This document includes supplemental material to an article titled "Thermochemical Investigations of Solute Transfer into Ionic Liquid Solvents: Updated Abraham Model Equation Coefficients for Solute Activity Coefficient and Partition Coefficient Predictions," published in Physics and Chemistry of Liquids.

Supporting Material for: Thermochemical Investigations of Solute Transfer into Ionic Liquid Solvents: Updated Abraham Model Equation Coefficients for Solute Activity Coefficient and Partition Coefficient Predictions

Experimental solubilities have been determined by spectrophotometric methods for 1-chloro-4-bromobenzene, 1,4-dibromobenzene, 1,4-dichloro-2-nitrobenzene, benzoic acid, 4-nitrobenzoic acid, 3,5-din...

Development of Abraham model correlations for solute transfer into 2-ethyl-1-hexanol from both water and the gas phase based on measured solubility ratios

Estimation of enthalpies of sublimation of organic, organometallic and inorganic compounds

Published experimental enthalpy of solution data and excess molar enthalpy of mixing data have been compiled from the chemical and engineering literature for systems containing N,N-dimethylacetamid...

Abraham model correlations for enthalpies of solvation of organic solutes dissolved in N,N-Dimethylacetamide, 2-butanone and tetrahydrofuran (UPDATED) at 298.15 K

Abraham model correlations for describing solute transfer into 4-methyl-2-pentanol from both water and the gas phase

Spectrophotometric methods were used to measure the mole fraction solubility of o-acetoacetanisidide dissolved in 13 alcohol solvents (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, 2-propanol, 2-butanol, 2-methyl-1-propanol, 2-methyl-2-propanol, 2-methyl-2-butanol, 3-methyl-1-butanol and 4-methyl-2-pentanol), in 3 dialkyl ether solvents (diisopropyl ether, dibutyl ether and methyl tert-butyl ether), in 6 alkyl alkanoate solvents (methyl acetate, ethyl acetate, propyl acetate, butyl acetate, pentyl acetate and methyl butyrate) and in 1 alkanenitrile solvent (propanenitrile) at 298.15 K. Solute descriptors were calculated for o-acetoacetanisidide by analysing the measured solubility data in accordance with the Abraham solvation parameter model. The calculated solute descriptors describe the observed solubility data to within 0.099 log units.

Determination of Abraham model solute descriptors for o-acetoacetanisidide based on experimental solubility data in organic mono-solvents

Experimental solubilities have been measured at 298.15 K for benzil, biphenyl, pyrene, fluoranthene, acenaphthene, xanthene, fluorene, 1,2,4,5-tetramethylbenzene, 4-tert-butylbenzoic acid, benzoic ...

Development of Abraham model correlations for describing solute transfer into 2-methyl-1-butanol from both water and the gas phase from experimental solubility data of crystalline organic compounds

Experimental solubilities have been determined for xanthone dissolved in 15 different alcohol solvents (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 2-methyl-1-propanol, 3-methyl-1-butanol, 2-ethyl-1-hexanol, 2-propanol, 2-butanol, 4-methyl-2-pentanol, 2-methyl-2-propanol and 2-methyl-2-butanol), in five alkyl acetate solvents (methyl acetate, ethyl acetate, propyl acetate, butyl acetate and pentyl acetate), in diisopropyl ether and in 2-ethoxyethanol at 298.2 K. In total, solubility measurements were performed in 22 organic solvents of varying polarity and hydrogen-bonding character. Results of the experimental measurements were used to calculate the Abraham model solute descriptors for xanthone. The calculated solute descriptors describe the experimental solubility data to within 0.096 log units.

Reese Neal

Papers

Abraham model correlations for describing solute transfer into 4-methyl-2-pentanol from both water and the gas phase

Determination of Abraham model solute descriptors for o-acetoacetanisidide based on experimental solubility data in organic mono-solvents

Development of Abraham model correlations for describing solute transfer into 2-methyl-1-butanol from both water and the gas phase from experimental solubility data of crystalline organic compounds

Determination of Abraham model solute descriptors for xanthone based on experimental solubility measurements at 298.2 K