The effect of neutral nonresonant collisions on the shape, shift, and intensity of atomic spectral-line profiles is reviewed. A general treatment for the study of an atomic spectral line is developed by establishing reasonable assumptions about the relevant collision processes and by finding an expression for the Fourier transform of the line profile. The authors look at parallel developments of other methods of calculation, consider special limits of practical interest, and illustrate numerical evaluations of complete line profiles. Interatomic potentials for use in line-profile calculations are described, and the problems imposed by nonadditivity and nonadiabaticity are also noted. The observation of line profiles by both conventional and tunable-laser techniques is surveyed. Representative experimental measurements of the widths and shifts of collision-broadened spectral line cores are tabulated, and the phenomena of satellites, oscillations, and power-law behavior of line wings are compared with theoretical expectations. The use of experimental results for the determination of excited atom-atom interactions, the prediction of collision broadening in stellar atmospheres, and the effect of foreign gases on laboratory standard wavelengths are also discussed.

The effect of neutral nonresonant collisions on atomic spectral lines

A set of tables of the Stark width of the first three lines of Lyman and Balmer series of hydrogen, useful for plasma diagnosis purposes, is presented in this work. These tables have been obtained by means of a fully recognized computer simulation technique. Computer experiments have been carried out for density values between and . Simulation temperatures range from 2245 K to 224 856 K. Ion dynamics effects are taken into account in a natural way and the most significative gas mixtures have been covered in the simulations, carried out at the reduced mass of the emitter - perturber pair , 0.6, 0.8, 0.9, 1.0, 1.25, 1.5, 1.75 and 2.0. A detailed discussion of the influence of the relevant plasma parameters on the characteristics of the profiles is also included. The results show an excellent agreement with up-to-date experimental results and confirm these kind of profile calculation techniques as now the most accurate.

https://iopscience.iop.org/article/10.1088/0953-4075/29/20/029/pdf

New plasma diagnosis tables of hydrogen Stark broadening including ion dynamics

In this paper, we report modifications of well known semiempirical and semiclassical approximation furmulas for Stark line-width calculations. Comparisons with experiments for doubly ionized atoms yield, as an average ratio of measured to calculated widths 1.06 ± 0.31 for a modified semiempirical formula and 0.96±0.24 for a modified semiclassical formula. For triply ionized atoms these ratios are 0.91±0.42 and 1.08±0.41, respectively. Comparison with other theoretical calculations have also been made.

Stark widths of doubly- and triply-ionized atom lines☆

The Virtual Atomic and Molecular Data Centre (VAMDC) Consortium is a worldwide consortium which federates atomic and molecular databases through an e-science infrastructure and an organisation to support this activity. About 90% of the inter-connected databases handle data that are used for the interpretation of astronomical spectra and for modelling in many fields of astrophysics. Recently the VAMDC Consortium has connected databases from the radiation damage and the plasma communities, as well as promoting the publication of data from Indian institutes. This paper describes how the VAMDC Consortium is organised for the optimal distribution of atomic and molecular data for scientific research. It is noted that the VAMDC Consortium strongly advocates that authors of research papers using data cite the original experimental and theoretical papers as well as the relevant databases.

/pdf/the-virtual-atomic-and-molecular-data-centre-vamdc-14rikmpf5c.pdf

The virtual atomic and molecular data centre (VAMDC) consortium

The broadening and shift of spectral lines caused by the interaction of the emitting (or absorbing) atoms with surrounding particles in the plasma are commonly observed in laboratory and astronomical spectra. A detailed analysis of the observed line shapes can give information about the density and temperature of the plasma, and in cases where the interaction between emitter and perturber is not known, some information on its form may be deduced.

S. Sahal-Brechot

Papers

Impact theory of the broadening and shift of spectral lines due to electrons and ions in a plasma.