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Showing papers by "Prathap Haridoss published in 2008"


Journal ArticleDOI
TL;DR: A wide compositional range of Ni-Pd alloy catalysts were prepared by electrodeposition for use as anode materials for methanol oxidative fuel cells in alkaline conditions.
Abstract: A wide compositional range of Ni–Pd alloy catalysts were prepared by electrodeposition for use as anode materials for methanol oxidative fuel cells in alkaline conditions. Structural characterization of the electrocatalysts in their as-plated condition revealed that the Ni–Pd catalysts synthesized were nanocrystalline, single phase, face centered cubic materials, indicating the formation of complete solid solution in the alloy. Compositional analysis of the alloys indicated that the palladium composition of the alloy increased with decrease in current density. This change in the composition of the alloy resulted in a shift in the X-ray diffraction peaks. The percentage shift in the d-spacing calculated from X-ray diffraction is in good agreement with percentage of palladium in the alloy. The electrocatalysts prepared are active for methanol oxidation in alkaline medium.

78 citations


Journal ArticleDOI
TL;DR: In this paper, the use of mechanical means to separate the metallic and non-metallic components present in printed circuit boards (PCBs) was examined and the separation efficiency was analyzed in terms of composition, particle size and operating condition of the elutriation flow rate.

40 citations


Journal ArticleDOI
TL;DR: In this article, it is proposed that rotation of the cathode drags plasma formed between two electrodes away from high temperature region, which results in a sudden quenching of the reactive plasma.

34 citations


Journal ArticleDOI
TL;DR: In this paper, the synthesis and characterization of a nanocomposite incorporating zinc oxide (ZnO) in mesoporous silica (MPS), a host medium for stabilizing the nanoparticles, is reported.

31 citations