R
Rashad R. Karimov
Researcher at Auburn University
Publications - 24
Citations - 663
Rashad R. Karimov is an academic researcher from Auburn University. The author has contributed to research in topics: Catalysis & Chemistry. The author has an hindex of 11, co-authored 20 publications receiving 480 citations. Previous affiliations of Rashad R. Karimov include Memorial Sloan Kettering Cancer Center & Kettering University.
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Transition-Metal-Catalyzed Selective Functionalization of C(sp3 )-H Bonds in Natural Products.
TL;DR: Advances in the transition-metal-catalyzed functionalization of C(sp3 )-H bonds have allowed natural product derivatives to be created selectively and strategies to achieve such transformation are reviewed.
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Late Stage Azidation of Complex Molecules
TL;DR: The site-selective azidation of benzylic and aliphatic C–H bonds in complex molecules catalyzed by the combination of Fe(OAc)2 and a PyBox ligand is reported, providing a wide variety of nitrogen-containing complex molecules.
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Übergangsmetall‐katalysierte selektive Funktionalisierung von C(sp3)‐H‐Bindungen in Naturstoffen
TL;DR: In this paper, Jungste Fortschritte bei Ubergangsmetall-katalysierten Funktionalisierungen von C(sp3)-H-Bindungen, den zwar haufigsten, aber inerten Bindungen in Naturstoffen, haben gezeigt, dass selektiv Derivate dieser NaturStoffe hergestellt werden konnen.
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Highly efficient RuCl3-catalyzed disproportionation of (diacetoxyiodo)benzene to iodylbenzene and iodobenzene; leading to the efficient oxidation of alcohols to carbonyl compounds
TL;DR: In this paper, RuCl 3 (0.8 − 1.0 ) is used to accelerate the disproportionation of DIB to iodobenzene and iodylbenzene with the latter acting as the actual stoichiometric oxidant toward alcohol.
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2-iodylphenol ethers: preparation, X-ray crystal structure, and reactivity of new hypervalent iodine(V) oxidizing reagents.
TL;DR: Single-crystal X-ray diffraction analysis of 1-iodyl-2-isopropoxybenzene 8d revealed pseudopolymeric arrangements in the solid state formed by intermolecular interactions between IO2 groups of different molecules.