Nanoindentation in polymer nanocomposites

................................................................................................................................... ii Dedication................................................................................................................................ iv Acknowledgments.................................................................................................................... v Vita........................................................................................................................................... vii List of Tables............................................................................................................................. xii List of Figures............................................................................................................................ xiv Chapter 1 ‐ Introduction........................................................................................................... 1 1.1 ‐ Microbial fuel cells.................................................................................................. 2 1.2 ‐ Microbial fuel cell applications............................................................................... 4 1.3 ‐ Research problems associated with MFC technology............................................. 5 1.4 ‐ Introduction to this research study......................................................................... 6 Chapter 2 ‐ Effects of Nano‐structure Enhanced Cathodes on Electricity Production of Two‐ Chamber Microbial Fuel Cells 2.1 ‐ Introduction............................................................................................................ 8 2.2 ‐ Materials and Methods........................................................................................... 16 2.2.1 ‐ Electrode construction Graphite bar anodes.......................................................................................... 18 Graphite bar cathodes....................................................................................... 20

In Partial Fulfillment of the Requirements for the Degree of

Thermal stability and flame-retardancy mechanism of poly(ethylene terephthalate)/boehmite nanocomposites

Low-temperature processed mesoporous nanocrystal thin films are platforms for fabricating functional composite thin films on flexible substrates. Using a random arrangement of anisotropic nanocrystals can be a facile solution to generate pores without templates. However, the tendency for anisotropic particles to spontaneously assemble into a compact structure must be overcome. Here, we present a method to achieve random networking of nanorods during solution phase deposition by switching their ligand-stabilized colloidal nature into a charge-stabilized nature by a ligand-stripping chemistry. Ligand-stripped tungsten suboxide (WO2.72) nanorods result in uniform mesoporous thin films owing to repulsive electrostatic forces preventing nanorods from densely packing. Porosity and pore size distribution of thin films are controlled by changing the aspect ratio of the nanorods. This template-free mesoporous structure, achieved without annealing, provides a framework for introducing guest components, therefore en...

http://pubs.acs.org/doi/pdf/10.1021/acs.nanolett.7b02730

Template-Free Mesoporous Electrochromic Films on Flexible Substrates from Tungsten Oxide Nanorods

Boehmite is an aluminum oxyhydroxide [AlO(OH)] which is preferentially used as precursor for the production of (transition) aluminum oxides. Boehmite alumina (BA) nanoparticles are available in various morphologies due to versatile synthesis routes, which are briefly introduced. The peripheral hydroxyl groups of BA offer manifold functionalization possibilities for tailoring the dispersion and filler/matrix adhesion properties. The incorporation of BA nanofillers, with and without surface treatments, may yield improved mechanical and novel functional properties in polymers. BA can be introduced in polymers and polymer composites through different methods. This comprehensive overview covers the basic results reported on polymer/BA nanocomposites in the open literature. In this review, polymer matrices are grouped into thermoplastics, thermosets, and rubbers. Using literature results and our own findings, we have identified promising R&D trends with polymer/BA nanocomposites. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45573.

https://onlinelibrary.wiley.com/doi/pdf/10.1002/app.45573

Polymer/boehmite nanocomposites: A review

https://dr.ntu.edu.sg/bitstream/10220/8217/1/61.%20The%20effect%20of%20AlOOH%20boehmite%20nanorods%20on%20mechanical%20property%20of%20hybrid%20composite%20coatings.pdf

Q. Chen

Papers

The effect of AlOOH boehmite nanorods on mechanical property of hybrid composite coatings