;DR: In this article, the triisopropylsilyl (TIPS) enol ethers were treated with PhIO/TMSN3/at −18 to −15 °C rapidly (5 min) with only traces of the α-azido adduct.
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Concise syntheses of (-)-galanthamine and (+/-)-codeine via intramolecular alkylation of a phenol derivative.
TL;DR: This is the shortest synthesis of codeine (13 steps, 20% overall yield) and, for the first time, allows access to codeine without having to reduce codeinone.
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Dibenzotetraphenylperiflanthene: Synthesis, photophysical properties, and electrogenerated chemiluminescence
TL;DR: Fissure coupling of the fluoranthene adduct (7,12-diphenyl)benzo[k]fluoranthene (3) using AlCl3/NaCl, CoF3/TFA, or Tl(OCOCF3) gave the new polyaromatic hydrocarbon dibenzo{[f,f]]-4,4’,7,7’-tetraphenyl}diindeno[1,2,3-cd:1‘,2
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Conversion of α,β-unsaturated ketones into α-hydroxy ketones using an MnIII catalyst, phenylsilane and dioxygen: acceleration of conjugate hydride reduction by dioxygen
TL;DR: In this article, a variety of α,β-unsaturated ketones with Mn(dpm)3 (3 mol%)/PhSiH3 (1.3 equiv.)/isopropyl alcohol/O2, followed by reductive work-up with P(OEt)3 resulted in the formation of α-hydroxyketones.