P
Piero Spagnolo
Researcher at University of Bologna
Publications - 187
Citations - 2504
Piero Spagnolo is an academic researcher from University of Bologna. The author has contributed to research in topics: Radical & Azide. The author has an hindex of 29, co-authored 187 publications receiving 2417 citations.
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From azides to nitrogen-centered radicals: applications of azide radical chemistry to organic synthesis.
TL;DR: Over the last thirty years organic azides have drawn a great deal of attention as radical traps for carbon- and heteroatom-centered radicals, both in intra- and in intermolecular processes.
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Free-radical reactions of benzenethiol and diphenyl disulphide with alkynes. Chemical reactivity of intermediate 2-(phenylthio)vinyl radicals
TL;DR: In this article, it was shown that 1-phenyl-2-(phenylthio)vinyl radicals can exhibit homolytic intramolecular cyclization reactions, leading to benzothiophene products to a comparatively much greater extent than the 1-alkyl- 2-substituted analogues.
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Hexamethyldisilathiane: Its Use in the Conversion of Aromatic and Heteroaromatic Azides to Amines
Antonella Capperucci,Alessandro Degl'Innocenti,Maria Funicello,Giacomo Mauriello,Patrizia Scafato,Piero Spagnolo +5 more
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Approach to Spirocyclohexadienimines and Corresponding Dienones through Radical ipso Cyclization onto Aromatic Azides
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An Insight into the Radical Thiol/Yne Coupling: The Emergence of Arylalkyne-Tagged Sugars for the Direct Photoinduced Glycosylation of Cysteine-Containing Peptides
Matteo Minozzi,Alessandro Monesi,Daniele Nanni,Piero Spagnolo,Nicola Marchetti,Alessandro Massi +5 more
TL;DR: The glycosylation of the tripeptide glutathione in its native form was successfully applied, under physiological conditions, to a cysteine-containing nonapeptide with marked advantages over the analogous Thiol-Ene Coupling (TEC) derivatization.