Philippe Guionneau

TL;DR: In this paper, it was shown that the hexagonal layer motif [AM{sup III}(C{sub 2} O{sub 4} ]{sub 3}]{sup n-} containing bridging oxalate groups, which has been shown to form a wide variety of compounds with electronically inactive counter-cations having unusual cooperative magnetic properties, can also stabilize lattices containing the organic {pi}-donor BEDT-TTF.

TL;DR: In this article, the potential for the application of the spin crossover (SCO) phenomenon in various domains, such as molecular electronics, data storage, display devices, is reviewed, and several requirements must be fulfilled before any use in a genuine device becomes feasible.

TL;DR: In this paper, structural modifications due to spin crossover are first estimated, these include the expansion and the distortion of the FeN 6 octahedron, the isotropic and the anisotropic changes of the unit cell.

TL;DR: In this paper, the authors developed a method for determining experimentally the charges of BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene, also ET) molecules.

TL;DR: A correlation between the nature of the coordination sphere of the metal and the photomagnetic lifetime can be drawn and this result clearly opens the way towards room-temperature photonic materials, based on the spin-crossover phenomenon, which will be of great interest for future communication devices.