P
Philip P. Duce
Researcher at University of Leicester
Publications - 18
Citations - 179
Philip P. Duce is an academic researcher from University of Leicester. The author has contributed to research in topics: Aqueous solution & Reaction rate constant. The author has an hindex of 7, co-authored 18 publications receiving 174 citations.
Papers
More filters
Journal ArticleDOI
Solubilities of salts and kinetics of reaction between hydroxide ions and iron(II)–di-imine complexes in water–methanol mixtures. Derivation of single-ion transfer chemical potentials and their application to analysis of solvent effects on kinetic parameters
Michael J. Blandamer,John Burgess,Barbara Clark,Philip P. Duce,Andrew W. Hakin,Nrinder Gosal,Stojan Radulovic,Pilar Guardado,Francisco Sánchez,Colin D. Hubbard,Ezz-Eldin A. Abu-Gharib +10 more
TL;DR: In this article, a range of inorganic salts containing simple and complex ions are examined and, depending on the extrathermodynamic assumption, shown to predict different trends in the properties of ions in these aqueous mixtures.
Journal ArticleDOI
Kinetic and spectroscopic intimations of intermediates in nucleophilic attack at diimine complexes of iron(II) and of molybdenum(O)
Michael J. Blandamer,John Burgess,Philip P. Duce,Keith S. Payne,Robert Sherry,Paul Wellings,Martyn V. Twigg +6 more
TL;DR: In this paper, the role and nature of intermediates in nucleophilic substitution reactions of transition metaldiimine complexes was discussed, and of ancillary qualitative observations, and the role of the intermediates was discussed.
Journal ArticleDOI
Initial state and transition state contributions to reactivity in mercury(II)-catalysed aquation of thetrans-[Rh(en)2Cl2]+, [Cr(NH3)5Cl]2+, andcis-[Cr(NH3)4(OH2)Cl]2+ cations in binary aqueous solvent mixtures
A. Olabode Adeniran,Gareth J. Baker,Gabriel J. Bennett,Michael J. Blandamer,John Burgess,Nilam K. Dhammi,Philip P. Duce +6 more
TL;DR: In this article, the rate constants for the mercury-catalysed aquation of trichloro-transition metal complexes were investigated in water and methanol-, ethanol-, and acetonitrile-water solvent mixtures.
Journal ArticleDOI
Kinetics of peroxodisulphate oxidation of low-spin iron(II) complexes in binary aqueous mixtures
TL;DR: In this paper, the rate constants for the oxidation of two low-spin iron(II) complexes by peroxodisulphate in binary aqueous mixtures have been investigated.
Journal ArticleDOI
Kinetics of reactions in microheterogeneous aqueous systems
TL;DR: In this article, the authors investigated the kinetics of reaction involving two low-spin iron(II) di-imine complexes, Fe(phen)2+3 and Fe(hxsbH)2+, where the solvent media include three micro-emulsions and a range of aqueous 2-butoxyethanol mixtures.