R
Roxanne P. Spencer
Researcher at Princeton University
Publications - 10
Citations - 181
Roxanne P. Spencer is an academic researcher from Princeton University. The author has contributed to research in topics: Glycosyl & Glycal. The author has an hindex of 5, co-authored 10 publications receiving 174 citations.
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Titanium(III) Reagents in Carbohydrate Chemistry: Glycal and C-Glycoside Synthesis
TL;DR: Titanocene(III) chloride and zirconcene(III), a mild reagents for radical generation in organic synthesis, were used for the conversion of glycosyl halides to glycals in this article.
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Rapid preparation of variously protected glycals using titanium(iii)
TL;DR: In this article, a reaction mechanism based on heteroatom abstraction is proposed to give an intermediate glycosyl radical, which reacts with a second equivalent of Ti(III) to yield a glycosyltitanium(IV) species.
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Titanium(III)-Promoted Stereoselective Synthesis of Simple C-Glycosides.
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Variously substituted glycals are readily prepared from glycosyl bromides using (Cp2TiCl)2
TL;DR: Glycosyl halides, variously substituted with ether, acetal, or ester protecting groups, were converted to the corresponding glycals in high yield by reaction with (C p2 TiCl) 2.