Recent advances in visible-light-mediated organic transformations in water

Photo-/electrocatalytic functionalization of quinoxalin-2(1H)-ones

Acyl Radicals from α-Keto Acids: Metal-Free Visible-Light-Promoted Acylation of Heterocycles.

Radical‐initiated difunctionalization of alkenes is one of the most important methods in organic synthesis and medicinal chemistry, which can be applied to synthesize value complex compounds as well as structural motifs that found in bioactive natural products and pharmaceuticals. In recent years, impressive progress have been made in this area with ideal silver catalysis. Here, we summarize recent advances in silver‐mediated radical difunctionalization of alkenes for the formation of diverse bonds, including 1) two‐component radical difunctionalization reactions enabled by an intramolecular cyclization process toward various cyclic compounds and 2) three‐component radical difunctionalization reactions leading to complex linear compounds. These silver‐mediated radical alkene difunctionalization transformations are general initiated by different radicals, such as carbon‐, oxygen‐, sulfur‐, phosphinyl‐, and halogen‐center radicals, followed by terminated with nucleophiles to form two new bonds in a single reaction.

Recent Advances in Silver-Mediated Radical Difunctionalization of Alkenes

Carbon–sulfur bond formation via photochemical strategies: An efficient method for the synthesis of sulfur-containing compounds

Arylaminomethyl Radical-Initiated Cascade Annulation Reaction of Quinoxalin-2(1H)-ones Catalyzed by Recyclable Photocatalyst Perovskite

Silver‐Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines

Synthesis of Phosphoryl‐Substituted Benzimidazo[2,1‐a]isoquinolin‐6(5H)‐ones from 2‐Arylbenzoimidazoles and Diarylphosphine Oxides

Radical Cascade Reactions of β,γ-Unsaturated Hydrazones/Oximes

An effective and simple visible light-induced heterogeneous g-C3N4-catalyzed decarboxylative reaction of quinoxalin-2(1H)-ones with N-aryl glycines was developed. When the reaction was performed in...

Divergent g‑C 3 N 4 ‑catalyzedReactions of Quinoxalin-2(1 H )‑ones with N ‑Aryl Glycines under Visible Light: Solvent-ControlledHydroaminomethylation and Annulation

Si Yafeng

Papers

Arylaminomethyl Radical-Initiated Cascade Annulation Reaction of Quinoxalin-2(1H)-ones Catalyzed by Recyclable Photocatalyst Perovskite

Silver‐Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines

Synthesis of Phosphoryl‐Substituted Benzimidazo[2,1‐a]isoquinolin‐6(5H)‐ones from 2‐Arylbenzoimidazoles and Diarylphosphine Oxides

Radical Cascade Reactions of β,γ-Unsaturated Hydrazones/Oximes

Divergent g‑C 3 N 4 ‑catalyzedReactions of Quinoxalin-2(1 H )‑ones with N ‑Aryl Glycines under Visible Light: Solvent-ControlledHydroaminomethylation and Annulation