S
Simon M. Doughty
Researcher at University of Sheffield
Publications - 10
Citations - 148
Simon M. Doughty is an academic researcher from University of Sheffield. The author has contributed to research in topics: Norbornadiene & Hydrogen bond. The author has an hindex of 8, co-authored 9 publications receiving 148 citations.
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Journal ArticleDOI
Second Sphere Coordination of Cationic Rhodium Complexes by Dibenzo[3n]crown‐n Ethers
Journal ArticleDOI
Second‐sphere Coordination of [Pt(bipy)(NH3)2]2+ by Dibenzo‐crown Ethers. Solution Spectroscopic Studies and the Crystal and Molecular Structures of [Pt(bipy)(NH3)2.dibenzo‐30‐crown‐10] [PF6]2.0.6 H2O and [Pt(bipy)(NH3)2.dibenzo‐24‐crown‐8] [PF6]2
Howard M. Colquhoun,Simon M. Doughty,John M. Maud,J. Fraser Stoddart,David J. Wllliams,John B. Wolstenholme +5 more
TL;DR: In addition to hydrogen bonding and Coulombic forces, charge transfer interactions stabilise the 1:1 adducts formed between [Pt(bipy)(NH3)2] 2+ and a series of dibenzo-3n-crown-n (n = 6-12) ethers as evidenced by 1H NMR and UV-visible spectra in solution and by X-ray crystal structures (for n = 8 and 10) in the solid state as mentioned in this paper.
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Diamminebis(1,5-cyclooctadiene)(μ-1,4,10,13-tetraoxa-7, 16-diazacyclooctadecane-N7, N16)dirhodiumbis-(hexafluorophosphate): An Example of Simultaneous First and Second Sphere Coordination†
Howard M. Colquhoun,Simon M. Doughty,Alexandra M. Z. Slawin,J. Fraser Stoddart,David J. Williams +4 more
Journal ArticleDOI
The isolation and X-ray structure of a complex between lithium picrate and dibenzo-36-crown-12
Simon M. Doughty,J. Fraser Stoddart,Howard M. Colquhoun,Alexandra M. Z. Slawin,David J. Williams +4 more
TL;DR: The crystal structure of 2Li picrate was determined by X-ray diffraction methods as mentioned in this paper, and the 2H2O complex was shown to have a 2:1 crystal structure.
Journal ArticleDOI
A comparison of the receptor stereochemistry in [Pt(bipy)(NH3)2·dinaphtho-30-crown-10][PF6]2 and [Diquat·dinaphtho-30-crown-10][PF6]2(bipy = 2,2′-bipyridine)
Billy L. Allwood,Howard M. Colquhoun,Simon M. Doughty,F. H. Kohnke,Alexandra M. Z. Slawin,J. Fraser Stoddart,David J. Williams,Ryszard Zarzycki +7 more
TL;DR: In this paper, X-ray crystallography and 1H n.m.r. spectroscopy have revealed dramatic differences in the binding of [Pt(bipy)(NH3)2]2 + and [Diquat]2+ dications by dinaphtho-30-crown-10 (DN30C10) with the platinum complex adopting a slewed position, apparently in order to maximise overlap between the π-arene systems in the receptor and in the complex, whereas the Diquat dication adopts a