The deposition of an overlay of higher refractive index than the cladding in a Long Period Fiber Grating (LPFG) permits to improve the sensitivity to ambient refractive index changes in a great manner. When the overlay is thick enough, one of the cladding modes is guided by the overlay. This causes important shifts in the effective index values of the cladding modes, and henceforward fast shifts of the resonance wavelength of the attenuations bands in the transmission spectrum. This could be applied for improving the sensitivity of LPFG sensors. The problem is analysed with a numerical method based on LP mode approximation and coupled mode theory, which agrees with so far published experimental results.

Optimization of sensitivity in Long Period Fiber Gratings with overlay deposition.

Colloidal suspensions of 3-aminopropylmethyl(tetraphenyl)silole nanoparticles can be used as selective chemosensors for carcinogenic chromium(VI) analyte. Methylhydrosilole is functionalized by hydrosilation of allylamine, and the colloid is prepared by the rapid addition of water to a THF solution of the silole. The method of detection is through electron-transfer quenching of the fluorescence of the silole colloid (λem = 485 nm at 360 nm excitation) by the analytes, with hundred parts per billion detection limits. Stern−Volmer plots are linear up to 10 ppm in the case of chromium, but exhibit saturation behavior near 5−10 ppm for arsenic. Dynamic light scattering experiments and AFM measurements show the particle sizes to be around 100 nm in diameter and dependent on solvent composition, with a particle size dispersity of ±25%. The fluorescence lifetimes of the silole in solution and colloid are ∼31 ps and ∼4.3 ns, respectively, while the silole has a lifetime of 6 ns in the bulk solid. A minimum volume...

Luminescent silole nanoparticles as chemoselective sensors for Cr(VI).

Optical sensors and biosensors based on sol-gel films.

In this work, the numerical and experimental investigation of the cladding modes re-organization in high refractive index (HRI) coated Long Period Gratings (LPGs) is reported. Moreover, the effects of the cladding modes re-organization on the sensitivity to the surrounding medium refractive index (SRI) have been outlined. When azimuthally symmetric nano-scale HRI coatings are deposited along LPGs devices, a significant modification of the cladding modes distribution occurs, depending on the layer features (refractive index and thickness) and on the SRI. In particular, if layer parameters are properly chosen, the transition of the lowest order cladding mode into an overlay mode occurs. As a consequence, a cladding modes re-organization can be observed leading to relevant improvements in the SRI sensitivity in terms of wavelength shift and amplitude variations of the LPGs attenuation bands.

Mode transition in high refractive index coated long period gratings.

This is the first comprehensive review on methods and materials for use in optical sensing of pH values and on applications of such sensors. The Review starts with an introduction that contains subsections on the definition of the pH value, a brief look back on optical methods for sensing of pH, on the effects of ionic strength on pH values and pKa values, on the selectivity, sensitivity, precision, dynamic ranges, and temperature dependence of such sensors. Commonly used optical sensing schemes are covered in a next main chapter, with subsections on methods based on absorptiometry, reflectometry, luminescence, refractive index, surface plasmon resonance, photonic crystals, turbidity, mechanical displacement, interferometry, and solvatochromism. This is followed by sections on absorptiometric and luminescent molecular probes for use pH in sensors. Further large sections cover polymeric hosts and supports, and methods for immobilization of indicator dyes. Further and more specific sections summarize the state of the art in materials with dual functionality (indicator and host), nanomaterials, sensors based on upconversion and 2-photon absorption, multiparameter sensors, imaging, and sensors for extreme pH values. A chapter on the many sensing formats has subsections on planar, fiber optic, evanescent wave, refractive index, surface plasmon resonance and holography based sensor designs, and on distributed sensing. Another section summarizes selected applications in areas, such as medicine, biology, oceanography, bioprocess monitoring, corrosion studies, on the use of pH sensors as transducers in biosensors and chemical sensors, and their integration into flow-injection analyzers, microfluidic devices, and lab-on-a-chip systems. An extra section is devoted to current challenges, with subsections on challenges of general nature and those of specific nature. A concluding section gives an outlook on potential future trends and perspectives.

Optical Sensing and Imaging of pH Values: Spectroscopies, Materials, and Applications

The fabrication and characterization of a fibre optic pH sensor based on evanescent wave absorption is presented. The unclad portion of a multi-mode optical fibre is coated with a pH sensitive dye, which is immobilized by the sol-gel route. The sensitivity of the device has been found to increase when multiple sol-gel coatings are used as the sensing region. The dynamic range and the temporal response of the sensor are investigated for two different dyes, namely bromocresol purple and bromocresol green. The performance of the device is evaluated in terms of the results obtained during actual measurements.

/pdf/a-sensitive-fibre-optic-ph-sensor-using-multiple-sol-gel-140cuomk2q.pdf

A sensitive fibre optic pH sensor using multiple sol-gel coatings

https://dyuthi.cusat.ac.in/xmlui/bitstream/handle/purl/2407/Dyuthi-P0235.pdf?sequence=3

A microbent fiber optic pH sensor

https://dyuthi.cusat.ac.in/xmlui/bitstream/handle/purl/2495/Dyuthi-P0250.pdf;sequence=3

Long period gratings in multimode optical fibers: application in chemical sensing

Design and development of an LED based fiber optic evanescent wave sensor for simultaneous detection of chromium and nitrite traces in water

In this communication, we discuss the details of fabricating an off-line fibre optic sensor (FOS) based on evanescent wave absorption for detecting trace amounts of Fe3+ in water. Two types of FOS are developed; one type uses the unclad portion of a multimode silica fibre as the sensing region whereas the other employs the microbent portion of a multimode plastic fibre as the sensing region. Sensing is performed by measuring the absorption of the evanescent wave in a reagent medium surrounding the sensing region. To evaluate the relative merits of the two types of FOS in Fe3+ sensing, a comparative study of the sensors is made, which reveals the superiority of the latter in many respects, such as smaller sensing length, use of a double detection scheme (for detecting both core and cladding modes) and higher sensitivity of cladding mode detection at an intermediate range of concentration along with the added advantage that plastic fibres are inexpensive. A detection limit of 1 ppb is observed in both types of fibre and the range of detection can be as large as 1 ppb–50 ppm. All the measurements are carried out using a LabVIEW set-up.

https://iopscience.iop.org/article/10.1088/0957-0233/14/6/322/pdf

S. Thomas Lee

Papers

A sensitive fibre optic pH sensor using multiple sol-gel coatings

A microbent fiber optic pH sensor

Long period gratings in multimode optical fibers: application in chemical sensing

Design and development of an LED based fiber optic evanescent wave sensor for simultaneous detection of chromium and nitrite traces in water

Evanescent wave fibre optic sensors for trace analysis of Fe3+ in water